Rsr Limited

Other

St. Joe Minerals Corporation

Raymond D Prengaman

Herschel B McDonald

James Howard

Clifford E Morgan

An electrowinning anode is formed by tightly joining a sheet of lead anode material to a copper busbar using solder to fill the joint. The busbar is optimally coated with a tin alloy by dipping the busbar into the alloy prior to being joined with the sheet. A lead coating is electrodeposited onto the busbar and the soldered joint to provide a complete metallurgical seal and good resistance to acid corrosion.

Electrowinning anode and method of manufacture

Calcium and aluminum are alloyed into lead by adding a eutectic calcium-aluminum alloy to molten lead preferably at a temperature of at least 1020.degree.. The eutectic alloy contains about 73% calcium and about 27% aluminum.

Method of alloying calcium and aluminum into lead

A thread sealing and lubricating composition which can be employed at elevated temperatures without carburization of stainless steel fittings is disclosed. The composition contains 8-25% finely divided copper flakes, 5-20% finely divided aluminum particles, and 4-15% non-metallic, non-carbon powder suspended in a petroleum vehicle. The preferred composition contains 10% copper flakes, 5% aluminum powder, 5% non-metallic powder and 80% viscous petroleum vehicle.

Thread sealing and lubricating composition

Low antimony lead alloys suitable for use as grid material in maintenance-free high capacity lead acid batteries are disclosed. The alloys comprise 0.6 to 1.1 weight percent antimony, 0.06 to 0.25 weight percent arsenic, 0.1 to 0.4 weight percent tin, 0.06 to 0.11 weight percent copper, and the balance lead. A preferred alloy contains 0.8 weight percent antimony, 0.15 weight percent arsenic, 0.25 weight percent tin and 0.08 weight percent copper.

Low antimony alloy

A lead anode for electrowinning metals from sulfuric acid solutions is formed by soldering a sheet of lead anode material endwise in a slot, which extends longitudinally along and partially through a lead alloy coated copper bus bar and into which the sheet fits tightly, and thereafter depositing lead alloy filler at all joints between the bar and anode. Anodes thus constructed have a uniform, smooth joint between the bar and sheet and thus are corrosion resistant and exhibit uniform conductivity.

Method of manufacturing electrowinning anode

An improved insoluble anode for electrowinning is described which comprises a graphite substrate covered by a tight fitting sheet of a nonconductive electrolytically inert mesh material over which covered substrate is electrodeposited a layer of lead dioxide. The anode is formed by covering the graphite substrate with a sheet of the inert mesh material and thereafter electrodepositing lead dioxide thereon until a smooth layer of lead dioxide completely covers the mesh material. The anodes are electrolytically stable and are not susceptible to cracking.

Stable lead dioxide anode and method for production

An electrolyte and a process for reducing lead peroxide formation when electrowinning lead from inorganic acid solutions are disclosed. In accordance with the invention, arsenic is added to an inorganic acid electrolyte containing lead, whereby oxygen is evolved at the anode while lead peroxide formation is reduced or eliminated during electrolysis.

Process for reducing lead peroxide formation during lead electrowinning

A process for recovery of substantially all lead values in battery sludge as metallic lead is disclosed. By means of the process, lead is substantially completely and efficiently recovered as metallic lead in an environmentally acceptable manner. The process comprises (a) subjecting the sludge to low temperature reducing conditions; (b) converting lead sulfates to insoluble nonsulfur containing compounds while solubilizing all sulfur materials and thereafter separating the solid residue by solid-liquid separation techniques; (c) dissolving the solid products resulting from steps (a) and (b) in an acid selected from the group consisting of fluoboric and fluosilicic acid; (d) collecting the supernatant from step (c) by means of solid-liquid separation techniques; and (e) electrowinning the lead from the collected supernatant. The lead peroxide reduction of step (a) may be effected by low temperature reducing roasts or by contacting the lead peroxide with sulfur dioxide gas or sulfites.

Method of recovering lead values from battery sludge

Stable wrought lead-calcium-tin alloys can be prepared by casting an alloy of lead having a calcium content of from about 0.02% or 0.03% to about 0.1% by weight and having a tin content such that the tin to calcium weight ratio or relative tin content is from about 7:1 to 10:1 and preferably is more than 10:1 up to about 100:1, with the proviso that the absolute tin content be from about 0.3% to about 2.0%; and thereafter cold working the casting at a time period of within about 24 hours after casting for the lead-calcium-tin alloys having a tin to calcium weight ratio of from about 7:1 to 10:1 and within about 48 hours after casting for the lead-calcium-tin alloys having a tin to calcium weight ratio of from more than 10:1 up to about 100:1. Aged work pieces heated sufficiently to dissolve the precipitated calcium phases can be similarly treated.

Growing community of inventors

Arlington, TX, United States of America

Raymond D Prengaman