Atochem

Elf Atochem S.a.

Arkema Inc.

Societe Atochem

Atofina

P C U K Produits Chimiques Ugine Kuhlmann

Raymond Commandeur

Bernard Jean Gurtner

Noelle Berger

Pierre Jay

Elie Ghenassia

Jean-Pierre Sarron

Jacques Kervennal

Henri Mathais

Rene Clair

Renato Paludetto

Jean-Jacques Masini

Massimo Morbidelli

Sergio Carra

Jean-Louis Guillaumenq

Gilles Drivon

Jaume Castella Sola

Jaime Palencia Adrubau

Giuseppe Storti

No&euml;lle Berger

Achille Pontoglio

Bernard Gorny

Daniel Missos

Dominique Audoux

R&eacute;gis Loze

Sergio Nebel

Guiseppe Storti

The invention concerns a heat transfer fluid comprising a monobenzyl-1,2,3,4-tetrahydronaphthalene or a mixture of mono-and polybenzyl-1,2,3,4-tetrahydronaphthalene and/or a mixture of partly hydrogenated polyphenyls and at least a polyphenylmethane composition.

Heat transfer fluid based on polyphenylmethanes exhibiting improved thermal stability

The invention concerns compositions comprising a mixture of mono- and polybenzyl-1,2,3,4-tetrahydronaphthalenes. The invention also concerns said compositions or a mixture of monobenzyl-1,2,3,4-tetrahydronaphthalene isomers as heat transfer fluid. Said compositions or the mixture of monobenzyl-1,2,3,4-tetrahydronaphthalene isomers are obtained by the action of benzyl chloride on 1,2,3,4-tetrahydronaphthalene in the presence of FeCl.

Mono-and polybenzyl-1,2,3,4-tetrahydronaphthalene compositions, use of said compositions or mixture of monobenzyl-,1,2,3,4-tetrahydronaphthalene as heat transfer fluid

The invention relates to a dielectric composition having improved gas absorption for electrical devices which comprises from 99% to 70% by weight of a mineral oil and from 1% to 30% by weight of at least one polyarylalkane composition.

Dielectric composition having an improved gas absorption

In a process for the continuous preparation of mono- and/or bis(mono- and/or di- and/or trichloromethyl) benzenes by gradual chlorination of the corresponding mono-or dimethylbenzenes in several reactors in cascade, the first reactor has a greater volume than each of the other reactors.

Process for the continuous preparation of mono- and/or bis(mono-and/or di-and/or trichloromethyl) benzenes

In a process for the purification by distillation of chlorinated aromatic hydrocarbons originating from the chlorination of aromatic hydrocarbons in the presence of FeCl.sub.3, the crude reaction product is first partially degassed and then directly subjected to distillation in the presence of said FeCl.sub.3.

Process for the purification of chlorinated aromatic hydrocarbons

The invention relates to a dielectric composition including at least one polyarylalkane oligomer of formula: ##STR1## in which n.sub.1 and n.sub.2 =0, 1 or 2, with the proviso that n.sub.1 +n.sub.2 =1 or 2, x=0, 1, 2, 3, 4, 5 or 6 and that the said composition has, in particular, a breakdown voltage increasing with the temperature.

Dielectric composition based on polyarylalkanes which have improved

Novel dielectric liquids for such electrical components as transformers, capacitors and cables, especially adopted for low temperature applications, comprise immixtures of benzyltoluene, (methylbenzyl)toluene, benzylxylene and (methylbenzyl)xylene, and optionally include the benzyl or methylbenzyl derivatives thereof; these immixtures are facilely prepared by chlorinating a mixture of xylene and toluene and then adding a catalytically effective amount of a Friedel-Crafts catalyst to the medium of chlorination.

Dielectrics comprising methyl/benzyl derivatives of diphenylmethane

Unique heat transfer fluid media include (methylbenzyl)xylene or a composition comprising admixture of the compounds (A): ##STR1## in which n.sub.1 +n.sub.2 =0 or 1, wherein a fraction of such compounds (A) n.sub.1 +n.sub.2 =0 and further wherein another fraction of such compounds (A) n.sub.1 +n.sub.2 =1; the tricyclic compounds (A) may be replaced, in whole or in part, by a tricyclic compound (B): ##STR2##

Heat transfer fluids comprising mono- and bis(methylbenzyl)xylene isomers

Novel dielectric liquids for such electrical components as transformers, capacitors and cables, especially adopted for low temperature applications, comprise a mixture of benzyltoluene and (methylbenzyl)xylene isomers, notably a mixture of benzyltoluene/dibenzyltoluene isomers with (methylbenzyl)xylene/di(methylbenzyl)xylene isomers.

Dielectric compositions comprising benzyltoluene/(Methylbenzyl) xylene

Benzyltoluene/benzylxylene admixtures, easily prepared via Friedel-Crafts condensation of benzyl chloride with a mixture of toluene and xylene, are useful dielectric oils exhibiting improved rigidity and are well suited for inclusion in voltage transformers, capacitors, electrical cables, and the like.

Benzyltoluenes/benzylxylenes dielectric compositions

Water-containing mixtures of at least one hydrocarbon/halocarbon and hydrochloric acid, e.g., the methyl chloride feedstream in conventional process for the synthesis of chloromethanes, are desiccated by intimately contacting such mixtures with an effective drying amount of an essentially anhydrous drying agent that includes (i) a metal sulfate, chloride or perchlorate, or (ii) phosphorus pentoxide.

Drying of hydrocarbon/hydrochloric acid/water admixtures

Unique heat transfer fluid media include (methylbenzyl)xylene or a composition comprising admixture of the compounds (A): ##STR1## in which n.sub.1 +n.sub.2 =0 or 1, wherein a fraction of such compounds (A) n.sub.1 +n.sub.2 =0 and further wherein another fraction of such compounds (A) n.sub.1 +n.sub.2 =1; the tricyciic compounds (A) may be replaced, in whole or in part, by a tricyclic compound (B): ##STR2##

Heat transfer fluids comprising mono- and bis(methylbenzyl)xylene

Process for the preparation of

Halogenated organic species, e.g., chlorinated or brominated dioxins or dibenzofurans, PCBs, and the like, are consumed by contacting such species, at a temperature of greater than 220.degree. C., with a stoichiometric excess, relative to the halogen content thereof, of at least one alkali metal alcoholate.

Destruction of halogenated organic species

Benzyltoluene/dibenzyltoluene oligomers essentially devoid of contaminating amounts of chlorine values, well adapted as dielectric liquids, are prepared by (a) condensing benzyl chloride with toluene or with lower benzyltoluene oligomers in the presence of a catalytically effective amount of ferric chloride, and then (b) directly dechlorinating the crude product of condensation, e.g., by contacting same with sodium methylate.

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Vizille, France

Raymond Commandeur