China Petroleum Chemical Corporation

Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation

Other

Renqi Peng

Yuexiang Liu

Xianzhi Xia

Weili Li

Jigui Zhang

Ping Gao

Zhihui Zhang

Jin Zhao

Yang Tan

Suzhen Qiao

Xinsheng Wang

Tianyi Zhang

Ruilin Duan

Yongtai Ling

Futang Gao

Ying Li

Jie Lin

Mingzhi Gao

Maoping Yin

Linna Yang

Changyou Ma

Baoquan Xing

Zhaowen Ma

Yijing Sun

Maozhu Jin

Baolan Zhu

Jing Ma

Changbing Xie

Huibo Shen

Meizhen Yin

A magnesium halide adduct represented by the formula (I): MgX.mROH.nE.pHO, in which X is chlorine, bromine, a C-Calkoxy, a C-Ccycloalkoxy or a C-Caryloxy, with the proviso that at least one X is chlorine or bromine; R is a C-Calkyl, a C-Ccycloalkyl or a C-Caryl; E is an o-alkoxybenzoate compound represented by the formula (II): in which Rand Rgroups are independently a C-Clinear or branched alkyl, a C-Ccycloalkyl, a C-Caryl, a C-Calkaryl or an C-Caralkyl, the Rand Rgroups are identical to or different from the R group; m is in a range of from 1.0 to 5.0; n is in a range of from 0.001 to 0.5; and p is in a range of from 0 to 0.8, is disclosed. A catalyst component useful in olefin polymerization, which comprises a reaction product of (1) the magnesium halide adduct, (2) a titanium compound, and optionally (3) an electron donor compound, is also disclosed. 

Spherical magnesium halide adduct, a catalyst component and a catalyst for olefin polymerization prepared therefrom

Spherical carriers for an olefin polymerization catalyst, catalyst components, catalysts, and preparation methods therefor are disclosed. The method for preparing the spherical carriers comprises the following steps: (1) reacting, in the presence of at least one polymeric dispersion stabilizer, a magnesium halide with an organic compound containing active hydrogen to form a complex solution; (2) reacting said complex solution with an alkylene oxide-type compound to directly precipitate solid particles; and (3) recovering the solid particles to obtain spherical carriers. When a catalyst prepared by using the present spherical carrier is used in propylene polymerization, said catalyst exhibits high polymerization activity and high stereo-directing ability.

Spherical carriers for olefin polymerization catalyst, catalyst components, catalyst, and preparation methods therefor

The present invention provides a catalyst component for olefin polymerization and a preparation method thereof, and a catalyst for olefin polymerization and an application thereof. The catalyst component for olefin polymerization comprises reaction products of the following components: (1) a solid component; (2) at least one titanium compound; and (3) at least two internal electron donors, wherein the solid component comprises a magnesium compound represented by formula (1) and an epoxide represented by formula (2), wherein Ris a C-Clinear or branched alkyl; Rand Rare identical or different, and are independently hydrogen or unsubstituted or halogen-substituted C-Clinear or branched alkyl; X is halogen; m is in a range of from 0.1 to 1.9, n is in a range of from 0.1 to 1.9, and m+n=2. 

Catalyst component for olefin polymerization, preparation method thereof, and catalyst comprising same

A catalyst component for olefin polymerization is disclosed, which comprises at least one diol ester type electron donor compound (a) and at least one diether type electron donor compound (b) among others, wherein the molar ratio of a to b is 0.55-50. A preparation method of the catalyst component, a catalyst comprising the catalyst component, and an olefin polymerization method using the catalyst which can especially be used for preparation of polypropylenes of low ash contents are also disclosed.

Catalyst component for olefin polymerization and preparation method thereof

A spheric magnesium compound comprises a reaction product of at least the following components: (a) a magnesium halide having a formula of MgXR, wherein X is independently chloride or bromide, R is a C-Calkyl, a C-Caryl, a C-Calkoxy, or a C-Caryloxy, and n is 0 or 1; (b) an alcohol compound; and (c) an epoxy compound having a general formula (I), wherein Rand Rare independently hydrogen, a C-Clinear or branched alkyl, or a C-Clinear or branched haloalkyl. The magnesium compound has characteristic DSC curve and X-ray diffraction pattern, and can be used as a carrier for olefin polymerization catalyst.  

Carrier for olefin polymerization catalyst, preparation method and application thereof

A catalyst component for olefin polymerization is disclosed, which comprises a reaction product of the following components: (1) a spheric carrier; (2) a titanium compound; and optionally, (3) an electron donor, wherein the spheric carrier comprises a reaction product of at least the following components: (a) a magnesium halide represented by a general formula of MgXR, wherein X is independently chloride or bromide, R is a C-Calkyl, a C-Caryl, a C-Calkoxy, or a C-Caryloxy, and n is 0 or 1; (b) an alcohol compound; and (c) an epoxy compound represented by a general formula (I), wherein Rand Rare independently hydrogen, a C-Clinear or branched alkyl, or a C-Clinear or branched haloalkyl. When the catalyst of the invention is used in olefin polymerization, in particular in propylene polymerization, at least one of the following desired effects can be achieved: high polymerization activity of catalyst, high stereospecificity of catalyst, good hydrogen response of catalyst, high stereoregularity of polymer having high melt index, and low content of polymer fines. 

Catalyst component for olefin polymerization and catalyst comprising the same

A magnesium halide adduct is provided, comprising at least one compound of the formula MgXY, at least one compound of the formula ROH, methanol, at least one modifying agent chosen from DOE and o-hydroxy benzoates, and optionally water. Also provided herein are a catalyst component comprising the magnesium halide adduct, a catalyst for olefin polymerization comprising the catalyst component; the respective processes for preparing the magnesium halide adduct and the catalyst component; use of the magnesium halide adduct for preparing the catalyst component, use of the catalyst component in a catalyst for olefin polymerization and use of the catalyst in olefin polymerization; and a process of olefin polymerization.

Magnesium halide adducts, catalyst components and catalysts comprising the same, and preparation processes thereof

The present invention provides a compound catalyst system useful for synthesizing polyethylenes or copolymers of ethylene having bimodal or broad molecular weight distributions, prepared by incorporating an organic alcohol as an electron-donor compound and an aluminoxane compound into the prior art compound catalyst systems, thereby promoting the activities of the two active centers, which leads to not only a large improvement in the activity of the catalyst system, but also the formation of polyethylenes and copolymers of ethylene having bimodal or broad molecular weight distributions, which in turn gives polymers having excellent processability and mechanical properties. A process for preparing the solid catalyst component used in the compound catalyst system according to the present invention and use of the compound catalyst system are also disclosed.

Compound catalyst system for synthesizing polyethylenes or copolymers of ethylene having bimodal or broad molecular weight distributions, process for preparing the same and use of the same

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Beijing, China

Renqi Peng