Basf Se Corporation

Rene Backes

Martin Weber

Stephan Andreas Schunk

Christian Maletzko

Richard Dehn

Alvaro Gordillo

Markus Piepenbrink

Holger Werhan

Martin Alexander Bohn

Svenia Duefert

Joaquim Henrique Teles

Rolf Pinkos

Klaus Ditrich

Alexander Panchenko

Alois Kindler

Wolfgang Ladner

Mathias Schelwies

Kirsten Dahmen

Ivana Jevtovikj

Daniel Breuninger

Benoit Blank

Bryan Cooper

Tobias Wabnitz

Feelly Ruether

Monika Charrak

Jens Heimann

Melanie Bonnekessel

Carmen Feldner

Lei Zhang

Jürgen Däuwel

Achim Sorg

A polyarylene ether sulfone comprising in polymerized form A) isosorbide, isomannide, isoidide or a mixture thereof and B) at least one nonsulfonated dihalodiaryl! sulfone (compound B) and C) at least one sulfonated dihalodiaryl sulfone (compound C), a process for its preparation and its use in the preparation of coatings, films, fibers, foams, membranes or molded articles.

Polyarylene ether sulfone

A polyarylene ether comprising in polymerized form A) at least one tri- or higher functional compound and B) isosorbide. isomannide, isoidide or a mixture thereof, wherein the polyarylene ether is a polyarylene ether sulfone or a polyarylene ether ketone, ¢ process for its preparation and its use in the preparation of a coating, film, fiber, foam, membrane or molded article.

Polyarylene ether

A polyarylene ether copolymer comprising i) at least one block comprising in polymerized form A) isosorbide, isomannide, isoidide or a mixture thereof and B) at least one unit comprising at least one difunctional compound comprising at least one dichlorodiaryl sulfone, a dichlorodiaryl ketone or a mixture thereof and ii) at least one block comprising in polymerized form C) at least one polyalkylene oxide, a process for its preparation and its use in the preparation of coatings, films, fibers, foams, membranes or molded articles.

Polyarylene ether copolymer

Provided herein is a process for preparing furan-2,5-dicarboxylic acid. The process includes the following steps: (A-1) preparing a starting mixture comprising one, two or more carbohydrate compounds selected from the group consisting of: hexoses, oligosaccharides comprising hexose units, and polysaccharides including hexose units, and as a solvent or as a co-solvent for the carbohydrate compounds an amount of one or more carboxylic acid esters of a formula (II) and (A-2) subjecting the starting mixture to reaction conditions so that at least one of the one, two or more carbohydrate compounds reacts, and a fraction of the amount of one or more carboxylic acid esters of formula (II) is hydrolyzed, resulting in a mixture including 5-(hydroxymethyl)furfural and/or the one or more HMF esters of a formula (I), one or more carboxylic acids of a formula (III) and a remaining fraction of the amount of one or more carboxylic acid esters of formula (II).

Process for preparing furan-2,5-dicarboxylic acid

A process for preparing furan-2,5-dicarboxylic acid is disclosed. The process includes the following steps: preparing or providing a starting mixture including 5-(hydroxy-methyl)furfural (HMF), 5,5'-[oxy-bis(methylene)]bis-2-furfural (di-HMF), and water; subjecting said starting mixture to oxidation conditions in the presence of an oxygen-containing gas and a catalytically effective amount of a heterogeneous catalyst including one or more noble metals on a support so that both HMF and di-HMF react to give furane-2,5-dicarboxylic acid in a product mixture also including water and oxidation by-products. The use of a catalyst is also disclosed, the catalyst including one or more noble metals on a support as an heterogeneous oxidation catalyst for catalyzing in an aqueous starting mixture the reaction of both HMF and di-HMF to furane-2,5-dicarboxylic acid.

Provided herein is a process for preparing a mixture including 5-(hydroxy-methyl)furfural (HMF) and one or more HMF esters of formula (I), the process including the following steps: (A-1) preparing or providing a starting mixture which includes one, two or more carbohydrate compounds and as the solvent or as a co-solvent for the carbohydrate compounds an amount of one or more carboxylic acid esters of formula (II); (A-2) subjecting the starting mixture to reaction conditions so that at least one of the one, two or more carbohydrate compounds reacts, and a fraction of the amount of one or more carboxylic acid esters of formula (II) is hydrolyzed, so that a mixture results that includes 5-(hydroxy-methyl)furfural and/or the one or more HMF esters of formula (I), one or more carboxylic acids of formula (III) and a remaining fraction of the amount of one or more carboxylic acid esters of formula (II).

Process for preparing a mixture comprising 5-(hydroxymethyl) furfural and specific HMF esters

The present invention relates to the preparation of isomerically pure substituted cyclohexanols starting from a mixture of cis/trans substituted cyclohexanols which comprises reacting the cis/trans mixture of a substituted cyclohexanol with a dicarboxylic acid anhydride in the presence of a lipase, to give the trans semi-ester which is separated off from the unreacted substituted cyclohexanol cis isomer.

Preparation of isomerically pure substituted cyclohexanols

The present invention provides a process for preparing 2-methyltetrahydrofuran by one-stage hydrogenation of furfural with a hydrogen-comprising gas in the presence of a structured bed of at least one copper catalyst and at least one catalyst which comprises at least one noble metal from groups 8, 9 and/or 10 of the periodic table of the elements applied on a support material.

Process for one-stage preparation of 2-methyltetrahydrofuran from furfural over two catalysts in a structured bed

Growing community of inventors

Lampertheim, Germany

Rene Backes