3m Innovative Properties Company

Exxon Research and Engineering Company

Minnesota Mining and Manufacturing Company

Richard M Minday

Martin Leo Gorbaty

Norman N Li

Gopal H Singhal

Richard M Flynn

Michael G Costello

John G Owens

Daniel R Vitcak

Michael J Parent

Jason M Kehren

Susrut Kesari

Fred E Behr

Julian B Cooley

Paul B Olson

Zhongxing Zhang

Charles F Kolpin

John C Smeltzer

Thomas M Barrett

Paul E Rivers

Larry A Zazzera

Methods of using reactive gases containing a perfluoroketone having 4 to 7 carbon atoms for removing unwanted deposits that build up in a vapor reactor, for etching dielectric and metallic materials in a vapor reactor, and for doping a material in a vapor reactor are described. The perfluoroketones perform as well as or better than the standard perfluorocarbons used in the semiconductor industry but have minimal impact on global warming.

Use of perfluoroketones as vapor reactor cleaning, etching, and doping gases

Fire extinguishing compositions and methods for extinguishing, controlling, or preventing fires are described wherein the extinguishing agent is a fluorinated ketone having up to two hydrogen atoms, alone, or in admixture with a co-extinguishing agent selected from hydrofluorocarbons, hydrochlorofluorocarbons, perfluorocarbons, perfluoropolyethers, hydrofluoroethers, hydrofluoropolyethers, chlorofluorocarbons, bromofluorocarbons, bromochlorofluorocarbons, iodofluorocarbons, hydrobromofluorocarbons, and mixtures thereof.

Use of fluorinated ketones in fire extinguishing compositions

A lubricant composition comprising a perfluoropolyether lubricant and fluorinated ketone solvent is described. The lubricant composition can be applied as a coating to a substrate such as magnetic media. After the coating dries, a thin uniform lubricant film covers the substrate surface. The fluorinated ketone solvent can solubilize a wide range of perfluoropolyether compounds but not potential contaminants such as water and hydrocarbons. Additionally, the solvent has low potential to adversely affect global warming.

Fluorinated ketones as lubricant deposition solvents for magnetic media applications

A method for cleaning a vapor reactor by applying a liquid cleaning agent comprising a fluorinated ketone having about 5 to about 10 carbon atoms and up to two hydrogen atoms is described. The fluorinated ketone has low global warming potential.

Use of fluorinated ketones as wet cleaning agents for vapor reactors and vapor reactor components

A process for preparing fluorochemical compounds, e.g., perfluoroalkanes, perfluoroethers, and perfluoroalkyl tertiary amines, comprises

Process for preparing fluorochemicals

Process for refining hydrocarbon feedstocks comprising contacting a hydrocarbon feedstock with zeolite-containing particles that are free-flowing, discrete, rounded, rigid, frangible, hollow, and opaque. The zeolite-containing particles are essentially completely de-coked upon regeneration, and then retain their catalytic activity even after several cycles of use-regeneration.

Process for catalytic conversion of hydrocarbon feedstock

Novel zeolite-containing particles. The particles are free-flowing, discrete, rounded, rigid, frangible, hollow, and opaque. The shell or wall of each particle is porous to gases and fluids. The particles are useful as catalysts for refining processes. They are essentially completely de-coked upon regeneration, and they retain their catalytic activity even after several cycles of use-regeneration.

Hollow zeolite-containing particles useful as refining catalysts

This invention relates to novel liquid membrane formulations which are water-in-oil emulsions wherein the oil phase comprises a sulfonated polymer having a backbone which is substantially nonaromatic, for example, less than 10 mole % aromatic, and uses thereof in high temperature liquid membrane processes. The emulsions are useful in liquid membrane water treating processes, especially in water treating processes which are desirably run at high temperatures. In the most preferred embodiment, these compositions are used in a liquid membrane sour water treating process wherein a waste water stream containing ammonium sulfide is contacted with a liquid membrane emulsion, i.e. the emulsions of the instant invention, at conditions whereby ammonia permeates through the external phase of the emulsion into an acidic internal phase wherein it is converted to a nonpermeable form, e.g. ammonium ion, while H.sub.2 S is continuously stripped out of the waste water solution by means of an inert gas, e.g. steam. Processes of this sort are most effectivey carried out at temperatures greater than 80.degree. C. wherein the emulsions of the instant invention have excellent stability.

Sour water treating process utilizing liquid membranes having a

The instant invention relates to novel liquid membrane formulations, i.e., emulsions, which comprise an aqueous interior phase and a water-immiscible exterior phase; said water-immiscible exterior phase comprising an ethylene vinyl acetate copolymer and a solvent for this polymer. These compositions may additionally contain a water insoluble surfactant to stabilize the emulsions. In the most preferred embodiment, the aqueous interior phase comprises a strong acid, for example from about 1 to 10 percent by weight sulfuric acid. These emulsions are useful in liquid membrane processes for the separation of dissolved components from aqueous solution. Emulsions of the instant invention are characterized as showing very low swelling when contacted with aqueous solutions, especially at higher temperatures and thus are especially effective for use in the treatment of sour water feed streams by the liquid membrane technique.

Novel liquid membrane formulations and uses thereof

This invention relates to novel liquid membrane formulations which are water-in-oil emulsions wherein the oil phase comprises a sulfonated polymer having a backbone which is substantially nonaromatic, for example, less than 10 mole % aromatic, and uses thereof in high temperature liquid membrane processes. The emulsions are useful in liquid membrane water treating processes, especially in water treating processes which are desirably run at high temperatures. In the most preferred embodiment, these compositions are used in a liquid membrane sour water treating process wherein a waste water stream containing ammonium sulfide is contacted with a liquid membrane emulsion, i.e., the emulsions of the instant invention, at conditions whereby ammonia permeates through the external phase of the emulsion into an acidic internal phase wherein it is converted to a nonpermeable form, e.g., ammonium ion, while H.sub.2 S is continuously stripped out of the waste water solution by means of an inert gas, e.g., steam. Processes of this sort are most effectively carried out at temperatures greater than 80.degree.C. wherein the emulsions of the instant invention have excellent stability.

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Stillwater, MN, United States of America

Richard M Minday