Degussa Aktiengesellschaft

Pku Pulverkautschuk Union Gmbh

Evonik Degussa Gmbh

Henkel Kgaa

Degussa Atiengesellschaft

Reinhard Stober

Michael Huss

Matthias Schmitt

Wolfgang Fischer

Uwe Ernst

Udo G&ouml;rl

Udo Goerl

Dietmar Bischoff

Hartmut Lauer

Andreas Gouw

Reimund Pieter

Udo Gorl

Silke Teike

Udo Görl

Jürgen Leimann

Susanne Esser

Ellen Kohn

Martin Kuge

Klaus Udluft

Siegfried Wolff

Ulrich Deschler

Rolf Wirthwein

Jan Kopietz

Gert Roessler

Georg Hellwig

Peter Kopietz

Christoph Klatte

Thomas Trempler

An adsorbent for organic compounds consisting of filler granules, which contain 20 to 99.9 wt. % of fillers and a binder. The adsorbent is produced by mixing at least one binder with at least one filler and performing granulation in a mixing or granulation apparatus. The adsorbent may be used for adsorbing and/or absorbing organic and/or inorganic substances from a liquid or gaseous phase.

Absorbents, process for the production thereof and use thereof

An adsorbent for organic compounds including filler granules, which contain 20 to 99.9 wt. % of fillers and a binder. The adsorbent is produced by mixing at least one binder with at least one filler and performing granulation in a mixing or granulation apparatus. The adsorbent may be used for adsorbing and/or absorbing organic and/or inorganic substances from a liquid or gaseous phase.

Adsorbents, process for the production thereof and use thereof

The present invention provides a process, which includes:

Rubber pellets comprising silicatic and oxidic fillers

The invention relates to a process for preparing fine-particle free-flowing rubber powders, composed of carbon black fillers and a rubber, prepared by solution polymerization. The process operates on the basis of a two-phase system involving transfer of the organic rubber phase in a non-aggressive manner into the inorganic filler suspension, without addition of chemicals. A rubber/carbon black composite is formed. The process comprises measures to avoid clumping of product in the aqueous phase. After mechanical water removal and thermal drying, the product obtained flows freely and is a storage-stable powder or pellet and are markedly superior to the standard both in their processing and in their rubber-technology property profile.

Pulvurent rubber comprising carbon black filler, process for their preparation and application

Rubber powders with a high degree of filling are obtained by precipitating water-containing suspensions which contain fillers and rubber emulsions or rubber solutions. Use thereof to prepare vulcanizable rubber mixtures.

Rubber powders which contain large amounts of fillers, a process for preparing them and the use thereof

A process for preparing silica-filled rubber powder is provided, which includes contacting a salt-containing silica-precipitation suspension with at least one selected from the group including a rubber latex, rubber solution, and rubber emulsion, to form a mixture; and precipitating to produce a silica-filled rubber powder. A silica-filled rubber powder prepared by the process, and compositions and uses containing the same, are also provided.

Modified rubber powders comprising silicatic fillers prepared from precipitation suspensions, process for their preparation and their use

A fine-particle, free-flowing rubber powder containing silicatic fillers, one or more organosilanes having trialkoxysilyl groups, and a rubber prepared by solution polymerization is prepared by a process that starts from a two-phase system: 1) filler in water, and 2) rubber in organic solvent. A rubber/silicatic filler/silane composite is formed during transfer, under gentle conditions, of the various reactants into a single phase. The process features a high degree of freedom in selecting forms of filler and in selecting the organosilane and gives a finished rubber powder in which a silicatic filler and an organosilane have undergone complete chemical reaction.

Rubber powders having pulverulent silicatic fillers and prepared from rubbers present in organic solvents, a process for their preparation, and their use

Fine-particle, filled rubber powders prepared by precipitation from aqueous mixtures of a filler suspension and a rubber-latex emulsion in the absence of water-soluble salts of metals of groups IIa, IIb, IIIa, or VIII of the Periodic Table of the Elements and in the absence of alkali metal silicate are used for vulcanizable rubber mixtures.

Process for preparing carbon-black-filled rubber powders based on aqueous polymer-latex emulsions

Pulverulent rubber powder containing filler which remains free-flowing even after exposure to mechanical stresses, a process for the production thereof, in which the rubber powder is obtained in two precipitation steps, and the use of these powders for the production of vulcanizable rubber compounds.

Pulverulent rubber powder containing filler, process of the production thereof and use thereof

Finely divided, pulverulent rubbers containing filler which contain further processing and vulcanization auxiliaries necessary for the production of vulcanizable rubber mixtures, which rubbers are pourable even after exposure to mechanical action, and to a process for the production thereof. The rubber powder is obtained within two precipitation steps. These rubber powders are used for the production of vulcanizable rubber mixtures. The fillers used, which comprise not only precipitated silicas but also carbon blacks known in the rubber industry, are optionally surface modified with organosilicon compounds.

Rubber powder compositions and process for the production thereof

Finely divided powdered rubbers containing filler which remain free-flowing even after exposure to mechanical stresses and to a process for the production thereof, in which the rubber powder is obtained in two precipitation steps, and to the use of these powders for the production of vulcanizable rubber compounds. The fillers used, which are both precipitated silicas and carbon blacks known in the rubber art, are surface-modifed by organosilicon compounds.

Powdered rubber containing modified fillers, process for the production thereof and use thereof

The invention relates to a process for the preparation of finely divided rubbers (rubber powders) by precipitation from aqueous mixtures, which comprise filler in the form of suspensions, water-soluble salts of a metal of groups IIa, IIb, IIIa and VIII of the periodic table of the elements arid a rubber latex (polymer latex), aqueous emulsions of a rubber or rubber solution, in which one or more organosilicon compound(s) containing at least one alkoxy group is or are dissolved or emulsified, optionally in the presence of a surface-active substance, in water, or the compounds mentioned are mixed directly, optionally with a surface-active substance, with an aqueous suspension of an oxidic or silicatic finely divided filler or a mixture of these fillers at a temperature of 10 to 60&deg; C., preferably at room temperature, while stirring, the amount of this mixture envisaged for incoporation in the rubber, based on the filler content, in general being divided into two batches.

Pulverulent rubber powders comprising modified fillers, processes for their preparation and their use

Bis(2,4-organylthio-s-triazine-6-yl) polysulfides of the general Formula (I) ##STR1## prepared from compounds of the general formula (II) ##STR2## and from an ammonium or alkali polysulfide and the use of such compounds as accelerators in vulcanizable rubber mixtures.

Vulcanizable rubber mixtures containing

The invention relates to a method of preparing an adjustable-viscosity cationized starch in which, in a process step in the presence of 10 to 35 wt. % water and preferably 0.01 to 2.00 wt. % of a finely-divided silica and/or silicate (in each case relative to the total amount of mixture) the starch is homogenized with an alkaline oxide, hydroxide, silicate aluminate or mixtures thereof, an alkylene epoxide and a peroxo compound or a mixture of at least two peroxo compounds and then boiled in known manner at the desired time.

Method of manufacturing an adjustable-viscosity cationic starch

A process for the dry cationization of polyvinyl alcohol (PVA) by reaction of alkylidene epoxides with PVA in alkaline medium in the presence of water, in which the reaction mixture contains 11 to 30 weight % of water, based on its total amount, and 1 to 4 weight % of an alkali metal or alkaline earth metal hydroxide or alkaline earth metal oxide, based on the quantity of PVA. As the cationizing agent there are used alkylidene epoxides or their mixtures having the general formula: ##STR1## wherein n=1, 2 or, 3, R.sup.1, R.sup.2 and R.sup.3 represent the same or different alkyl residues having 1 to 18 carbon atoms or R.sup.1 represents the benzyl or --C.sub.2 H.sub.4 OH, and X.sup.- denotes chloride, bromide, sulfate or acetate. Instead of alkylidene epoxides, the corresponding halohydrins, e.g. chlorohydrin or bromohydrin, can be used.

Growing community of inventors

Hasselroth, Germany

Reinhard Stober