Alliedsignal Inc.

Allied Chemical Corporation

Allied Corporation

Richard E Eibeck

Martin A Robinson

Michael Van Der Puy

Henry R Nychka

Bernard F Sukornick

Hillel Magid

Morris B Berenbaum

Francis E Evans

Richard M Hollister

Dennis M Lavery

David Nalewajek

David Paul Wilson

Louis G Anello

Hsueh Sung Tung

Raymond Hilton Thomas

Timothy R Demmin

Richard F Sweeney

Robert Christian Parker

James O Peterson

Gary Michael Knopeck

Robert E Booth

Michael Vanderpuy

Donna M Ruszaj

Andrew Joseph Poss

Alagappan Thenappan

Chien C Li

David J Friedland

Lynn E McCurry

Edward Stephen Jones

Eugene B Recla

Phillip J Persichini

Lois A Shorts

Hang Thanh Pham

Rajat S Basu

Stephen Frederic Yates

George David Green

Ellen L Swan

Matthew H Luly

Keith A Horn

Willis Hammond

Joseph Gaynor

G V Madhavan

Robert A Wiles

Valentine Theodore Zuba

William Burke Fox

Charles J Lind

Michael Van Der Puv

Lois A Ellis

Charles J Felice, Jr

John B Hino

George D Lockyer, Jr

George D Lockyer

B V Bindu Madhavan

Lois Anne Short Ellis

The invention relates to the preparation of 1-chloro-1,1,3,3,3-pentafluoropropane (HCFC-235fa), useful as an intermediate in the production of 1,1,1,3,3-pentafluoropropane (HFC-245fa). The invention further relates to a process for the preparation of HFC-245fa comprising reacting HCFC-235fa with hydrogen in the presence of a reduction catalyst wherein the said HCFC-235fa is prepared by reacting CCl,CHCCl,with hydrogen fluoride in the presence of fluorination catalyst in either the liquid phase or the vapor phase.

Process for the preparation of fluorine containing hydrohalocarbons

The invention provides a process for separating fluorinated organic compounds from mixtures of the such compounds and hydrogen fluoride. More particularly, the invention provides a method for separating a fluorinated organic compound from a mixture containing at least one fluorinated organic compound and hydrogen fluoride by adding an inorganic salt to the mixture.

Process for separating fluorocarbon compounds

This invention is related to the preparation of hydrofluorocarbons (HFCs). Specifically, it relates to the manufacture of 1,1,1,3,3-pentafluoropropane, CF.sub.3 CH.sub.2 CF.sub.2 H (HFC-245fa) by the steps comprising (1) the formation of CCl.sub.3 CH.sub.2 CCl.sub.3 by the reaction of CCl.sub.4 with vinylidene chloride; (2) the conversion of CCl.sub.3 CH.sub.2 CCl.sub.3 to CF.sub.3 CH.sub.2 CF.sub.2 Cl by reaction with HF in the presence of a fluorination catalyst, selected from TiCl.sub.4, SnCl.sub.4 or mixtures thereof; and (3) reduction of CF.sub.3 CH.sub.2 CF.sub.2 Cl to CF.sub.3l CH.sub.2 CF.sub.2 H.

Process for the preparation of 1,1,1,3,3-pentafluoropropane

A vapor phase process for the preparation of fluorinated ketones, such as 1,1,1,3,3,3-hexafluoro-2-propanone via oxidation of hydrofluorocarbons, such as 1,1,1,3,3,3-hexafluoropropane, with an oxidizing agent and elemental fluorine at temperatures ranging from 50.degree. C. to 300.degree. C. and residence times ranging from 2 to 60 seconds.

Process for the preparation of 1,1,1,3,3,3-hexafluoro-2-propanone

A vapor phase process for producing a fluorinated alcohol, such as 2,2,2-trifluoroethanol via oxidation of an hydrofluorocarbon, such as 1,1,1-trifluoroethane, with an oxidizing agent and elemental fluorine.

Process for the preparation of 2 2 2 trifluoroethanol

Stable azeotrope-like compositions consisting essentially of dichloropentafluoropropane and a hydrocarbon containing six carbon atoms which are useful in a variety of industrial cleaning applications including cold cleaning and defluxing of printed circuit boards.

Azeotrope-like compositions of dichloropentafluoropropane and

The present invention relates to foam compositions which are expanded with hydrohalocarbon blowing agents in the presence of catalysts which are capable of decreasing the amount of decomposition of the hydrohalocarbon blowing agents to haloalkenes during the polymerization. Thus, the present invention provides compositions comprising polyisocyanate, polyol, hydrohalocarbon blowing agent, surfactant, and catalyst for polymerization of the polyisocyanate and polyol wherein the catalyst is capable of decreasing the amount of decomposition of the hydrohalocarbon blowing agents to haloalkenes during polymerization of the polyisocyanate and the polyol.

Catalysts which stabilize hydrohalocarbon blowing agent in

The present invention provides a composition for use in refrigeration and air-conditioning comprising: (a) at least one refrigerant selected from the group consisting of hydrofluorocarbon, hydrochlorofluorocarbon, fluorocarbon, and chlorofluorocarbon; and (b) a sufficient amount to provide lubrication of at least one lubricant prepared by polymerizing alkene having a perfluoroalkyl group on one end thereof. The lubricant has a molecular weight of about 300 to about 3,000 and a viscosity of about 5 to about 150 centistokes at 37.degree. C. The lubricant is miscible in combination with the refrigerant in the range between about -40.degree. C. and at least about +20.degree. C.

Refrigeration lubricants prepared by polymerizing alkene having a

The present invention provides hydrofluorocarbon solvents having a portion which is fluorocarbon and the remaining portion is hydrocarbon and having 4 to 7 carbon atoms. The solvents are useful for dissolving contaminants or removing contaminants from the surface of a substrate.

Method of dissolving contaminants from substrates by using

Azeotrope-like compositions comprising dichloropentafluoropropane and 1,2-dichloroethylene are stable and have utility as degreasing agents and as solvents in a variety of industrial cleaning applications including cold cleaning and defluxing of printed circuit boards.

Azeotrope-like compositions comprising 1-H-perfluorohexane and trifluoroethanol or n-propanol and optionally nitromethane are stable and have utility as degreasing agents and as solvents in a variety of industrial cleaning applications including cold cleaning and defluxing of printed circuit boards and dry cleaning.

Azeotrope-like compositions of 1-H-perfluorohexane and trifluoroethanol

The present invention relates to foam compositions which are expanded with hydrohalocarbon blowing agents in the presence of additives which decrease the formation of haloalkenes during the polymerization. Thus, the present invention provides compositions comprising polyisocyanate, polyol, hydrohalocarbon blowing agent, catalyst, surfactant, and at least one additive wherein the additive is capable of decreasing the amount of decomposition of said dehydrohalocarbon blowing agent to haloalkenes during polymerization of the polyisocyanate and the polyol. Depending upon the polyol and polyisocyanate used and the quantity of polyisocyanate used, the compositions may be used in pour-in-place molded foams; rigid urethane spray foams; rigid high and low density foams for slabstock, froth foams, and molded foams; rigid laminated boardstock; or specialty foams.

Additives which stabilize hydrohalocarbon blowing agent in polyurethane

Stable azeotrope-like compositions consisting essentially of dichloropentafluoropropane and an alkanol having 1-4 carbon atoms which are useful in a variety of industrial cleaning applications including cold cleaning and defluxing of printed circuit boards.

Azeotrope-like compositions of dichloropentafluoropropane and an alkanol

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Orchard Park, NY, United States of America

Richard E Eibeck