Essilor International (compagnie Generale D'optique)

Essilor International

Essilor of America, Inc.

Robert Alan Valeri

Kimberly Denise Anderson

Ronald A Berzon

John Biteau

Sheila M Tatman

Claudine Biver

Aref Jallouli

Haipeng Zheng

Pierre Fromentin

Sidney Shaw White, Jr

Hoa Thien Dang

Steven Weber

Jean-Marc Padiou

Xu Chen

Hao-Wen Chiu

Mathieu Feuillade

Pascale Tardieu

Noémie Lesartre

Joey Oliveros Obordo

Sidney S White, Jr

Anne Robert

Matthew James Lockwood

Tipparat Lertwattanaseri

Ronald Harmon

Matthew Freeman

Julie S Berzon

Kelly Benjamin

Thanisararat Saleesung

Sheila Tatman

Eric Glen Johnson

Sidney Shaw White Jr

Kimberly Denise Oliver

An ophthalmic lens including a substrate-independent adhesive primer for joining a functional element to a lens substrate. In particular, the ophthalmic lens includes at least one polymerized lens substrate including at least one thermoset monomer, a functional component including at least one thermoplastic layer, a surface of the at least one thermoplastic layer facing the polymerized lens substrate, and a primer coating deposited onto the surface of the at least one thermoplastic film facing the polymerized lens substrate.

Primer for ophthalmic lenses

The present invention relates to a curable coating composition, especially a radiation curable coating composition comprising at least one poly(meth)acrylate compound comprising at least 6 (meth)acrylate groups, at least one unsaturated silane compound, and at least one photoinitiator. Said at least one poly(meth)acrylate compound comprising at least 6 (meth)acrylate groups and said at least one unsaturated silane compound represent at least 95% of the weight of polymerizable compounds present in the composition. Upon radiation-curing, the composition provides an abrasion- and/or scratch-resistant coating.

Curable coating composition

The present invention proposes a polymer composition of manufacturing ophthalmic lens by polymerization of polymerizable composition wherein the shrinkage phenomenon is minimized. The polymerizable composition comprised two different categories of monomers which are able during crosslinking to control and limit said chemical shrinkage. The present invention comprises also ophthalmic lens obtained from said polymer composition using a manufacturing process of casting or additive manufacturing.

Polymer composition and methods using said polymer composition to manufacture ophthalmic lens

Disclosed are UV curable adhesive compositions and methods to adhere polycarbonate substrates containing UV absorbers to glass for use in ophthalmic lenses.

Optical adhesive for glass and polycarbonate

The present invention relates to a heat-curable composition comprising at least one epoxy monomer comprising two or three epoxy groups, which is not a hydrolysis-polymerizable silicon compound, at least one epoxy compound bearing at least one silicon atom having at least one hydrolyzable group directly linked to the silicon atom and at least one epoxy group, and at least one epoxy ring-opening catalyst. The composition comprises at least 50% by weight of compounds having at least one epoxy group, relative to the total weight of polymerizable compounds present in the composition and provides upon pre-curing a tack-free coating that can be removed by treatment with a solution of sodium hydroxide, and upon post-curing a coating that cannot be removed by treatment with a solution of sodium hydroxide.

Heat-curable hybrid epoxy functional composition and transparent heat-cured caustic-resistant coatings prepared therefrom

An ophthalmic article and methods of manufacturing the ophthalmic article are described herein. The ophthalmic article can include a first coating and a second coating. The first coating can include an abrasion resistant coating that includes flexible materials. The abrasion resistant coating can be radiation cured. The second coating can include a sputter-applied anti-reflective (AR) coating. Such an ophthalmic article can have a Bayer value of at or between 1.25 and 2.6, between 1.25 and 2.0 or 1.25 and 1.75; and a hand steel wool value of 3 or less.

UV curable coating compositions for improved abrasion resistance

A method using additive manufacturing technologies and processes to manufacture a three-dimensional ophthalmic lens with a high management level of the homogeneity during the construction of the ophthalmic lens, through a control of two technical characteristics of voxel: the ability to modify their viscosity, and the ability to inter-diffuse together to provide a final homogeneous element. These two technical characteristics are managed by the choice of component(s) used to manufacture each voxel and by the kind of physical and/or chemical treatment apply to each of them.

Additive manufacturing for transparent ophthalmic lens

UV curable coating composition includes a non hydrolyzed epoxy- alkoxy-silane, polyfunctional acrylate and/or epoxy compounds and a cationic and/or free-radical photo-initiator; with polyfunctional acrylate and/or epoxy compounds representing more than 40 weight % of the total dry matter and the composition being without any hydrolyzed epoxy-alkoxy-silane. This composition is coated and cured on an optical substrate.

A heat-curable composition comprises&#x2014;from 25 to 65% by weight of a mixture of epoxy-functional monomers, said mixture consisting of at least one polyfunctional epoxy monomer selected from monomers comprising from 4 to 8 glycidyl groups and/or cycloaliphatic epoxy groups, and at least one bi- or tri-functional epoxy monomer selected from monomers comprising two or three glycidyl groups and/or cycloaliphatic epoxy groups, &#x2014;from 25 to 70% by weight of at least one organic solvent selected from glycol monoethers, &#x2014;from 2.5 to 5% by weight, relative to the total weight of epoxyfunctional monomers (a) and (b), of at least one blocked strong acid catalyst, said heat-curable composition not containing any non-epoxyfunctional monomers, in particular not containing any acrylic, methacrylic or silane monomers.

Heat-curable epoxy functional composition and transparent heat-cured caustic-resistant hard-coatings prepared therefrom

An abrasion resistant photocurable acrylic coating composition that can provide good adhesion to subsequent coatings deposited thereon, and a hard coated article, especially an optical article such as an ophthalmic lens, comprising a substrate coated with a coating obtained from the above abrasion resistant acrylic coating composition providing good subsequent adhesion.

Photocurable acrylic coating compositions having good adhesion properties to a subsequent coating and corresponding coated substrates

Process for obtaining a hard coated article having anti-fouling properties, including, for example, an optical article such as an ophthalmic lens, comprising a substrate coated with a hard coating providing abrasion resistance and hardness and adhesion to the anti-fouling coating, and the article obtained from such process.

Process for obtaining a hard coated article having anti-fouling properties

A method for producing an article which is made of a transparent material and devoid of visible surfacing lines, comprising:

Method for producing an article made of a transparent material devoid of visible surface lines and the thus obtained article

Abrasion-resistant tintable coating

A method and coating used to prepare a photochromically-enabled bifocal ophthalmic lens. The method and equipment includes injection molding a single vision lens, for example, from polycarbonate. The clamp opens vertically and the top insert is exchanged for a bifocal mold having a base curve similar to the single vision lens. The thermoset coating includes compounds from several acrylate classes, and is applied to the single vision lens. The coating may include a photochromic dye. The coating is also formulated to receive a photochromic solution through an imbibition process.

Method for adding a thermoset overmold layer to a lens within a mold

The invention relates to primer coating compositions exhibiting very good adhesion properties on a large variety of substrates, in particular plastic substrates such as ophthalmic lenses made of organic glasses and which also impart good impact resistance properties to the thus coated substrates. The invention also concerns substrates coated with these primer coating compositions as well as a method for making such coated substrates.

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Tampa, FL, United States of America

Robert Alan Valeri