Eastman-kodak Company

Other

Carestream Health, Inc.

Robert E Dickerson

Alan S Fitterman

Phillip C Bunch

William E Moore

David J Steklenski

Stephen A Hershey

Anthony Adin

Franklin C Brayer

Jeffrey S Baugher

Richard F Davis

Marcia K Hansen

James C Bolthouse

Ronald J Perry

James E Kelly

Peter J Kelch

Patrick M Jeffries

Rickey J Seyler

Kenneth A Duke

Mridula Nair

Donald R Diehl

Lloyd A Lobo

Steven G Link

Allen K Tsaur

Ronda E Factor

George L Oltean

David G Sherburne

Richard B Anderson

Wayne W Weber, Ii

Susan K Mroczek

Richard E Beal

Fred M Macon

Kenneth E Huff

Wray Earl Paul

Max Allen Weaver

Alphonse D Camp

Wayne P Pruett

Kurt Michael Schroeder

Kevin W Williams

Richard L Daubendiek

Robert D Wilson

George J Burgmaier

Luther C Roberts

Larry K Maier

Elizabeth K Priebe

Steven P Szatynski

James T Samuels

Anthony D Gingello

Michael Phillip Youngblood

Eric L Dillenbeck

Carl R Preddy

Thomas I Abbott

Nathan J Romano

Mark P Pavlik

Paul W Twombly

Robert L Childers

Arthur G Haus

Richard J Jebo

A radiographic X-ray film comprising a polymer support. One or more silver halide emulsion layers are coated on each side of the support. A blue dye is contained within at least one of the polymer support or in an adjacent hydrophilic layer in a sufficient amount to result in a CIELAB measurement of L* less than or equal to 80 and b* less than or equal to &#x2212;25. This configuration provides, after imaging and development, radiographic images having desirable visual contrast, image tone, b*, and image quality.

Film with blue dye

A radiographic material containing tabular silver halide grains also includes an amido compound as an antifoggant precursor that can slowly release an antifoggant over time. These compounds are present in reactive association with the silver halide in tabular silver halide emulsion layers, and are present in an amount of at least 0.5 mmol/mol of silver. The radiographic materials are protected from fog during storage particularly in high temperature environments.

Radiographic materials with antifoggant precursors

Photographic silver halide materials containing an incorporated black-and-white developing agent can be quickly and simply processed using unique processing compositions and methods. In a 'two-step' method, the exposed material is contacted with an alkaline activator solution followed by a fixing composition. In a 'one-step' method, activation and fixing are combined using a single alkaline activator-fixing composition containing the fixing agent. None of the processing solutions include black-and-white developing agents. The photographic silver halide materials are preferably radiographic silver halide materials that have a reflective support and provide black-and-white images that can be viewed without a light box.

Method of processing silver halide materials

A radiographic imaging assembly comprises a symmetric radiographic silver halide film has an overall system speed of at least 1100 to provide images with improved contrast and sharpness and reduced fog. The imaging assembly includes a symmetric radiographic film having a speed of at least 700 that includes at least two silver halide emulsions on each side of the support that comprise tabular silver halide grains. The emulsions closer to the support comprise a suitable crossover control agent. The imaging assembly also includes a pair of phosphor intensifying screens that have an average screen sharpness measurement (SSM) greater than reference Curve A of FIG.. The screens can have a support that includes a reflective substrate comprising a continuous polyester phase and microvoids containing inorganic particles dispersed within the polyester phase.

Ultrahigh speed imaging assembly for radiography

Photothermographic materials are coated with imaging layers and an antihalation layer between the support and thermally developable imaging layers on one or both sides of the support. Such materials can be arranged in association with one or more phosphor intensifying screens capable of providing emission at a predetermined wavelength in imaging assemblies. These imaging assemblies can be exposed to X-radiation and thereby excited to form a latent image in the photothermographic material that can eventually be used for medical diagnosis. The antihalation layers contain radiation absorbing compounds (such as a UV-radiation absorbing compounds) that absorb radiation at the predetermined wavelength (for example at 300 to 450 nm) and have limited absorption at higher wavelengths.

Photothermographic materials with UV absorbing compounds

Photothermographic materials are coated with thermally developable imaging layers on both sides of the support. Such materials can be arranged in association with one or more phosphor intensifying screens capable of providing emission at a predetermined wavelength in imaging assemblies. These imaging assemblies can be exposed to X-radiation and thereby form a latent image in the photothermographic material that can eventually be heat developed and used for medical diagnosis. The photothermographic materials contain an opaque material that acts as a crossover control agent that absorbs radiation at the predetermined wavelength, for example at 300 to 450 nm, and has limited absorption at higher wavelengths. When the photothermographic material is heated, the opaque material loses its opacity. Additional crossover control agents, such as UV-absorbing compounds, can also be added to the support or to an antihalation layer.

Photothermographic materials with opaque crossover control means

A reflective radiographic material is useful to provide images that can be viewed without a light box. This reflective radiographic material has a reflective support and a silver halide emulsion on one side of the support only. The material can be used with a single green- or blue-light emitting fluorescent intensifying screen as part of an imaging assembly. The reflective support enables the image in the radiographic material to be viewed without a light box and the speed of the material enables the use of low power X-radiation generating equipment.

High speed reflective radiographic material

A reflective radiographic material (at least 200 system speed) is useful especially to provide images that can be viewed without a light box. This reflective radiographic material has a reflective support, a silver halide emulsion on one side of the support only, and a photographic speed of at least 200. The reflective material also includes an incorporated black-and-white developing agent and a co-developing agent, and can be used with a single fluorescent intensifying screen as part of an imaging assembly. The reflective support enables viewing the resulting image without a light box and the high speed of the material enables the use of low power X-radiation generating equipment. The incorporated black-and-white developing agent and co-developing agent allow the radiographic material to be quickly processed after exposure using simplified processing chemistry.

Reflective radiographic material with incorporated developer

A radiographic imaging assembly comprises a symmetric radiographic silver halide film has an overall system speed of at least 200 but less than 800 to provide images with improved contrast and sharpness and reduced fog. The imaging assembly includes a symmetric radiographic silver halide film having a speed of at least 700 that includes two silver halide emulsions on both sides of the support that comprise tabular silver halide grains. The emulsions closer to the support comprise a suitable crossover control agent. The imaging assembly also includes a pair of phosphor intensifying screens that have a screen sharpness measurement (SSM) greater than reference Curve A of FIG.. The screens can have a support that includes a reflective substrate comprising a continuous polyester phase and microvoids containing inorganic particles dispersed within the polyester phase.

High speed imaging assembly for radiography

A high-speed (over 700) radiographic silver halide film is useful for radiography to provide images with improved contrast and sharpness and reduced fog. The film includes at least one tabular grain silver halide emulsion layer on each side of a film support which grains are dispersed in a hydrophilic polymeric vehicle mixture comprising at least 0.05% of oxidized gelatin, based on the total dry weight of the hydrophilic polymeric vehicle mixture. Where multiple silver halide emulsion layers are disposed on each side of the film support, the emulsion layers closest to the support on each side can include crossover control agents to reduce crossover to less than 15%.

High-speed radiographic film

An ultra-high-speed radiographic imaging assembly (at least 900 system speed) is useful especially for pediatric radiography to provide images with improved contrast and sharpness and reduced fog. The imaging assembly includes a symmetric film having a speed of at least 400 that includes at least two silver halide emulsion layers on each side of a film support that comprise tabular silver halide grains. The imaging assembly also includes two fluorescent intensifying screens wherein the pair of screens has a screen speed of at least 400 and the screens have an average screen sharpness measurement (SSM) value greater than reference Curve A of. The screens can have a support that includes a reflective substrate comprising a continuous polyester phase and microvoids containing inorganic particles dispersed within the polyester phase.

High speed radiographic imaging assembly

A method of mammography imaging includes exposing a patient to a peak voltage greater than 29 kVp using X-radiation generating equipment comprising rhodium or tungsten anodes. The film used in this method comprises a cubic grain silver halide emulsion layer on one side of the support and a tabular grain silver halide emulsion layer on the other side. The cubic grain silver halide emulsion layer comprises a combination of first and second spectral sensitizing dyes that provides a combined maximum J-aggregate absorption on the cubic silver halide grains of from about 540 to about 560 nm. The first spectral sensitizing dye is an anionic benzimidazole-benzoxazole carbocyanine, the second spectral sensitizing dye is an anionic oxycarbocyanine. The cubic grain silver halide emulsion layer also includes a mixture of gelatin or a gelatin derivative and a second hydrophilic binder other than gelatin or a gelatin derivative. The cubic silver halide grains comprise from about 1 to about 20 mol % chloride and from about 0.25 to about 1.5 mol % iodide, both based on total silver in the cubic grain emulsion layer, which cubic silver halide grains have an average ECD of from about 0.65 to about 0.8 &#x3bc;m. Moreover, the cubic silver halide grains are doped with a hexacoordination complex compound within part or all of the innermost 95% of the grains. The film can be exposed to provide a black-and-white image having a d(&#x3b3;)/d(log E) value greater than 5.

Mammography imaging method using high peak voltage and rhodium or tungsten anodes

A radiographic silver halide film comprises a cubic grain silver halide emulsion layer on one side of the support and a tabular grain silver halide emulsion layer on the other side. The cubic grain silver halide emulsion layer comprises a combination of first and second spectral sensitizing dyes that provides a combined maximum J-aggregate absorption on the cubic silver halide grains of from about 540 to about 560 nm. The first spectral sensitizing dye is an anionic benzimidazole-benzoxazole carbocyanine, the second spectral sensitizing dye is an anionic oxycarbocyanine. The cubic grain silver halide emulsion layer also includes a mixture of gelatin or a gelatin derivative and a second hydrophilic binder other than gelatin or a gelatin derivative at a weight ratio of first to second hydrophilic binder of from about 2:1 to about 5:1. The cubic silver halide grains comprise from about 1 to about 20 mol % chloride and from about 0.25 to about 1.5 mol % iodide, which cubic silver halide grains have an average ECD of from about 0.65 to about 0.8 &#x3bc;m. Moreover, the cubic silver halide grains are doped with a hexacoordination complex compound within part or all of the innermost 95% of the grains. These films can be exposed to provide a black-and-white image having a d(&#x3b3;)/d(log E) value greater than 5 and are particularly useful when imaged using X-radiation generating devices comprising rhodium or tungsten anodes.

Mammography film and imaging assembly for use with rhodium or tungsten anodes

A method of mammography imaging includes exposing a patient to a peak voltage greater than 29 kVp. The film used in this method comprises a cubic grain silver halide emulsion layer on one side of the support and a tabular grain silver halide emulsion layer on the other side. The cubic grain silver halide emulsion layer comprises a combination of first and second spectral sensitizing dyes that provides a combined maximum J-aggregate absorption on the cubic silver halide grains of from about 540 to about 560 nm. The first spectral sensitizing dye is an anionic benzimidazole-benzoxazole carbocyanine, the second spectral sensitizing dye is an anionic oxycarbocyanine. The cubic grain silver halide emulsion layer also includes a mixture of gelatin or a gelatin derivative and a second hydrophilic binder other than gelatin or a gelatin derivative. The cubic silver halide grains comprise from about 1 to about 20 mol % chloride and from about 0.25 to about 1.5 mol % iodide, both based on total silver in the cubic grain emulsion layer, which cubic silver halide grains have an average ECD of from about 0.65 to about 0.8 &mgr;m. Moreover, the cubic silver halide grains are doped with a hexacoordination complex compound within part or all of the innermost 95% of the grains. The film can be exposed to provide a black-and-white image having a d(&ggr;)/d(log E) value greater than 5.

Mammography imaging method using high peak voltage

A radiographic imaging assembly comprises a radiographic silver halide film having a film speed of at least 100 and a single fluorescent intensifying screen that has a screen speed of at least 200. This imaging assembly is particularly useful for mammography or imaging or other soft tissues.

Radiographic imaging assembly for mammography

Growing community of inventors

Hamlin, NY, United States of America

Robert E Dickerson