Standard Oil Company (indiana)

Amoco Corporation

Richard A Hall

Jeffrey I Rosenfeld

Evelyn A Taylor

Edward J Bernier, Jr

Michael G O'Connell

In a mechanical cell for blending elastomer particles and solution into uniform mixtures, a solid core with an entrance surface, an exit surface spaced apart from and substantially parallel to the entrance surface, and a plurality of minute core passageways therebetween for flow of an elastomer-containing hydrocarbon solution from the entrance surface to the exit surface, the passageways have a characteristic dimension of predetermined size to reduce globules of elastomer to small particles distributed evenly in liquid hydrocarbon solution without plugging the passageways. Typically the passageways have a characteristic dimension of predetermined size to reduce globules of elastomer selected from the group consisting of natural rubber, styrene-butadiene rubber, polybutadiene rubber, polyisoprene, a nitrile rubber, and a copolymer of a 1,4-conjugated diene and a vinyl aromatic monomer, to small particles distributed evenly in liquid hydrocarbon solution comprising a vinyl aromatic monomer. Preferably the passageways have a characteristic dimension of predetermined size to reduce globules of elastomer to small particles having diameters in a range downward from about 200 micrometers.

Apparatus and process for blending elastomer particles and solution into

A first reactor is used to graft polystyrene to a rubber-like polymer. A second reactor is used to obtain a mixture of styrene and polystyrene. The effluent from both the first and the second reactors are fed into a quiescent reaction zone where phase inversion occurs. The phase inverted material is fed into post inversion reactors to substantially complete the polymerization of the styrene monomer, and any unreacted styrene monomer is driven off to form the improved high-impact polystyrene.

High-impact polystyrene

In a process for the mass polymerization of vinyl aromatic monomer wherein vinyl aromatic monomer is polymerized in successive stages of increasing temperature, the improvement which narrows the molecular weight distribution of the resulting polymer comprising incorporating a polymerization inhibiting agent into a polymerizing mass at a point where about 60 to about 95% of monomer is converted to polymer.

Process for obtaining narrow molecular weight distribution in vinyl

A laminate is formed, without an adhesive, between an acrylic polymer film and a styrene polymer containing minor amounts of an .alpha.,.beta.-unsaturated carboxylic acid.

Method to adhere acrylic films to styrenic polymers

In a process for the mass polymerization of vinyl aromatic monomer wherein vinyl aromatic monomer is polymerized in successive stages of increasing temperature, the improvement which narrows the molecular weight distribution of the resulting polymer comprising incorporating a crosslinking agent into a polymerizing mass at a point where about 60 to about 95% of monomer is converted to polymer.

Growing community of inventors

Naperville, IL, United States of America

Richard A Hall