Rohm and Haas Company

Richard A Haggard

Sheldon N Lewis

David R Gehman

Norman Shachat

Polymers of esters of methacrylic acid having an average chain length of about 6 to about 50 mers are prepared by an anionic polymerization reaction, carried out in the presence of a chain-regulating alcohol and a catalytic amount of an alkoxide anion, in which control of the molecular weight and molecular weight distribution of the polymer are achieved by regulating the ratio of the total quantity of alcohol employed to the total monomer charge. These polymers, their hydrolysis products, and their derivatives have a wide variety of applications, including use as components in films, coatings, fibers, impregnants, adhesives, printing inks, and binders, and use as modifiers, plasticizers, melt flow improvers, and leveling agents.

Novel polymers of alkyl methacrylates

Polymers of esters of acrylic acid having an average chain length of about 6 to about 30 mers are prepared by an anionic polymerization reaction, carried out in the presence of a catalytic amount of an alkoxide anion. These polymers, their hydrolysis products, and their derivatives have a wide variety of applications, including among others use as components in films, coatings, fibers, impregnants, adhesives, and binders, and use as modifiers, plasticizers, melt flow improvers, and leveling agents.

Novel polymers of alkyl acrylates

Polymers of esters of methacrylic acid having an average chain length of about 6 to about 50 mers are prepared by an anionic polymerization reaction, carried out in the presence of a chain-regulating alcohol and a catalytic amount of an alkoxide anion, in which control of the molecular weight and molecular weight distribution of the polymer are achieved by regulating the ratio of the total quantity of alcohol employed to the total monomer charge. These polymers, their hydrolysis products, and their derivatives having condensation-crosslinkable functionality have a wide variety of applications, including use as components in films, coatings, fibers, impregnants, adhesives, printing inks, and binders, and use as modifiers, plasticizers, melt flow improvers, and leveling agents.

Composition comprising condensation cross-linkable novel methacrylate

Use of novel polymers of alkyl acrylates

Novel methacrylic polymers having condensation-crosslinkable

Polymers of esters of methacrylic acid having an average chain length of about 6 to about 50 mers are prepared by an anionic polymerization reaction, carried out in the presence of a chain-regulating alcohol and a catalytic amount of an alkoxide anion, in which control of the molecular weight and molecular weight distribution of the polymer are achieved by regulating the ratio of the total quantity of alcohol employed to the total monomer charge. These polymers, their hydrolysis products, or their hydroxyl-containing derivatives are esterified or transesterified to give polymers having pendant acrylate or methacrylate functionality which are useful in formulating films, coatings, inks, and the like.

Novel methacrylic polymers having pendant acrylate and methacrylate

This invention discloses the composition and use of salts of low molecular weight polymers of methacrylic and acrylic esters formulated with wetting, emulsifying, plasticizing or coalescing agents as aqueous finish compositions for hard surfaces. The polymers have molecular weights between 700 and 5000 and acid numbers between 50 and 275. The finishes produced by the compositions are water clear and are self-dispersible. Thus, on reapplication, the previous film is dissolved, the embedded soil removed and a fresh film left.

Oligomeric aqueous finishes

Polymers of alkyl acrylates

Polymers of esters of methacrylic acid having an average chain length of about 6 to about 50 mers are prepared by an anionic polymerization reaction, carried out in the presence of a chain-regulating alcohol and a catalytic amount of an alkoxide anion, in which control of the molecular weight and molecular weight distribution of the polymer are achieved by regulating the ratio of the total quantity of alcohol employed to the total monomer charge. These polymers, their hydrolysis products, and their derivatives having allyl functionality have a wide variety of applications, including use as components in films, coatings, fibers, impregnants, adhesives, printing inks, and binders, and use as modifiers, plasticizers, melt flow improvers, and leveling agents.

Compositions containing novel methacrylic polymers having allyl

Polymers having pendant acrylate and methacrylate functionality

Novel methacrylic polymers having allyl functionality

A method for leveling latex polishes which comprises treating said polishes with a salt of partially hydrolyzed polymer of methacrylic ester wherein said polymer has an average chain length of from about 6 to about 20 mer units.

An improved method is provided for producing polymers of organic compounds, such as ethylenically unsaturated monomers, containing a betaine-type group of the formula: ##STR1## The method involves the reaction of acrylic acid or aqueous methyl acrylate and an aminoalkyl (meth)acrylate or an N-amino-alkyl (meth)acrylamide having a basic tertiary nitrogen atom in the presence of a free radical initiator. The monomers undergo vinyl addition polymerization to form valuable polymers having a wide variety of uses, such as flocculants, retention aids in the deposition of polymers, pigments, etc. on the fibers in a paper pulp, e.g., in the formation of mineral-filled papers.

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Fort Washington, PA, United States of America

Richard A Haggard