Basf Se Corporation

The Dow Chemical Company

Basf Corporation

Dow Global Technolgoies LLC

Richard Jacubinas

Joaquim Henrique Teles

Kai Gumlich

Philip Kampe

Christian Bartosch

Ulrich Mueller

Peter Bassler

Wolfgang Friedrich Ruettinger

Meinolf Weidenbach

Ulrich Müller

Andrei-Nicolae Parvulescu

Hans-Georg Goebbel

Markus Weber

Dominic Riedel

Gerhard Cox

Goetz-Peter Schindler

Götz-Peter Schindler

Nicolas Vautravers

Daniel Urbanczyk

Natalia Trukhan

Michael Breen

Bianca Seelig

Peter Resch

Werner J Witzl

Hans-Georg Göbbel

Saeed Alerasool

Thomas Grassler

Peter Baβler

Bernd Hinrichsen

Soo Yin Chin

Martin Cogswell

Thomas Graßler

Peter BAßler

A continuous process for the preparation of propylene oxide, comprising (i) providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, water, optionally propane, and at least one dissolved potassium salt of a phosphorus oxyacid wherein the molar ratio of potassium relative to phosphorus in the at least one potassium salt of a phosphorus oxyacid is in the range of from 0.6 to 1.4; (ii) passing the liquid feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MWW comprising zinc, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation reactor, obtaining a reaction mixture comprising propylene oxide, acetonitrile, water, the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane; (iii) removing an effluent stream from the epoxidation reactor, the effluent stream comprising propylene oxide, acetonitrile, water, at least a portion of the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane.

Process for preparing propylene oxide

A tin containing zeolitic material having an MWW-type framework structure (Sn-MWW), having a tin content of at most 2 weight-%, calculated as element and based on the weight of the Sn-MWW, and having an X-ray diffraction pattern comprising peaks at 2 theta diffraction angles of (6.6&#xb1;0.1)&#xb0;, (7.1&#xb1;0.1)&#xb0;, and (7.9&#xb1;0.1)&#xb0;.

Tin-containing zeolitic material having an MWW-type framework structure

Provided are methods of making dehydrogenation catalyst supports containing bayerite and silica. Silica-stabilized alumina powder, prepared by spray drying of bayerite powder, precipitating silica in a bayerite slurry with an acid, or impregnation or co-extrusion of bayerite with sodium silicate solution was found to be a superior catalyst support precursor. Catalysts prepared with these silica containing support materials have higher hydrothermal stability than current CATOFIN&#xae; catalysts. Also provided is a dehydrogenation catalyst comprising CrO, an alkali metal oxide, SiOand AlO, and methods of using said catalyst to make an olefin and/or dehydrogenate a dehydrogenatable hydrocarbon.

Chromia alumina catalysts for alkane dehydrogenation

A process for producing propylene oxide comprising reacting propene with hydrogen peroxide in the presence of a catalyst to give a mixture (G1) comprising propylene oxide, unreacted propene, and oxygen; separating propylene oxide from mixture (G1) to give a mixture (GII) comprising propene and oxygen; and adding hydrogen to mixture (GII) and reducing the oxygen comprised in mixture (GII) at least partially by reaction with hydrogen in the presence of a catalyst comprising copper in elemental and/or oxidic form on a support, wherein copper is present on the support in an amount of 30 to 80 wt.-% based on the whole catalyst and calculated as CuO.

Process for producing propylene oxide

Disclosed are dehydrogenation catalyst composites and methods of making the dehydrogenation catalyst composites. The dehydrogenation catalyst composites contain alumina, lithium oxide, alkaline earth metal oxide, chromium oxide, and sodium oxide. Also disclosed are methods of dehydrogenating a dehydrogenatable hydrocarbon involving contacting the dehydrogenatable hydrocarbon with a dehydrogenation catalyst composite containing alumina, lithium oxide, alkaline earth metal oxide, chromium oxide, and sodium oxide to provide a dehydrogenated hydrocarbon, such as an olefin.

Alkane dehydrogenation catalysts

A continuous process for the production of propylene oxide comprising reacting propene with hydrogen peroxide in methanolic solution in the presence of a titanium silicalite-1 catalyst to obtain propylene oxide, wherein a reaction feed comprising propene, methanol and hydrogen peroxide is introduced into a reactor, said reaction feed containing potassium cations and phosphorus in the form of anions of at least one phosphorus oxyacid.

Process for the production of propylene oxide

A method for separating acetonitrile from water, comprising (i) providing a stream Scontaining at least 95 wt.-%, based on the total weight of S, acetonitrile and water, wherein the weight ratio of acetonitrile: water is greater than 1; (ii) adding a stream P, comprising at least 95 wt.-% C3, based on the total weight of stream P, to Sto obtain a mixed stream S, C3 being propene optionally admixed with propane with a minimum weight ratio of propene: propane of 7:3; (iii) subjecting Sto a temperature of 92&#xb0; C. at most and a pressure of at least 10 bar, obtaining a first liquid phase Lessentially consisting of C3, acetonitrile, and water, and a second liquid phase Lessentially consisting of water and acetonitrile wherein the weight ratio of acetonitrile: water in Lis less than 1; (iv) separating Lfrom L

Method for the separation of acetonitrile from water

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Bloomfield, NJ, United States of America

Richard Jacubinas