Arthur D. Little, Inc.

Mcneil Ab

Hasbro Industries, Inc.

Seal Incorporated

Universal Optical Co., Ltd.

Empire Enterprises, Inc.

Richard E Merrill

Arthur A Massucco

Irving J Arons

Robert E Eller

Theodore H Krueger

George E Pickering

Harold Grossman

Paul B Monaghan

E Joseph Stilwell

E Joseph Stillwell

Arthur P Drennan

A tamper-resistant vessel which contains a liquid is provided with a non-adherent multi-walled construction having, in one embodiment, at least two adjacent non-adherent layers for providing a void in between to enable tamper indication by discoloration indicative of gross spoilage. In one embodiment, the container or vessel has an opaque inner wall and a closely spaced transparent outer wall, with a void in between. Puncture from the outside through the two walls provides seepage of the interiorly-carried liquid between the multiple walls to provide the look of spoilage. In a second embodiment, a multi-wall structure is utilized in which all walls are transparent or semi-transparent, and in which a hydrophilic and/or dissolvable intermediate wall is provided between the inner and outer walls, with the intermediate wall containing minute particles of a water-soluble dye, such that when the container is punctured from the outside, liquid from within the container penetrates and works either in a void between the walls or through the intermediate wall to activate the dye particles, thereby to provide the look of spoilage through dye solvation, color development, and consequent bleeding. The interior wall or walls of the container are made of either flexible or fragible material, which material does not come back to its original rest position vis a vis the outer heavier wall upon penetration of the container, which makes it difficult to gauge the distance at which sealing adhesive is to be applied, thereby to thwart effort to conceal the tampering. Labeling for the subject bottles is preferably transparent so that the spoilage or mottling effect can be easily viewed through the label.

Multi-walled tamper-proof container and method for enhancing tamper

A tamper-resistant vessel which contains a liquid is provided with a non-adherent multi-walled construction having, in one embodiment, at least two adjacent non-adherent layers for providing a void in between to enable tamper indication by discoloration indicative of gross spoliage. In one embodiment, the container or vessel has an opaque inner wall and a closely spaced transparent outer wall, with a void in between. Puncture from the outside through the two walls provides seepage of the interiorly-carried liquid between the multiple walls to provide the look of spoilage. In a second embodiment, a multi-wall structure is utilized in which all walls are transparent or semi-transparent, and in which a hydrophilic and/or dissolvable intermediate wall is provided between the inner and outer walls, with the intermediate wall containing minute particles of a water-soluble dye, such that when the container is punctured from the outside, liquid from within the container penetrates and works either in a void between the walls or through the intermediate wall to activate the dye particles, thereby to provide the look of spoilage through dye solvation, color development, and consequent bleeding. The interior wall or walls of the container are made of either flexible or frangible material, which material does not come back to its original rest position vis a vis the outer heavier wall upon penetration of the container, which makes it difficult to gauge the distance at which sealing adhesive is to be applied, thereby to thwart efforts to conceal the tampering. Labeling for the subject bottles is preferably transparent so that the spoilage or mottling effect can be easily viewed through the label.

A 'cold-processed' thermoset plastic pencil lead is produced by extruding a composition formed by blending a mixture of a marking material, a phenolic novolac resin, a hardening agent, a plasticizer, and a lubricant. Blending, billeting, and extruding operations are performed at material temperatures that, in general, do not exceed about 200.degree. F. The extrudate is cured at higher temperatures of, for example, 260.degree. F. to 325.degree. F.

Compositions, processes, and writing elements employing resins of the

Disclosed are molded plastic parts particularly eyeglass frame components, the centrifugal spin-casting of such parts and mold apparatus for producing such parts. Also disclosed are flexible molds for spin-casting eyeglass fronts and temples. In accordance with one aspect of the invention, the plastic parts are made from a resin system or mixture in liquid form comprising an epoxy resin, a curing agent therefore and an ultra-violet absorber and/or an antioxidant. DGEBA-type epoxy resins and polyoxypropylenediamine curing agents are the disclosed preferred epoxy resin and curing agent.

Molded plastic parts, particularly spin-cast plastic parts for eyeglass

Screen printing stencils are prepared by afixing to a printing screen substrate an indicia-defining, ultraviolet-sensitive film and cross-linking the film by exposure to ultraviolet radiation. The coating compositions used to form the film comprise copolyacrylate/polyurethane block copolymers, in which the copolyacrylate blocks are copolymers of at least one hydroxy-containing acrylate and at least one acrylate or methacrylate which may be partially substituted with bromine, ultraviolet initiators and cross-linking monomers. Screen printing stencils are provided which are compatible with both water-based and oil-based inks. The disclosed screen printing stencils are used in improved screen-printing methods.

Photocrosslinkable compositions for screen printing stencils

A lithographic printing plate in which the oleophilic imaging areas are formed as a thin cross-linked block copolymer film adhered to the hydrophilic surface of a backing plate. The block copolymer comprises blocks of copolyacrylate and polyurethane wherein the copolyacrylate blocks are a copolymer of a hydroxy-containing acrylate and a second acrylate component comprising one or more esters of acrylic acid or methacrylic acid or mixtures thereof and the polyurethane blocks are formed of polyoxybutylene as the prepolymer component. In forming the printing plate the block copolymer is deposited as a thin film containing an ultraviolet initiator and a cross linking promoter and the cross-linked imaging areas are formed by exposure to ultraviolet radiation.

Method of preparing lithographic printing plates using novel compounds

Screen printing stencils are prepared by affixing to a printing screen substrate an indicia-defining, ultraviolet-sensitive film and cross-linking the film by exposure to ultraviolet radiation. The coating compositions used to form the film comprise copolyacrylate/polyurethane block copolymers, in which the copolyacrylate blocks are copolymers of at least one hydroxy-containing acrylate and at least one acrylate or methacrylate which may be partially substituted with bromine, ultraviolet initiators and cross-linking monomers. Screen printing stencils are provided which are compatible with both water-based and oil-based inks. The disclosed screen printing stencils are used in improved screen-printing methods.

Screen printing stencils using novel compounds and compositions

A lithographic printing plate in which the oleophilic imaging areas are formed as a thin cross-linked block copolymer film adhered to the hydrophilic surface of a backing plate. The block copolymer comprises blocks of copolylacrylate and polyurethane wherein the copolyacrylate blocks are a copolymer of a hydroxy-containing acrylate and a second acrylate component comprising one or more esters of acrylic acid or methacrylic acid or mixtures thereof and the polyurethane blocks are formed of polyoxybutylene as the prepolymer component. In forming the printing plate the block copolymer is deposited as a thin film containing an ultraviolet initiator and a cross linking promoter and the cross-linked imaging areas are formed by exposure to ultraviolet radiation.

Photocrosslinkable compositions for lithographic printing plates

Method of preparing screen printing stencils using novel compounds and

A dry system for forming and transferring images is provided. The system comprises a photoactive component comprising a tacky photohardenable layer on a selected carrier sheet and a transfer component comprising a frangible color layer on a selected carrier sheet. The two components are disposed with their photohardenable and color layers in air-free contact with one another and then subjected to irradiation with actinic radiation in accordance with a selected image pattern so as to cause selected portions of the photohardenable layer to harden and fuse to confronting portions of the color layer. Then the two components are separated whereby the fused portions of the color layer are separated from its carrier sheet and transferred to the photoactive component. Thereafter the color layer remaining on the transferable component is coated with a pressure-sensitive adhesive. Finally, the transferable component is positioned with its adhesive coating engaging a receptor substrate and the rear side of its carrier sheet is rubbed hard or burnished with a suitable implement so as to cause the remaining image-defining portions of the color layer to separate from its carrier sheet and adhere to the receptor substrate.

Dry transfer image systems

Dry transfer image systems with non-light sensitive frangible layer

A method for improving adhesion of nonfogging film coatings comprising a block copolymer containing alternating blocks of polyurethane and a hydrophilic polyacrylic, to a polymeric substrate by subjecting the substrate to a controlled exposure to UV irradiation. Exposure may be prior to or following casting the nonfogging coating in place on the substrate. By varying the weight ratio of polyurethane/polyacrylic it is possible to vary the flexibility of the coating and hence to widen the range of substrates to which the coating may be applied, e.g., from flexible wrapping material to rigid mirrors.

Method of rendering surfaces nonfogging

Pencils made with a resin-based sheath to replace wood sheaths. A sheath material consisting essentially of a resin binder, a fibrous filler and a metallic soap is extruded around a marking core. The resulting extrudate is immediately chilled after leaving the die, and cut into pencil lengths. The apparatus includes core feeding and transport means, core preheating means and chilling means. The resulting pencils possess the physical qualities associated with wood-sheathed pencils due to the fine, closed cell structure of the sheath material. The surface of the sheath is smooth and may be coated with a pigmented resin or painted.

Pencil comprising a marking core and a porous resin sheath

Pencil sheath compositions, method for making pencils

A method for treating a surface of a substrate to render it nonfogging and the resulting article formed by the treatment. A thin film coating of a block copolymer containing alternating blocks of polyurethane and a hydrophilic copolyacrylic is adhered to the surface to be made nonfogging. The copolyacrylic is a copolymer of a hydroxy substituted acrylate and an ethylenically unsaturated acid such as acrylic acid. By varying the weight ratio of polyetherurethane/copolyacrylic it is possible to vary the flexibility of the coating and hence to widen the range of substrates to which the treatment is applicable, e.g., from flexible wrapping material to rigid mirrors.

Growing community of inventors

Wakefield, MA, United States of America

Richard E Merrill