Union Carbide Chemicals & Plastics Technology Corporation

Rickey Epps

David Burns

Craig Norman Schubert

Richard Alan Gregory

Paul Garland

Robert Jerry Hlozek

Eduardo Garcia-Rameau

An improved composition and method for acid gas treatment, comprising an effective amount of tetraethylene glycol dimethyl ether, optionally in combination with other alkyl ethers of alkylene glycols. Utilization of a predominance of tetraethylene glycol dimethyl ether produces significant benefits in carbon dioxide slip in, e.g., ammonia systhesis plants. A solvent based predominantly on tetraethylene glycol dimethyl ether can be used neat or can be added to the existing recirculating solvent stream to increase the concentration of tetraethylene glycol dimethyl ether to a satisfactory level.

Composition and method for acid gas treatment

Absorption solvents for removing mercaptans from gas streams are disclosed. The absorption solvents comprise an alkylether of a polyalkylene glycol, e.g., methoxytriglycol, and a secondary monoalkanolamine, e.g., N-methylethanolamine, as well as optionally other amines, e.g., methyldiethanolamine and diethanolamine. The absorption solvents do not require the presence of iodine for removal of mercaptans. Absorption processes utilizing the solvents are also disclosed.

Absorption of mercaptans

Process for absorption of mercaptans

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Houston, TX, United States of America

Rickey Epps