Xerox Corporation

Richard A Burt

Peter Michael Kazmaier

Cheng-Kuo Hsiao

George Liebermann

Giuseppa Baranyi

Ah-Mee Hor

Sandra J Gardner

Katsumi Daimon

Barkev Keoshkerian

Katsumi Nukada

Anthony M Horgan

Dasarao K Murti

Gordon K Hamer

Carol A Jennings

Kathleen M Carmichael

Cuong Vong

James Daniel Mayo

Paul Farrell Smith

Timothy P Bender

Marko D Saban

Yasuo Sakaguchi

Roger E Gaynor

Rafik O Loutfy

Ryosaku Igarashi

Christine J DeVisser

Guiseppa Baranyi

Process for preparing polyarylene ethers

A process comprising forming chlorogallium phthalocyanine (ClGaPc) in N-methyl-2-pyrrolidinone (NMP) to provide a ClGaPc (NMP) Type I; separately dry milling and then wet treating the Type I product to form Type II ClGaPc (NMP); blending the ClGaPc Type II product with hydroxygallium phthalocyanine (HOGaPc) Type V and a resin to form a coating mixture; coating the resulting mixture to form a photoconductive charge generator layer.

Imaging members

A process including: forming a first chlorogallium phthalocyanine (ClGaPc) in N-methyl-2-pyrrolidone (NMP) to form a ClGaPc (NMP) Type-I product; forming a second chlorogallium phthalocyanine in dimethyl sulfoxide (DMSO) to form a ClGaPc (DMSO) Type-I product; separately dry milling and then wet treating the Type-I products to form respective Type-II products; blending the Type-II products together along with a resin to form a coating mixture; and coating the mixture to form a charge generator layer in an electrostatographic imaging article.

Process for tuning photoreceptor sensitivity

A process for the preparation of Type V hydroxygallium phthalocyanine which comprises the in situ formation of an alkoxy-bridged gallium phthalocyanine dimer, hydrolyzing said alkoxy-bridged gallium phthalocyanine dimer to hydroxygallium phthalocyanine, and subsequently converting the hydroxygallium phthalocyanine product obtained to Type V hydroxygallium phthalocyanine.

Processes for the preparation of hydroxygallium phthalocyanine

A process for the preparation of alkoxy-bridged metallophthalocyanine dimers by the reaction of a trivalent metal compound with ortho-phthalodinitrile or 1,3-diiminoisoindoline in the presence of a diol.

Processes for the preparation of alkoxy-bridged metallophthalocyanine

Alkoxy-bridged metallophthalocyanine dimers of the formula C.sub.32 H.sub.16 N.sub.8 MOROMN.sub.8 H.sub.16 C.sub.32, or of the formula ##STR1## wherein M is a metal, and R is an alkyl or an alkyl ether.

Alkoxy-bridged metallophthalocyanine dimers

Photoconductive imaging members comprised of an alkoxy-bridged metallophthalocyanine dimer as a charge generator material, wherein said dimer is of the formula C.sub.32 H.sub.16 N.sub.8 MOROMN.sub.8 H.sub.16 C.sub.32 wherein M is a trivalent metal, and R is an alkyl group or an alkyl ether group ##STR1##

Photoconductive imaging members containing alkoxy-bridged

Disclosed is an improved layered photoresponsive imaging member comprised of a supporting substrate; an imidazole perinone comprised of components with a mixture of cis and trans isomers of Formulas III, IV, and V, including trans indanthrene Brilliant Orange, cis indanthrene Bordeaux Red; bis(4,5-dimethyl)benzimidazole perinone and bis 2,3 naphthimidazole perinone, and an aryl amine hole transport layer comprised of molecules of the following formula: ##STR1## dispersed in a resinous binder and wherein X is selected from the group consisting of halogen and alkyl.

Photoconductive imaging members with imidazole perinones

An improved layered photoresponsive imaging member comprised of a supporting substrate; a photogenerator layer comprised of cis and trans naphthalene imidazole perylene component of the following formula; ##STR1## and an aryl amine hole transport layer dispersed in a resinous binder.

Electrophotographic photoconductive imaging members with cis, trans

Disclosed are unsymmetrical squaraine compounds of the following formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently selected from the group consisting of alkyl, aryl, heterocyclic, benzyl, and halobenzyl; and X.sub.1, X.sub.2 and X.sub.3 are independently selected from the group consisting of hydrogen, alkyl, halogen, carboxy, and hydroxy; and photoresponsive imaging members having incorporated therein the aforementioned squaraine compounds.

Photoconductive imaging members with unsymmetrical squaraine compounds

Disclosed are unsymmetrical squaraine compounds of the following formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently selected from the group consisting of alkyl, aryl heterocyclic, benzyl, and halobenzyl; and X.sub.1, X.sub.2 and X.sub.3 are independently selected from the group consisting of hydrogen, alkyl, halogen, carboxy, and hydroxy; and photoresponsive imaging members having incorporated therein the aforementioned squaraine compounds.

An improved process for the preparation of mixed squaraine compositions which comprises reacting squaric acid, an aromatic amine, and a fluoroaniline, in the presence of an aliphatic alcohol, and an optional azeotropic substance. Also disclosed are mixed squaraine composition products of the following formulas: ##STR1##

Processes for the preparation of mixed squaraine compositions

Mixed squaraine photoconductive compositions

Photoresponsive devices, including layered photoresponsive devices comprised of a photoconductive layer of squaraine compositions of the following formula: ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 are independently selected from the group consisting of alkyl substitutents and aryl substituents.

Photoconductive devices with hydroxy containing squaraine compositions

Disclosed is an improved process for the preparation of squaraine compositions which comprises reacting squaric acid, an aromatic amine, and a composition selected from the group consisting of phenols and phenol squaraines, in the presence of an aliphatic alcohol, and an optional azeotropic substance.

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Mississauga, Canada

Richard A Burt