Amoco Corporation

Other

Richard Layton

Paul D Frayer

Paul J Huspeni

Markus Matzner

James W Cleary

Brian A Stern

This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (IV). ##STR1## and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the 'Description of the Invention.' The instant copolyesters display orientation in the molten state, good fiber ratings and high strength; they have melting points in the range of from about 340.degree. to about 400.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of over 240.degree. C. up to about 280.degree. C. and higher, when measured under a load of 264 psi. When blended, certain properties are improved, particularly they are easier to melt fabricate, have a decreased tendency to blister and increased strength. These polymers and blends may be used advantageously in ovenware, electronic components, electrical equipment, and other end uses requiring high temperatures.

Heat resistant polymers and blends of hydroquinone poly

Blends of liquid crystalline polymers of hydroquinone

This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (IV). ##STR1## and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the 'Description of the Invention.' The instant copolyesters display orientation in the molten state, good fiber ratings and high strength. Advantageously, the polymers of the present invention display a significant improvement in viscosity and moldability of the neat polymer. The polymers have excellent mechanical and surface properties including blister resistance, strength, toughness, and ability to vapor phase solder, and form strong fibers while still maintaining a high heat distortion temperature. They have melting points in the range of from about 250.degree. to about 360.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of up to 240.degree. C., when measured under a load of 264 psi. The polymers may be blended to tailor properties. These polymers and blends may be used advantageously in producing fibers and in electrical equipment, electronic components and other end uses requiring moderately high temperatures.

High strength polymers and blends of hydroquinone

High strength polymer of hydroquinone poly(iso-terephthalate) containing

A molded article of permanent ovenware comprising (A) 35-85% by weight of a wholly aromatic polyester resin; (B) 15-65% by weight of a specifically defined talc containing a minimum amount of materials decomposable at elevated temperatures; and (C) 0-20% titanium dioxide, wherein the wholly aromatic polyester resin (A) is a blend comprising a first resin based on repeating units of hydroquinone, isophthalic acid (or mixtures of iso- and terephthalic acids), and para-hydroxybenzoic acid, and a second resin based on repeating units of biphenol, isophthalic acid, terephthalic acid and para-hydroxybenzoic acid. The ovenware shows excellent resistance to blistering, bubbling and cracking during molding and oven use.

Plastic ovenware compositions

A high modulus, high strength melt processable copolyester consisting essentially of recurring units (I), (II), (III) and (IV): ##STR1## wherein said copolyester has a melting point in the range of from about 340.degree. C. to 400.degree. C., a crystallization temperature of from about 300.degree. C.-340.degree. C., and a crystallization rate of at least 1,000 counts/minute.

Hydroquinone poly(iso-terephthalates) containing residues of

Disclosed are novel blends of fully aromatic copolyesters which comprise (a) 1-19 parts by weight of a polyester comprising recurring moieties of dihydroxybenzene, nonvicinal benzene dicarboxylate, para oxybenzoate to (b) 1 part by weight of a polyester comprising recurring moieties of diphenol, nonvicinal benzene dicarboxylate, para oxybenzoate; wherein the polyester (a) has a melting point in the range of about 340 C. to 400 C., a crystallization temperature of from about 300-340 C., and a crystallization rate of at least 1,000 counter per minute. The blends display improved surface properties, particularly improved blistering resistance.

Polymer compositions having improved molding characteristics

Wholly aromatic polyester of isophthalic acid, terephthalic acid,

This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (V). ##STR1## and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the 'Description of the Invention'. The instant copolyesters display orientation in the molten state, good fiber ratings and high strength; they have melting points in the range of from about 340.degree. to about 400.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of over 240.degree. C. up to about 280.degree. C. and higher, when measured under a load of 264 psi. When blended, certain properties are improved, particularly they are easier to melt fabricate, have a decreased tendency to blister and increased strength. These polymers and blends may be used advantageously in ovenware, electronic components, electrical equipment, and other end uses requiring high temperatures.

High modulus, high strength melt-processible polyester of hydroquinone

Wholly aromatic polyesters based on isophthalic acid, terephthalic acid, p-hydroxybenzoic acid, hydroquinone and an arylene diol, e.g. 4,4'-biphenol are described. The materials displayed are excellent overall combination of mechanical and thermal properties. Their melting points and heat distortion temperatures (264 psi) are at least about 260.degree. C. and 260.degree. C., respectively. These novel polymers can be melt-fabricated using standard injection molding, extrusion, and melt spinning techniques and yield fabricated articles with good surface characteristics.

Wholly aromatic polyesters comprising isophthalic acid, terephthalic

Process for preparing polyarylates comprising the steps of (a) prepolymerizing a diester of Bisphenol-A with at least one aromatic dicarboxylic acid to form a prepolymer having a melting point of at least about 200.degree. C. and being fluid at the polymerization temperature; followed by (b) polycondensing said prepolymer under agitation until it is substantially transformed into a powdery solid; maintaining said agitation to keep the powdery solid in a polydispersed solid state; and continuing the polymerization below the agglomeration temperature of the polymerizing solid, until the desired molecular weight is reached.

Process for preparing bisphenol polyarylates

This invention relates to the preparation of wholly aromatic polyesters from monomers having a total ash content of no more than 50 ppm and a total potassium content of no more than 20 ppm. These polyesters have good color and good thermal stability and are essentially free of char material which can lead to unacceptable molded and extruded articles.

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Augusta, GA, United States of America

Richard Layton