E.i. Dupont De Nemours and Company

Richard James Arhart

David M Dean

Geraldine Marie Lenges

Richard T Chou

Karlheinz Hausmann

George Wyatt Prejean

Arthur Nersasian

Diego Boeri

Geraldine M Lenges

The present invention is a film obtained from a blend of chemically distinguishable copolymers, wherein the film has a light transmission of at least 85%, and/or a haze of less than 6%, and wherein the blend comprises a component copolymer has a secant modulus of less than 15,000 when cast independently into a film.

Transparent ionomeric films from blends of ionomeric copolymers

The present invention is photovoltaic (solar) cell module comprising a multilayer laminate ionomer film as an encapsulant layer wherein the laminate has a light transmission of at least 85%, and or a haze of less than 6%, and wherein the laminate has a modulus of less than 15,000 psi.

Multilayer ionomer films for use as encapsulant layers for photovoltaic cell modules

A flame retardant, halogen-free polymer composition that is a blend of: (1) a polyolefin selected from (a) EVA containing 25-90% by weight ethylene and 10-75% by weight vinyl acetate, (b) LLDPE, (c) LDPE, (d) VLDPE, (e) HDPE, or mixtures thereof; (2) a coupling agent made from (f) about 10 to about 50% by weight of a copolymer of ethylene and about 1% by weight to about 15% by weight functional comonomer and (g) about 50% by weight to about 90% by weight of an ethylene-based polymer; and (3) an inorganic flame retardant filler.

Flame retardant, halogen-free compositions

The present invention relates a process for manufacturing polymer coated wire and cable and an electrically conductive wire having a metal core and an outer electrically-insulative, polymer coating capable of withstanding temperatures as high as 150&deg; C., wherein the polymer composition contains polyphenylene sulfide, a polymeric grafting agent and an ethylene copolymer. The polymeric grafting agent is a copolymer of at least about 50% by weight ethylene, about 0.5% to about 15% by weight of a reactive comonomer (e.g. unsaturated epoxide of 4-11 carbon atoms) and the ethylene copolymer comprises at least about 50% by weight ethylene and about 1% to about 35% by weight of an acid-containing unsaturated mono-carboxylic acid comonomer. The molar ratio of the reactive comonomer in the polymeric grafting agent to the unsaturated mono-carboxylic acid comonomer of the ethylene copolymer is to be maintained between 1.0 and 5.5 in order to achieve the desired polyphenylene sulfide wire coating properties.

Process for coating a wire or cable with polyphenylene sulfide alloy and resulting coated wire

The present invention relates to high performance wire and cable compositions and to hot melt adhesives containing a silyl-grafted ethylene copolymer having particularly low levels of glycidyl acrylate monomer. The preferred epoxy glycidyl methacrylate copolymerized into the polymer backbone provides a graft site for the aminosilane. Subsequent moisture crosslinking at the silyl site of the thermally stable graft copolymer provides compositions with attractive physical properties for wire and cable semicons, insulation, and jackets, as well as hot melt adhesives. The preferred aminosilane is N-cyclohexylaminopropyl trimethoxysilane.

Moisture curable, melt processible graft ethylene copolymers

The present invention relates an electrically conductive wire having a metal core and an outer electrically-insulative, polymer coating wherein the polymer composition contains polyphenylene sulfide, a polymeric grafting agent and an ethylene copolymer. The polymeric grafting agent is a copolymer of at least about 50% by weight ethylene, about 0.5% to about 15% by weight of a reactive comonomer selected from the group consisting of: (i) an unsaturated epoxide of 4-11 carbon atoms, (ii) an unsaturated isocyanate of 2-11 carbon atoms, (iii) an unsaturated alkoxy silane and/or unsaturated alkyl silane wherein the alkoxy or alkyl group is from 1-12 carbon atoms, and (iv) an oxazoline; and about 0 to about 49% by weight of a third optional comonomer selected from at least one of an alkyl acrylate, alkyl methacrylate, vinyl ether, carbon monoxide, and sulfur dioxide, where the alkyl and ether groups are of 1-12 carbon atoms. The ethylene copolymer comprises at least about 50% by weight ethylene, about 1% to about 35% by weight of an acid-containing unsaturated mono-carboxylic acid, and about 0 to about 49% by weight of a moiety selected from at least one of alkyl acrylate, alkyl methacrylate, vinyl ether, carbon monoxide, and sulfur dioxide, and further wherein the acid groups are neutralized from 0-100% by a metal ion. Such wire meets SAE J1678 specifications at 125&deg; C. or higher at a thickness of said polymer of less than 12 mils.

Polyphenylene sulfide alloy coated wire

The present invention relates to polymer compositions containing polyphenylene sulfide, a polymeric grafting agent and an ethylene copolymer. The polymeric grafting agent is a copolymer of at least about 50% by weight ethylene, about 0.5% to about 15% by weight of a first reactive moiety selected from the group consisting of: (i) an unsaturated epoxide of 4-11 carbon atoms, (ii) an unsaturated isocyanate of 2-11 carbon atoms, (iii) an alkoxy or alkyl silane wherein the alkyl group is from 1-12 carbon atoms, and (iv) an oxazoline; and about 0 to about 49% by weight of a second moiety selected from at least one of an alkyl acrylate, alkyl methacrylate, vinyl ether, carbon monoxide, and sulfur dioxide, where the alkyl and ether groups are of 1-12 carbon atoms. The ethylene copolymer comprises about 1% to about 20% by weight of an ethylene copolymer which comprises at least about 50% by weight ethylene, about 1% to about 35% by weight of an acid-containing unsaturated mono-carboxylic acid, and about 0 to about 49% by weight of a moiety selected from at least one of alkyl acrylate, alkyl methacrylate, vinyl ether, carbon monoxide, and sulfur dioxide, and further wherein the acid groups are neutralized from 0-100% by a metal ion. The molar ratio of polymeric grafting agent to ethylene copolymer preferably ranges from about 1.0 to about 5.5.

Polyphenylene sulfide alloy composition

The present invention relates to blends of copolymers having a certain percentage of vinyl acetate monomer with a terpolymer having a certain percentage of vinyl acetate wherein the composition provides heat and flame resistant properties to wires and cable or other manufactured goods prepared from such compositions. The preferred blends comprise or consist essentially of alkylene-vinyl acetate copolymers blended with alkylene/vinyl acetate/CO terpolymers selected from, for example, ethylene-vinyl acetate and ethylene/vinyl acetate/carbon monoxide. The blends are prepared by combining the ingredients with other excipients selected from aluminum trihydrate, carbon black, stearic acid, tri(2-methoxyethoxy) vinyl silane, polymeric hindered phenol, dilaurylthiopropionate, N,N'-m-phenylenedimalemide, and .alpha.,.alpha.'-bis (t-butylperoxy)diisopropylbenzene. The blends of the invention actually simulate a high vinyl acetate content EVA.

Ethylene vinyl acetate blends

Copolymers of vinylidene fluoride with at least one other fluorinated- ethylenically unsaturated monomer are press-cured at about 163.degree.-204.degree. C. by crosslinking with an aromatic polyhydroxy compound in the presence of an accelerator in a weakly basic system, at least a portion of the polyhydroxy compound being blocked by conversion to acetal or thioacetal groups. At the press-cure temperature some of the acetal or thioacetal groups are decomposed and the free hydroxyl groups are reformed, thus providing crosslinking capability. The remainder of acetal or thioacetal groups are decomposed during post-cure oven heating at a higher temperature, and under those conditions copolymer vulcanization is completed. Press-cured compositions of this invention have excellent hot tensile elongation, which permits easy demoldability; and very good recyclability, which eliminates or reduces fluoropolymer waste. The compositions of this invention also have excellent mold flow properties at press-cure temperature.

Press-curable fluoropolymer compositions and process

Adhesive compositions of acrylic or methacrylic monomers, chlorosulfonated polyethylene, and polymerization initiator of increased shelf stability but fast set up time, containing 2,6-di-t-butyl-4-methylphenol.

Growing community of inventors

Wilmington, DE, United States of America

Richard James Arhart