Alliedsignal Inc.

Honeywell International Inc.

Robert Christian Parker

Ian R Shankland

Gary Michael Knopeck

Timothy R Demmin

Earl August Lund, Deceased

Richard E Eibeck

Donna M Ruszaj

Earl A Lund

Stephen Frederic Yates

George David Green

Raymond Hilton Thomas

Keith A Horn

Willis Hammond

Hilde Lund, Legal Representative

Azeotrope-like compositions of 1,1,1,3,3-pentafluoropropane and at least one hydrocarbon selected from the group n-pentane, iso-pentane, cyclopentane, n-hexane and iso-hexane are provided. The compositions of the invention are useful in the preparation of polyurethane and polyisocyanurate foams.

Azeotrope-like compositions of 1,1,1,3,3-pentafluoropropane and hydrocarbons

Azeotrope-like compositions of 1,1,1,3,3-pentafluoropropane and 1,1-dichloro-1-fluoroethane are provided. The compositions of the invention are useful in the preparation of polyurethane and polyisocyanurate foams and as aerosol propellants.

Azeotrope-like compositions of 1,1,1,3,3-pentafluoropropane and

Azeotrope-like compositions of 1,1,1,3,3-pentafluoropropane and pentane

The present invention relates to foam compositions which are expanded with hydrohalocarbon blowing agents in the presence of catalysts which result in a decreased amount of decomposition of the hydrohalocarbon blowing agents to haloalkenes during the polymerization. Thus, the present invention provides compositions comprising polyisocyanate, polyol, hydrohalocarbon blowing agent, surfactant, and at least one catalyst for polymerization of the polyisocyanate and polyol wherein the catalyst is less volatile than N,N-dimethylcyclohexylamine or the catalyst is a tertiary amine having at least one isocyanate-reactive functionality selected from the group consisting of --OH and --NH-- and the catalyst results in a decreased amount of decomposition of the hydrohalocarbon blowing agents to haloalkenes during polymerization of the polyisocyanate and the polyol and especially during use of the foam samples at a temperature of at least about 54.degree. C.

Catalysts which stabilize hydrohalocarbon blowing agent in polyurethane

Azeotrope-like compositions of 1 1 1 3 3-pentafluoropropane and 1

Azeotrope-like compositions of 1, 1, 1, 3, 3-pentafluoropropane and at least one hydrocarbon selected from the group n-pentane, iso-pentane, cyclopentane, n-hexane and iso-hexane are provided. The compositions of the invention are useful in the preparation of polyurethane and polyisocyanurate foams.

Azeotrope-like compositions of 1,1,1,3,3-pentaflurorpropane and

The present invention relates to foam compositions which are expanded with hydrohalocarbon blowing agents in the presence of catalysts which are capable of decreasing the amount of decomposition of the hydrohalocarbon blowing agents to haloalkenes during the polymerization. Thus, the present invention provides compositions comprising polyisocyanate, polyol, hydrohalocarbon blowing agent, surfactant, and catalyst for polymerization of the polyisocyanate and polyol wherein the catalyst is capable of decreasing the amount of decomposition of the hydrohalocarbon blowing agents to haloalkenes during polymerization of the polyisocyanate and the polyol.

Catalysts which stabilize hydrohalocarbon blowing agent in

The present invention relates to foam compositions which are expanded with hydrohalocarbon blowing agents in the presence of additives which decrease the formation of haloalkenes during the polymerization. Thus, the present invention provides compositions comprising polyisocyanate, polyol, hydrohalocarbon blowing agent, catalyst, surfactant, and at least one additive wherein the additive is capable of decreasing the amount of decomposition of said dehydrohalocarbon blowing agent to haloalkenes during polymerization of the polyisocyanate and the polyol. Depending upon the polyol and polyisocyanate used and the quantity of polyisocyanate used, the compositions may be used in pour-in-place molded foams; rigid urethane spray foams; rigid high and low density foams for slabstock, froth foams, and molded foams; rigid laminated boardstock; or specialty foams.

Additives which stabilize hydrohalocarbon blowing agent in polyurethane

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Hamburg, NY, United States of America

Robert Christian Parker