American Air Liquide, Inc.

L'air Liquide, Soci&#xe9;t&#xe9; Anonyme Pour L'etude Et L'exploitation Des Proc&#xe9;d&#xe9;s Georges Claude

Air Liquide America, L.p.

Robert Benesch

Tracey Jacksier

Malik Haouchine

John Kuhn

George D Baker

Eric Coffre

Aurelie Grimberg

Bruce Talbert

George Baker

A purification process has been developed that allows the removal of several different impurities from unsaturated hydrocarbons. The purification process uses various adsorbents and metal oxides or getters to accomplish the purification. The process is capable of removing the following impurities: SO, HO, O, COand CO.

Systems and methods for purifying unsaturated hydrocarbon(s), and compositions resulting therefrom

Articles of manufacture and methods of making and using same concern a container having an internal space and a passivated internal metal surface. The container contains a composition of an acid gas and a balance gas contained within the internal space and in contact with the passivated internal metal surface. The stability of the acid gas concentration over time is enhanced.

Articles of manufacture containing increased stability low concentration gases and methods of making and using the same

Methods of passivating a metal surface are described, the methods comprising the steps of exposing the metal surface to a silicon-containing passivation material, evacuating the metal surface, exposing the treated surface to a gas composition, having a concentration of reactive gas that is greater than an intended reactive gas concentration of gas to be transported by the metal surface, evacuating the metal surface to remove substantially all of the gas composition to enable maintenance of an increased shelf-life, low concentration reactive gas at an intended concentration, and exposing the metal surface to the reactive gas at the intended reactive gas concentration. Manufactured products, high stability fluids, and methods of making same are also described.

Reactive gases with concentrations of increased stability and processes for manufacturing same

Methods of passivating a metal surface are described, the methods comprising the steps of i) exposing the metal surface to a silicon-containing passivation material; ii) evacuating the metal surface; iii) exposing the treated surface to a gas composition having a concentration of reactive gas that is greater than an intended reactive gas concentration of gas to be transported by the metal surface; iv) evacuating the metal surface to remove substantially all of the gas composition to enable maintenance of an increased shelf-life, low concentration reactive gas at an intended concentration; and v) exposing the metal surface to the reactive gas at the intended reactive gas concentration. Manufactured products, high stability fluids, and methods of making same are also described.

Increased stability low concentration gases, products comprising same, and methods of making same

Compositions comprising a reactive gas and a matrix gas are disclosed, as well as articles of manufacture and methods of making the articles. The methods of manufacturing preferably employ zeolites to remove moisture from the reactive gas and from the matrix gas, and then combine the moisture reduced gases either in a container, or prior to filling a container, which has been previously vacuum-baked and passivated. The invention produces stable standard gas compositions having improved shelf-life.

Reduced moisture compositions comprising an acid gas and a matrix gas, articles of manufacture comprising said compositions, and processes for manufacturing same

A filter-less regulator is implemented for use in fluid flow systems that process low concentration reactive gases. The regulator includes an inlet, an outlet and a fluid flow path defined between the inlet and outlet by internal surfaces of the housing. The regulator further includes a pressure regulating section to reduce the pressure of a reactive gas flowing through the regulator between the housing inlet and the housing outlet. The internal surfaces of the housing are formed of a suitable material and the combined area of the internal surfaces is sufficiently sized to facilitate use of the regulator in the system without prior passivation for reactive gases at low concentrations (e.g., in the range of about 10 ppm or lower) while minimizing or substantially preventing significant loss of the reactive gas due to reaction and/or adsorption within the regulator.

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Chicago, IL, United States of America

Robert Benesch