Uop Lcc

Spectramed, Inc.

Gould Inc.

Duracell Inc.

Richard C Murray

Mark S Goorsky

Gregory John Lewis

Mark B Koch

Ivar Martin Dahl

Arne Karlsson

Duncan E Akporiaye

Rune Wendelbo

David S Bem

Andrzej Z Ringwelski

Henry F Gibbard

Cheryl M Bratu

Cheryl Margaret Surman

Mark S Zetter

Ronald A Putt

Jay M Cech

Andrea L Rauch

Claude J Menard

Theodore W Valentine

J Scott Fowler

Steven M Lefkowitz

Christopher A Mendyk

Alan D Wilks

Embodiments of simulated moving bed systems for separating a preferentially adsorbed component from a feed stream and processes for determining a pump-around profile of the simulated moving bed systems are provided. The process comprises the steps of rotating a rotary valve to a first valve position to direct the feed stream to a first adsorbent sub-bed. An intermediate stream between two adsorbent sub-beds in direct fluid communication with each other is irradiated with laser light that is directed from a probe of a Raman system positioned for inline sampling of the intermediate stream. Scattered light from the irradiated intermediate stream is collected with the probe. A spectrum of the scattered light is generated with the Raman system to determine concentrations of the preferentially adsorbed component and one or more other components in the intermediate stream.

Simulated moving bed systems for separation of para-xylene and processes for determining pump-around profiles of the simulated moving bed systems

An apparatus and process for forming an array of powder samples arranged in predefined locations where all samples have a flat surface in a common plane has been developed. A monolithic block having a main support section having at least N perforations from a first surface of the main support through a second surface of the main support in predefined locations, where N is the number of samples in the array is provided. The monolithic block also has a flat support section covering the perforations of the main support section. All N samples are loaded simultaneously with sample X in perforation X of the main support where X is an integer from 1 to N. A flat surface of each sample where the flat surfaces are a common plane is formed by forcing the samples within the perforations against the flat support. The samples are retained in position within the perforations against the flat support, and are made ready for analysis since the flat surfaces of the samples are in predefined locations and are all in a common plane.

Process of parallel sample preparation

A process of forming an array of powder samples arranged in predefined locations where all samples have a flat surface in a common plane has been developed. A main support having at least N perforations from a first surface of the main support through a second surface of the main support in predefined locations, where N is the number of samples in the array is provided. The main support is equipped with a flat support temporarily attached to its first surface. All N samples are loaded simultaneously with sample X in perforation X of the main support where X is an integer from 1 to N. A flat surface of each sample where the flat surfaces are a common plane is formed by forcing the samples within the perforations against the flat support. The samples are retained in position within the perforations against the flat support, and are made ready for analysis by exposing the flat surfaces of the samples by removing the flat support. The exposed flat surfaces of the samples are in predefined locations and are all in a common plane. Alternatively, the flat support may be permanently attached to the main support.

A method for rapidly screening multiple X-ray powder diffraction patterns, such as those generated through combinatorial chemistry, has been developed. The method is directed toward measuring X-ray powder diffraction patterns of a set of samples, factoring the patterns using a suitable statistical technique into a small number of discrete components or factors, determining the scores corresponding to the factors for each X-ray powder diffraction pattern, and plotting the scores. The graphs of the scores are then inspected for clusters, trends, or outliers, which may represent new material or, perhaps, faulty data.

Method of rapidly screening X-ray powder diffraction patterns

Control of many chemical processes is optimized using compositional data, rather than physical properties, as the means of control. Using near infrared spectroscopy as the analytical tool affords the opportunity for on-line measurements in real time. A calibration set of NIR spectra bounding the acceptable process space within which a particular property is to be controlled is obtained by conventional means. Applying a multivariant statistical method to the calibration set affords a method of identifying the most important characteristics of the set which governs the controlled property, and is inherently related to the composition of the process product. Control then is effected by using only a small number (2-4) of such characteristics, which can be determined quickly and simply from the measured spectra, as the control criteria to be applied to the process as a whole. The result is a very effective way of controlling a complex process using only 2-4 non-obvious criteria objectively determined from a calibration set and which can be applied in real time and virtually continuously resulting in a well-controlled process whose product composition is (ideally) invariant.

Maintenance of process control by statistical analysis of product

The observation was made that virtually all octane number variations arise from 23 components present in a broad variety of gasolines. Consequently it is possible to develop a calibration set consisting of a gasoline base stock as modified by one or more of the 23 components. By measuring the octane number and near infrared spectrum of each member of the calibration set, the octane number of any sample at the site specific for the base stock may be determined from the near infrared spectrum of the sample.

Calibration of NIR spectra in measuring properties of petroleum products

It has been determined that the symmetric stretching frequency of water at concentrations of 10 ppm and more in liquid hydrocarbons is effectively independent of the nature of the hydrocarbon. On this basis one can rapidly, accurately, and precisely measure such water concentrations by comparing the transmittance of a narrow band of infrared frequencies within the symmetric stretching band of a wet sample with the transmittance at a frequency in the 3770-4000 cm.sup.-1 range, performing a second comparison with a dried sample, and forming the ratio of the two comparative measurements as a measure of dissolved water content.

Measurement of water levels in liquid hydrocarbon media

A fiber-optic probe for measuring the partial pressure of CO.sub.2 in a medium includes a single optical fiber having a distal end; a mirror; a hydrolyzed dye/gel polymer, the dye being in contact with a bicarbonate solution; a solution permeable membrane covering the fiber distal end, hydrogel and mirror; and a gas-permeable membrane covering the solution permeable membrane.

Fiber optic CO.sub.2 sensor

A hydrolyzed dye/gel polymer for use in a pH-based sensor is characterized by its chemical and optical stability with respect to dye loss with time. Preferably, the dye/gel polymer is hydrolyzed by heating in a dilute base solution for a period of time sufficient to remove weakly bonded dye molecules from the polymer, then washed to remove the base solution and loose dye.

Fiber optic pH sensor having low drift rate

A multiple sensor which can be readily inserted into, and removed from a radial arterial cannula for use in continuous in vivo patent monitoring includes a plurality of individual sensors, each sensor including a sensing element disposed on an optical waveguide, the sensors being bonded together by an adhesive without covering the sensing elements.

Method for forming multiple sensor bundle

A device is described for sensing oxygen, particularly for use in medical applications. The device includes an optical waveguide and an oxygen sensing medium disposed on the waveguide. The sensing medium fluoresces in response to light from a light source such that the intensity of fluorescence is dependent on the partial pressure of oxygen in the environment. The sensing medium includes an oxygen sensitive fluorescent dye in a matrix consisting of a plasticized polymer.

Optical sensor for monitoring the partial pressure of oxygen

Multiple sensor bundle

An electrode for use in miniaturized sensor applications includes an electrically conductive element, a first layer of a salt on the surface of the conductive element having a common cation with the conductive element, a second layer of a second salt coating the first layer, the second layer having a common anion with the first layer, and a membrane covering the second layer, wherein the electrode is completely anhydrous when formed. The membrane may be selected to form either an ion selective electrode or a reference electrode.

Solid phase electrode

A sealed, rechargeable nickel-zinc cell includes a zinc electrode active mass essentially free of zinc metal when at full discharge, a carboxylated styrene-butadiene binder retaining the zinc electrode mixture in a coherent structure, a predetermined amount of cadmium being included in the zinc electrode mixture, a separator preferably comprising at least two layers of material free of any adhesive binding the layers together and a wicking layer positioned between the nickel positive electrode and the separator.

Sealed nickel-zinc battery

The disclosure depicts a novel gas switch comprising a membrane having at least one passageway separating a first gas containing region from a second gas containing region. The gas switch also comprises a liquid having a low vapor pressure contained at least within the passageway of the membrane. The liquid is contained in the passageway when a pressure difference between the first and second regions is less than a first predetermined value, thereby preventing a gas exchange between the first and second regions. When the pressure difference across the membrane exceeds a second predetermined value the liquid substantially flows out of the passageway, thereby opening the passageway for a gas exchange between the first and second regions; and when the pressure difference across the membrane is reestablished at a value less than the first predetermined value, the fluid flows back into the passageway thereby closing the passageway and ending the gas exchange between the first and second region. In some embodiments the first predetermined value of pressure may be substantially identical to the second predetermined value of pressure.

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Palatine, IL, United States of America

Richard C Murray