Rhone-Poulenc Industries

Rhone-Poulenc Specialites Chimiques

Rhone-Poulenc Recherches

Ciba-Geigy Corporation

Rhone-Poulenc S.a.

Rhone-Poulenc Fibres

Kermel Snc.,

Robert Cassat

Bruno Vignando

Daniel Semanaz

Gerard Guillot

Jean-Paul Faure

Jean-Pierre Logel

Maurice Alliot-Lugaz

Composite article and method for making same

The present invention relates to a reactivable paper and to a process for obtaining it. The paper consists of fibres with a heat resistance .gtoreq.180.degree. C., bonded together by means of a fibrous binder composed of polyamide or aromatic polyester pulp and of a chemical binder consisting of a polyether-imide of an aromatic polyester or of a resin of polyimide type, with a particle size smaller than 100 .mu.m, a softening point of between 50.degree. and 200.degree. C., and a degree of crosslinking of between 0.025 and 0.25. The weight proportion of fibres in the finished paper is generally preferably between 45 and 85%, that of the fibrous binder between 5 and 20%, that of the chemical binder between 10 and 50%. The papers are obtained by a wet route and find wide applications as a function of the degree of conversion of the resin, for example as a dielectric.

Synthetic papers based on thermally stable fibres, pulp and binder and

A process for coating a plastics article with a thin layer of noble metal, wherein said plastics article contains a finely particulate, homogenized filler selected from the group consisting of MnO, NiO, Cu.sub.2 O, SnO and Bi.sub.2 O.sub.3, and said plastics article is coated with an acid aqueous solution of a noble metal salt.

Process for coating plastics articles

Substrate composites, well adopted for the production of metallized printed circuits and facilely prepared by, e.g., papermaking procedures, include a central core layer comprising fibrous cellulosic material or flaked mica within a matrix of a thermosetting resin binder, said central core element having coextensively laminated to at least one of the face surfaces thereof, a lamina of a thermosetting resin comprising non-conductive metal oxide filler material distributed therethrough, and said metal oxide being borohydride reduceable and reactive to form unstable metal hydride intermediates.

Metallizable substrate composites and printed circuits produced therefrom

Thick-layer hybrid electronic printed circuits are formed by printing predetermined circuit pattern onto an insulating substrate by deposition of predetermined ink pattern thereupon, advantageously by silk-screening or masking, and thence baking said ink circuit pattern, and repeating the deposition/baking steps as required, the subject forming process featuring use of an insulating ink comprising a non-conductive metallic oxide extender, desirably cuprous oxide, which ink is thus either potentially conductive or potentially resistive, and the development of such conductivity or resistivity, after baking, by treating the ink pattern with a reducing agent, desirably a borohydride, as to readily and quantitatively convert said metal oxide into a conducting metal.

Forming of thick-layer, hybrid electronic printed circuits

Plastic substrata are metallized, preferably by direct electrolytic metallization, by (i) providing a plastic shaped article comprising intimate admixture of a polymeric resin and a plurality of small metallic filler particles of a non-conductive oxide of a non-noble metal uniformly dispersed therethrough, at least one of the face surfaces of said shaped article having exposed thereon such high density of said metallic filler particles as to provide in step (ii) metallization growth nuclei adapted for direct electrolytic metallization; (ii) next subjecting said at least one face surface of said plastic shaped article to the action of a reducing agent to essentially quantitatively convert the non-conductive metal oxide filler particles to conductive free metal, metallization growth nuclei; and (iii) thence electrochemically and/or electrolytically metallizing the at least one reduced face surface of said plastic shaped article with a free metal deposit.

Metallizing of plastic substrata

Electrically insulating polyimide/aromatic polyamide film substrates are conductively metallized, e.g., to provide highly thermally stable base members useful in the fabrication of printed circuits and the like, by (1) shaping into such essentially thermosetting film substrate an intimate homogeneous admixture of a film-forming polyimide/aromatic polyamide matrix having from 20 to 60 percent by total weight of said admixture of finely divided, non-conductive metal oxide particles uniformly distributed therein, (2) disrupting at least one face surface of said shaped film substrate to expose thereon a plurality of said finely divided, non-conductive metal oxide particles, (3) treating said at least one disrupted face surface with a preferably borohydride reducing agent to reduce said exposed metal oxide particles into a layer of electrically conductive free metal, whereby said at least one surface is rendered electrically conductive, and, advantageously, (4) electrolytically depositing a reinforcing, electrically conductive metallic overlayer atop said first layer of electrically conductive free metal.

Metallization of electrically insulating polyimide/aromatic polyamide

Electrically insulating polymeric film substrates are conductively metallized, e.g., to provide base members useful in the fabrication of printed circuits and the like, by (1) shaping into such film substrate an intimate homogeneous admixture of a film-forming polymer matrix having from 10 to 70 percent by total weight of said admixture of finely divided, non-conductive metal oxide particles uniformly distributed therein, (2) disrupting at least one face surface of said shaped film substrate to expose thereon a plurality of said finely divided, non-conductive metal oxide particles, (3) treating said at least one disrupted face surface with a preferably borohydride reducing agent to reduce said exposed metal oxide particles into a layer of electrically conductive free metal, whereby said at least one face surface is rendered electrically conductive, and, advantageously, (4) eletrolytically depositing a reinforcing, electrically conductive metallic overlayer atop said first layer of electrically conductive free metal.

Metallization of electrically insulating polymeric film substrates

A metallized, laminated substrate well adapted for the production of printed circuits is comprised of:

Metal-clad laminate adapted for printed circuits

Essentially isotropic metallizable polymeric substrates having very low coefficients of thermal expansion are well adopted for printed circuits, are facilely prepared by papermaking technique and hot pressing, and are comprised of a fibrous polymer matrix, advantageously an aramide non-woven batt, bonded together with a cured imido prepolymer, and include particulate filler material, advantageously electrically insulating metal oxide particles, distributed therethrough.

Metallizable, essentially isotropic polymeric substrates well adopted

Thick-layer hybrid electronic printed circuits are formed by printing predetermined circuit pattern onto an insulating substrate by deposition of predetermined ink pattern thereupon, advantageously by silk-screening or masking, and then baking said ink circuit pattern, and repeating the deposition/baking steps as required, the subject forming process featuring use of an insulating ink comprising a non-conductive metallic oxide extender, desirably cuprous oxide, which ink is thus either potentially conductive or potentially resistive, and the development of such conductivity or resistivity, after baking, by treating the ink pattern with a reducing agent, desirably a borohydride, as to readily and quantitatively convert said metal oxide into a conducting metal.

Novel thermosetting compositions, including a polyimide/N-vinylpyrrolidone prepolymer, optionally comprising an unsaturated polyester, and an epoxy resin, are well adapted for the molding of a variety of useful shaped articles.

Growing community of inventors

Ternay, France

Robert Cassat