Other

Michigan State University

Weatherford/lamb, Inc.

Robert E Buxbaum

Andrew S Kuczma

Peter C Hsu

A method of operating a fuel cell system to produce electrical power that includes a hydrocarbon or alcohol fuel feed stock containing water vapor or steam being reformed in the fuel cell or in a separate reformer with the output gas from the fuel cell going to a water gas shift reactor to convert a portion of the carbon monoxide to carbon dioxide and hydrogen. A portion of the carbon dioxide then being removed to yield a hydrogen rich gas that is piped back into the solid oxide fuel cell or the molten carbonate fuel cell in concert with the reformed or unreformed fuel feed stock. A system for performing the method is also provided.

High efficiency fuel reforming and water use in a high temperature fuel-cell system and process for the such thereof

A hydrogen permeation membrane is provided having a cP2 Pearson symbol (Pm3m space group) structure. Suitable alloys include an 'A' element from Periodic Table groups 3b-5b and an 'M' element from the Periodic Table groups 6b-1b present at a stoichiometry that achieves the inventive crystal structure. Zr and Nb are the preferred A elements followed in preference by Ti and V. First Periodic Table row elements from groups 6b-1b are the preferred B elements. The inventive alloys also find applications as hydrogen getters, Ni-metal hydride battery materials, and hydrogen storage materials.

Space group Cp2 alloys for the use and separation of hydrogen

The membrane reactor of the present invention generates a desired gas such as hydrogen produced by steam reforming liquid fuels. The membrane reactor provides thermal integration between the heating source and the reaction catalyst by heat conduction through a solid medium. A gas purification system extracts energy from the waste gases to heat the membrane reactor. This, in concert with other control mechanisms provided results in a more efficient gas purification process.

Membrane reactor for gas extraction

The present invention generally provides a hydrogen gettering agent containing a fullerene compound, a protected optical fiber cable containing the hydrogen gettering agent and a method of making the same. According to some embodiments, the protected optical fiber cable is provided comprising a protective sheath, at least one optical fiber positioned within the protective sheath, and the hydrogen gettering agent surrounding the at least one optical fiber within the protective sheath.

Protected optical fiber cable and hydrogen gettering agent

The membrane reactor of the present invention generates a desired gas such as hydrogen produced by steam reforming liquid fuels. The membrane reactor provides thermal integration between the heating source and the reaction catalyst by heat conduction through a solid medium. Pressure energy within the membrane reactor provides compression of the feed to lower the partial pressure of product within the reactor, thereby increasing the membrane reactor effect.

A hydride battery electrode is coated with palladium or a palladium alloy to improve hydride storage properties and recycle characteristics. A hydrogen purification membrane including a metallic substrate likewise has improved properties upon coating with palladium and a surface species of an alkali metal, alkaline earth element or alkaline earth cation. Novel metal hydrogen purification membranes include vanadium alloyed with at least 1 to 20 atomic percent nickel and/or 1 to 20 atomic percent cobalt and/or 1 to 20 atomic percent palladium.

Hydrogen permeable membrane and hydride battery composition

An apparatus for extracting a gas, in particular hydrogen, from a fluid stream utilizing a plate membrane flattened with a wave spring on the low pressure side of the membrane and a turbulence generator on the high pressure side. Alternately, the membrane is folded and wrapped against a central conduit within the membrane fold. Extraction membranes have a substrate layer of Ta&mdash;W, V&mdash;Co, V&mdash;Pd, V&mdash;Au, V&mdash;Cu, V&mdash;Al, Nb&mdash;Ag, Nb&mdash;Au, Nb&mdash;Pt, Nb&mdash;Pd, V&mdash;Ni&mdash;Co, V&mdash;Ni&mdash;Pd, V&mdash;Nb&mdash;Pt or V&mdash;Pd&mdash;Au alloy or combination thereof and a first layer affixed to the outer surface of the substrate towards a mixed gas flow which is composed of palladium, platinum, rhodium, or palladium alloys.

Hydrogen generator

A high temperature membrane reactor or gas purification apparatus includes a housing containing a gas heating chamber and a gas extraction component, preferably one or more tubular membranes. The preferred application is for extracting hydrogen from a mixed gas flow or for generating hydrogen, e.g., by reforming methanol, ethanol, or gasoline. A surrounding annulus provides heat exchange and insulation by circulating the mixed gas flow about the housing and then injecting the mixed gas flow into the housing for extraction or reaction. The apparatus further includes an outlet for releasing raffinate preferably including a flow controlling restriction. Heating is provided by conducting the raffinate from the gas extraction component to the heating chamber wherein reaction with a catalyst generates heat. These features, alone or in combination, provide better energy management, better flow management, and better safety than current designs. A spring-type support for the membrane is further described which increases the maximum useable operation pressure of the membranes to take better advantage of the membrane reactor and gas purification features.

High temperature gas purification apparatus

Apparatus and methods for gas extraction

High temperature gas purification system

A membrane (14) for extracting hydrogen from fluid streams containing hydrogen consists essentially of a first layer (16) of a refractory metal or alloy which is permeable to hydrogen and has first and second surfaces (18,20). A second layer (22) is electroless or electrolytically deposited over the first surface (18) and attached thereto. A third layer (24) is similarly deposited over the other refractory surface (20), the second and third layers (22,24) consisting essentially of palladium, palladium alloys or platinum. A modification of this, for use in some applications, is the above membrane coated on only one surface with palladium, palladium alloys or platinum.

Composite metal membrane for hydrogen extraction

A method for plating palladium on Group IV-B and V-B metals, particularly niobium, vanadium, zirconium, titanium and tantalum as pure metals and as alloys is described. The method provides the metal to be plated with a roughened exposed surface to be plated which has been electrolytically hydrided and then the surface is plated using electroless or electrolytic plating. Hydride is removed from the plated surface, usually by heating. This also removes other surface impurities and aids the coat adhesion. The resulting palladium plated metal articles are usful for hydrogen extraction.

Growing community of inventors

Oak Park, MI, United States of America

Robert E Buxbaum