Exxonmobil Chemical Patents Inc.

Dow Global Technolgoies LLC

Exxonmobil Research and Engineering Company

Exxon Research and Engineering Company

Richard Edwards Walter

James Harding Beech, Jr

Matthew T Pretz

Don F Shaw

James Richardson Lattner

James H Beech

Keith Holroyd Kuechler

Stephen Neil Vaughn

Shun Chong Fung

Kenneth Ray Clem

Peter Loezos

Marcel Johannes Janssen

Nicholas Charles Nahas

Arun K Sharma

Dean C Draemel

Madhusudhan Kodam

Michael Siskin

Teng Xu

Luc R M Martens

Nicolas P Coute

Cor F Van Egmond

Marcel J G Janssen

Jeffrey Scott Smith

Luc Roger Marc Martens

Todd R Steffens

George D Cody

Mark William Stewart

Brian A Cunningham

Glen Edward Phillips

Donald F Shaw

Liwei Li

Rutton D Patel

Fermin Alejandro Sandoval

Henry A Wolf

Gerald V Storch, Jr

E Nicholas Jones

Linda Hofmann

Neil Vaughn Stephen

Bruce J Artuso

Peter N Loezos

Mark Stewart

A catalyst regenerator for combusting carbonaceous deposits from a catalyst comprising a first chamber which comprises a catalyst inlet for feeding spent catalyst with carbonaceous deposits to said first chamber, a supplemental fuel gas distributor, and a distributor for an oxygen containing gas for distributing oxygen containing gas into said first chamber to contact said spent catalyst and combust carbonaceous deposits and supplemental fuel which further deactivates the spent catalyst and generates flue gas; a riser section extending from said first chamber for transporting the spent catalyst and the flue gas, the riser section comprising an outer wall, at least one slot in the outer wall, and a riser termination device which comprises a substantially internally flat cover plate, at least one arm extending from the cover plate, wherein the arm extends about the slot from the outer wall, the arm comprising an outer shell that encloses the arm and wherein no internal portion of the cover plate extends above an upper surface of the outer shell of the at least one arm is provided. Further provided is a riser termination device.

Catalyst regenerator and a riser terminator used therein

A cyclonic reactor vessel comprising: a primary cyclonic separation device disposed within the shell and having an outlet; a plurality of secondary cyclones, said secondary cyclones being disposed within the shell, and each of said secondary cyclones having a body, an inlet and an outlet; wherein the outlet of the primary cyclonic separation device is connected to the inlet of at least one secondary cyclone; a first plenum having a skirt and a floor forming a sealed annular chamber within the shell; a second plenum having a smaller volume than a volume of the first plenum; and a secondary cyclone support system minimizing or eliminating mechanical thermal stresses; and wherein the outlets of the plurality of secondary cyclones are fluidly connected to the second plenum is provided.

Cyclonic reactor vessel having a low residence time plenum

A fluidized fuel gas combustor system for a catalytic dehydrogenation process comprising a vessel having a lower portion and an upper portion; a plurality of air injection diffusers located in the lower portion of the vessel; a plurality of fuel gas injection diffusers located on fuel gas distributors disposed in the vessel and spaced apart from and above a plurality of air injection diffusers, wherein the fuel gas diffusers are placed in a manner to maximize even mass distribution of a fuel gas injected through the fuel gas diffusers in the vessel, wherein each fuel distributor comprises a tube having a plurality of fuel gas injection diffusers; and one or more grid assemblies disposed in the vessel spaced above the fuel gas distributors is provided.

Fluidized fuel gas combustor system for a catalytic dehydrogenation process

A catalyst regenerator for combusting carbonaceous deposits from a catalyst comprising a first chamber which comprises a catalyst inlet for feeding spent catalyst with carbonaceous deposits to the first chamber, a supplemental fuel gas distributor, and a distributor for distributing oxygen containing gas into the first chamber; a riser section extending from the first chamber for transporting the spent catalyst and the flue gas, the riser section comprising an outer wall, at least one slot in the outer wall, and a riser termination device which comprises a substantially internally flat cover plate, at least one arm extending from the cover plate, wherein the arm extends about the slot from the outer wall, the arm comprising an outer shell that encloses the arm and wherein no internal portion of the cover plate extends above an upper surface of the outer shell of the at least one arm is provided.

Embodiments include a reactor and feed distribution assembly. The reactor and feed distribution assembly can include a reactor vessel, a gaseous feed conduit, a catalyst feed conduit, a catalyst feed conduit housing, and a catalyst backflow diverter.

Reactor and feed distribution assembly

This invention relates to a method for removing fouling from a heat transfer surface, such as a heat exchanger. The method involves conducting a vapor containing a scouring material to the heat transfer surface and contacting the scouring material with the foulant, the heat transfer surface, or both. Scouring material and removed foulant can be recovered and conducted away.

Method of recovering heat transfer in reactor and regenerator effluent coolers

A gas-solids reaction system is provided for improving product recovery in a multiple reactor reaction system. The solids of the product gas-solids flows from the multiple reactors are separated out in a separation vessel having a baffled transition zone. Additional product vapor is stripped from the solids as the solids pass through the baffled transition zone. The solids are then returned to the multiple reactors.

Product recovery in gas-solids reactors

A gas-solids reaction system with termination devices to connect a riser with one or more separation devices. The termination devices have a radius of curvature that is at least 1.0 times as great as the diameter of the conduit forming the termination device. The termination devices can be openly or closely coupled to the separation devices.

Riser termination devices for reduced catalyst attrition and losses

The present invention provides a method for adding heat to a reactor system used to convert oxygenates to olefin, in which supplemental heat is added with a heating fuel, e.g., a torch oil, having low autoignition temperature, low sulfur, and low nitrogen content.

Method for adding heat to a reactor system used to convert oxygenates to olefins

A multi-stage gas-solids separator having at least 4 stages is configured so that the penultimate stage of separators is operated in an underflow condition. The underflow from the penultimate stage is used as the input flow for the final stage of separators. The multi-stage separator is preferably composed of cyclone separators, with the final two stages of separators housed in external disengaging vessels.

Gas-solids separation device and method

This invention provides processes for transporting catalyst, preferably in an oxygenate to olefins reaction system. In one embodiment, an oxygenate contacts molecular sieve catalyst particles in a reactor under conditions effective to form an effluent stream comprising light olefins and forming coked catalyst particles. At least a portion of the coked catalyst particles are transported from the reactor or a device associated therewith to a catalyst regenerator through a conduit in a fluidized manner with a fluidizing medium comprising air and steam. At least a portion of the coked catalyst particles are regenerated in the catalyst regenerator to form regenerated catalyst particles, which are ultimately directed back to the reactor.

Processes for lifting spent catalyst into a regenerator in an oxygenate to olefins reaction system

This invention relates to efficiently regenerating catalyst particles by minimizing the formation of localized 'hot spots' and 'cold spots' in a regeneration zone. In one embodiment, the invention includes mixing spent catalyst from a reactor and cold catalyst from a catalyst cooler in a mixing zone and directing the mixed catalyst to the regeneration zone in a fluidized manner with a fluidizing medium. In the regeneration zone, the mixed catalyst contacts an oxygen-containing regeneration medium under conditions effective to regenerate the spent catalyst contained therein.

Controlling temperature in catalyst regenerators

The invention is directed to methods of shutting down reaction systems. The reaction systems are those that use catalysts that comprise molecular sieves, particularly metalloaluminophosphate molecular sieves, especially metalloaluminophosphate molecular sieves which are susceptible to loss of catalytic activity due to contact with water molecules. The methods provide appropriate mechanisms of stopping feed to the reactor and unloading catalyst to protect against loss of catalytic activity that can occur due to contact with water molecules.

Method of shutting down a reaction system

The invention is directed to methods of starting up reaction systems. The reaction systems are those that use catalysts that comprise molecular sieves, particularly metalloaluminophosphate molecular sieves, especially metalloaluminophosphate molecular sieves which are susceptible to loss of catalytic activity due to contact with water molecules. The methods provide appropriate mechanisms of heating and loading the activated molecular sieves to protect against loss of catalytic activity that can occur due to contact with water molecules.

Method of starting up a reaction system

The invention is directed to methods of transfering catalyst particles into and within reaction systems. The reaction systems are those that use catalysts that comprise molecular sieves, particularly metalloaluminophosphate molecular sieves, especially metalloaluminophosphate molecular sieves which are susceptible to loss of catalytic activity due to contact with water molecules. The transfer methods provide appropriate mechanisms for transporting catalyst into and within a reactor to protect against loss of catalytic activity that can occur due to contact with water molecules.

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Long Valley, NJ, United States of America

Richard Edwards Walter