Wacker-Chemie Gmbh

Reinhard Jira

Herbert Eck

Heinrich Hopf

Alfred Prasse

Hartmut Brabetz

Ralph Ottlinger

Hartmut Menzel

Alfred Rengstl

Hermann Braunling

The present invention provides a process for preparing disproportionation products of dichloromethylsilane in the presence of a catalyst, which comprises contacting dichloromethylsilane with a catalyst consisting of a carrier which is insoluble in the reaction medium and having NR.sub.3 groups or .sup.- X.sup.+ NR.sub.4 groups covalently bonded thereto, in which R represents the same or different alkyl, aryl, or alicyclic groups which may contain heteroatoms as constituents of the ring, or represents a hydrogen radical, and X.sup.- represents a chloride, bromide or iodide.

Process for preparing disproportionation products of

Polymers with conjugated double bonds having heterocyclic and/or carbocyclic rings or ring systems in which said rings or ring systems are linked with one another in pairs via a carbon atom as a bridge member. Polymers of the invention have, at least five of said ring or ring-systems. The polymers may be prepared by reacting at least one compound of the formula ##STR1## with at least one compound of the formula

Polymers with conjugated double bonds

A process for stabilizing organopolysiloxanes containing alkaline compounds such as alkali metal hydroxides, alkali metal silanolates, alkali metal siloxanolates, or a mixture of at least two such compounds, which comprises neutralizing the alkaline compound present in the organopolysiloxanes with a neutralizing agent selected from a compound containing carbon, hydrogen, and oxygen atoms, and optionally at least one halogen atom, in which the compound has 2, 3 or 4 hydrocarbon groups bonded to the same carbon atom via oxygen, or an acylacetic acid ester. The resultant organopolysiloxanes are stabilized against viscosity changes caused by the alkaline compounds.

Process for stabilizing organopolysiloxanes

Organosilicon compounds containing SiC-bonded biuret groups are prepared by (I) adding a silane containing 1 or 2 silicon atoms per molecule and an SiC-bonded organic radical having at least one basic ##STR1## group and at least one SiOC-bonded aliphatic radical per molecule to a monoisocyanate or a diisocycanate at a temperature up to 125.degree. C. and (II) maintaining the temperature at 110.degree. C. to 125.degree. C. for at least two minutes. In an alternate procedure the silane and mono- or diisocyanate may be heated to a temperature in the range of from 110.degree. C. up to 200.degree. C. for at least two minutes, after or while adding additional monoisocyanate or diisocyanate. The resultant silicon compounds are used in the preparation of polyurethanes and as additives to lacquers.

Silicon compounds containing SiC-bonded biuret groups and a method for

Organosilicon compounds containing SiC-bonded biuret groups are prepared by (I) adding a silane containing 1 or 2 silicon atoms per molecule and an SiC-bonded organic radical having at least one basic ##STR1## group and at least one SiOC-bonded aliphatic radical per molecule to a monoisocyanate or a diisocyanate at a temperature up to 125.degree. C. and (II) maintaining the temperature at 110.degree. C. to 125.degree. C. for at least two minutes. In an alternate procedure the silane and mono- or diisocyanate may be heated to a temperature in the range of from 110.degree. C. up to 200.degree. C. for at least two minutes, after or while adding additional monoisocyanate or diisocyanate. The resultant silicon compounds are used in the preparation of polyurethanes and as additives to lacquers.

A process for the preparation of aqueous polymer dispersions comprising polymerizing compounds with unsaturated ethylenic bonds at a temperature of 10.degree. to 100.degree. C. in the presence of an at least partially water-soluble free-radical initiator and at least one starch and/or starch derivative and optionally present conventional adjuvants with the starting mixture containing not more than one third of the total monomers and the remaining monomer being added during the polymerization, the initiators being at least one member of the group consisting of hydrogen peroxide, ketone peroxides and organic hydroperoxides in an amount of at least 30 mmol per kg of total monomer mixture and optionally present water-soluble reducing agents and the starch is water-soluble or gells in water and contains not more than 30% by weight of amylose and the starch derivative is hydrolyzed starch in an amount of at least 0.6% by weight based on the total monomer weight.

Aqueous polymer dispersions preparation

A process for the preparation of aqueous polymer dispersions comprising polymerizing compounds with unsaturated ethylenic bonds at a temperature of 10.degree. to 100.degree. C. in the presence of an at least partially water-soluble free-radical initiator and at least one water-soluble protein and optionally present conventional adjuvants with the starting mixture containing not more than 40% of the total monomers and the remaining monomer being added by metering during the polymerization, the initiators being at least one member of the group consisting of ketone peroxides and organic hydroperoxides in an amount of at least 30 mmol per kg of total monomer mixture and optionally present water-soluble reducing agents and the amount of protein being at least 3% by weight based on the total monomer weight and at least 30% by weight is added during the polymerization and the isoelectric point of the protein is not reached or exceeded during polymerization.

Process for aqueous polymer dispersion by polymerizing unsaturated

A process for the preparation of aqueous polymer dispersions comprising polymerizing vinyl esters and up to 50% by weight of the total monomer of compounds with unsaturated ethylenic bonds at a temperature of 10.degree. to 100.degree. C. in the presence of an at least partially water-soluble free-radical initiator and at least one starch member of the group consisting of cyanalkylated starch, hydroxyalkylated starch and carboxyalkylated starch and optionally present conventional adjuvants with the starting mixture containing not more than one-third of the total monomers and the remaining monomers being added by metering during the polymerization, the initiators being at least one member of the group consisting of hydrogen peroxide and organic hydroperoxides in an amount of at least 30 mmol per kg of total monomer mixture and optionally present water-soluble reducing agent and the amount of starch being at least 1% by weight based on the total monomer weight.

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Burghausen, Germany

Reinhard Jira