Westinghouse Electric Corporation

Westinghouse Electric Company LLC

Richard J Jacko

William A Byers

Warren R Junker

William G Clark, Jr

John P Foster

Jason P Mazzoccoli

Lee W Burtner

George C Economy

Fredric W Pement

Edward J Silva

Deborah J Buckley

Alfred W Klein

Rachel L Devito

William C Clark, Jr

James A Begley

The present invention relates to a pre-core hot functional testing (HFT) preconditioning process, which includes the introduction of chemical additives, e.g., zinc, into coolant water that circulates through the primary system of a new nuclear power plant, at various temperatures. The chemical additives contact the primary system surfaces, which results in the formation of a protective zinc-containing oxide film on the fresh surfaces to control corrosion release and deposition during subsequent normal operation of the nuclear power plant. The method includes a series of three chemistry phases to optimize the passivation process: 1) an alkaline-reducing phase, 2) an acid-reducing phase and 3) an acid-oxidizing phase.

Chemical process for primary system material passivation during hot functional testing of nuclear power plants

A high temperature-high pressure electrode for electrochemical potential measurement has a high temperature probe comprising an oxidized zirconium alloy tube member having an electroconductive core which includes a liquid electrolyte and a porous plug held in place by an oxidized zirconium alloy tube and end plug with an axial bore extending therethrough. The electroconductive core can comprise a liquid electrolyte of soaked zirconia sand and a second porous plug. In another embodiment, the zirconia sand is replaced by a surface oxidized zirconium alloy rod with grooves which extend between ends for containment of the liquid electrolyte. This embodiment also contains a second porous plug. In a modification of the latter embodiment, there is a bore in the proximal end of the surface oxidized rod which communicates with the grooves to provide electrical continuity. A Teflon sleeve forms an annular seal between the proximal end of the oxidized rod and the oxidized tube.

Rugged electrode for electrochemical measurements at high temperatures

A robotic sampling device (32) for cutting part of a tube wall (12) for sampling, containing a cutting head (36), a retrieval assembly (38) and a drive mechanism (40), is used to cut a window or hole (60) in the tube wall (12) and retrieve the tube wall sample (56), where the sample can be mounted onto a separate tube for testing the physical properties of the cut wall portion, and where a video probe (62) and the like can be passed through the window (60) to monitor conditions near the support plates (14) and tube sheets (16).

Remotely operated diagnostic tube sampling device and method of sampling

A method for monitoring the environment of a vessel provides a liquid (18) which may contain particles (20) in a vessel having containment walls (12), where a hollow member (26) such as a thin tube is inserted into the liquid near the containment walls, and the hollow member contains in it a robotic device (34), which can travel within the hollow member and which can emit and receive ultrasonic waves and electromagnetic fields, where both of the ultrasonic waves and electric fields can pass through the hollow member (26) to the containment walls (12), where the device: emits and receives low frequency ultrasonic waves to and from the containment walls (12) and high frequency ultrasonic waves to and from any particles (20), and emits electromagnetic fields to the containment walls (12) or their combination, where absorptions and reflections from the hollow member walls and the containment walls, and any particles present are measured and any current generated in the hollow member walls and the containment wall by the electromagnetic fields are measured, and then any differences are measured to determine flaws (24) in the hollow member and containment walls, and properties of any particles (20) in suspension.

Method and apparatus for monitoring the environment of a vessel

Both an improved method and apparatus for determining, on an accelerated basis, the susceptibility of a nickel-based alloy to suffer stress corrosion cracking within a steam generator environment is disclosed herein. The method generally comprises the steps of subjecting a mechanically stressed specimen of the alloy to a mixture of steam and hydrogen at a temperature of between about 365.degree. C. to 435.degree. C., wherein the partial steam pressure is between about 10.4 MPa to 30.4 MPa, and the partial hydrogen pressure is between about 32 kPa to 500 kPa. The improved testing apparatus of the invention generally comprises a vessel for containing a stressed specimen and a pressurized atmosphere formed of steam and hydrogen, and an inlet cell for injecting a selected amount of hydrogen into the pressurized atmosphere of the vessel which includes a diffusion membrane which is permeable to hydrogen but impermeable to the remainder of the pressurized atmosphere. The inlet cell has a tubular housing having a wall formed from a thin layer of hydrogen permeable palladium-silver alloy. The tubular housing contains a gas permeable sponge formed by sintered particles of stainless steel to prevent the thin layer of palladium-silver alloy used in the hydrogen diffusion membrane from imploding in response to the pressure within the vessel.

Apparatus for conducting accelerated corrosion testing of nickel alloys

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Forest Hills, PA, United States of America

Richard J Jacko