Dow Global Technolgoies LLC

Robert D Swindoll

Pradeep Jain

Alec Y Wang

Sean W Ewart

John G Pendergast, Jr

Shrikant Dhodapkar

Michael Joseph Zogg, Jr

Jorge Rubalcaba

Maria Pollard

Job D Guzman

Yujun Liu

Prasanna K Jog

Gary A Camp

Johnny W Masey

George W Haun, Jr

Bradley K Blanchard

Mitch Juneau

Nile A Mead

Prasanna Jog

Nile Mead

Job Guzman

Disclosed herein is a system for solution polymerization comprising a reactor system that is operative to receive a monomer and to react the monomer to form a polymer; a plurality of devolatilization vessels located downstream of the reactor system, where each devolatilization vessel operates at a lower pressure than the preceding devolatilization vessel; and a heat exchanger disposed between two devolatilization vessels and in fluid communication with them, where the heat exchanger has an inlet port temperature of 100&#xb0; C. to 230&#xb0; C., an outlet port temperature of 200&#xb0; C. to 300&#xb0; C., an inlet port pressure of 35 to 250 kgf/cmand an outlet port pressure of 20 to 200 kgf/cm; and wherein the polymer solution remains in a single phase during its residence in the heat exchanger.

Method and system for polymer production

Disclosed herein is a system for recovering olefins from a vent stream comprising an absorber; and a stripper; where the absorber and the stripper are in a recycle loop; and where the absorber is operative to treat a vent stream with a solvent to remove more than 99 wt % of a halogenated by-product contained in the vent stream and to recover 90 to 95 wt % of olefin molecules present in the vent stream; and where the stripper is operative to remove more than 99 wt % of the halogenated by-products present in the solvent; and where the solvent is recycled to the absorber.

Process for purification of vent streams

The present invention provides a system and process for olefin polymerization. The inventive system and process for olefin polymerization facilitate lower operating vacuum pressures in the polymer recovery system by requiring at least two sequential condensing units, wherein at least one of the condensing units operates at significantly lower temperature ranges than the temperature ranges at which the current systems operate.

System and process for olefin polymerization

The invention provides a solution polymerization process comprising: A) polymerizing one or more monomers in the presence of a solvent that comprises a heavy hydrocarbon solvent and a light hydrocarbon solvent, to form a polymer solution; B) transferring the polymer solution to a Liquid-Liquid Separator, without adding heat to the solution, and wherein the pressure of the polymer solution is actively reduced in a controlled manner prior to, or within, the Liquid-Liquid Separator, to induce at least two liquid phases, a polymer-rich phase and a solvent-rich phase, and wherein the concentration of polymer in the polymer-rich phase is higher than that in the polymer solution transferred to the Liquid-Liquid Separator; and C) removing the solvent-rich phase.

Polymerization process for olefin-based polymers

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Clute, TX, United States of America

Robert D Swindoll