Fluor Technologies Corporation

Fluor Corporation

Fluor Technologies Coporation

Ravi Ravikumar

Paul E Koppel

Sanjiv Dabee

Denny Li

Sunil Singhal

Paul M Mathias

Satish Reddy

Johnathon Zychowicz

Jim Wilson

Richard Bazata

Brian DeSousa

Gordon Sims

Harold Sandler

Kakul Singh

Patrick Goodman

Soumya Jyoti Choudhury

Ammonia, methanol, Fischer Tropsch products, and derivatives thereof are made by using hydrogen and oxygen supplied from an electrolyzer that is at least partially powered by renewable power, resulting in green process and systems that produce green products disclosed herein. A process using biomass and renewable energy includes producing an unshifted syngas from biomass and oxygen in a gasification unit, introducing water into an electrolyzer to produce an oxygen product and a hydrogen product, and introducing the oxygen product to the gasification unit. The electrolyzer is powered by renewable energy, and the oxygen product supplies at least a portion of the oxygen to the gasification unit.

Production of ammonia, methanol, and synthesis products from one or more gasification products

In a hydrocarbon-fed steam methane reformer hydrogen-production process and system, carbon dioxide is recovered in a pre-combustion context, and optionally additional amounts of carbon dioxide are recovered in a post-combustion carbon dioxide removal, to provide the improved carbon dioxide recovery or capture disclosed herein.

Pre-combustion CO2 removal in a natural gas fed steam methane reformer (SMR) based hydrogen plant

Pre-combustion COremoval in a natural gas fed steam methane reformer (SMR) based hydrogen plant

Embodiments relate generally to systems and method for processing tars to produce benzene, toluene, and xylene (BTX). A method for processing tars may comprise distilling the tars to separate creosotes and pitch; and processing the pitch via hydropyrolysis, including both hydrogenation and hydrocracking functions, to remove heteroatoms and break down polyaromatics in the pitch and produce monoaromatics, such as BTX. A system for processing tars may comprise one or more of the following: an input stream comprising tars feeding into a column; the column configured to separate the tars into one or more creosote streams and a pitch stream; and a reactor (or a series of reactors, or beds within a single reactor), wherein the pitch stream is fed to the reactor along with a stream of hydrogen, wherein the reactor is configured to break down the pitch to produce BTX.

Processing of gasification tars to high yields of BTX

A method of producing fuel from COcomprising introducing natural gas, steam, and recovered COto a reformer to produce unshifted syngas characterized by a molar ratio of hydrogen to carbon monoxide of from about 1.7:1 to about 2.5:1; introducing the unshifted syngas to a water gas shift unit to produce a shifted syngas, wherein an amount of COin the shifted syngas is greater than in the unshifted syngas; separating the COfrom the shifted syngas to produce recycle COand a hydrogen-enriched syngas; recycling the recycle COto the reformer; introducing the unshifted syngas to a Fischer-Tropsch (FT) unit to produce an FT product, FT water, and FT tail gas, wherein the FT product comprises FT liquids and FT wax; and separating the FT liquids from the FT product to produce a fuel.

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A method of diverting municipal solid waste (MSW) from a landfill that includes receiving, at a MSW processing system, a quantity of MSW, gasifying the quantity of MSW in a gasification unit to yield a syngas stream and biochar stream, converting at least a portion of the syngas to mixed alcohols in an alcohol synthesis unit, separating the mixed alcohols into one or more alcohol products, and determining a carbon offset for diverting the MSW from the landfill to the MSW processing system.

Methods and system for decreasing gas emissions from landfills

A method of processing stranded remote gas comprising (a) introducing stranded remote gas and steam to a reforming unit to produce synthesis gas (syngas), wherein the stranded remote gas comprises methane, carbon dioxide, and sulfur-containing compounds, and wherein the syngas is characterized by a molar ratio of hydrogen to carbon monoxide of from about 1.7:1 to about 2.5:1; (b) introducing at least a portion of the syngas to a Fischer-Tropsch (FT) unit to produce an FT syncrude product, FT water, and FT tail gas, wherein the FT syncrude product comprises FT hydrocarbon liquids, wherein the FT syncrude product comprises FT wax in an amount of less than about 5 wt. %, and wherein the FT unit is characterized by an FT reaction temperature of from about 300&#xb0; C. to about 350&#xb0; C.; and (c) blending the FT syncrude product with crude oil for storage and/or transport.

Small scale modular gas to liquids plant for stranded remote gas

A method of producing hydrogen comprising receiving a sour gas comprising CO, HS, and ammonia from a sour water stripper; introducing the sour gas to an absorption system to produce an ammonia rich gas and a sulfide rich gas, wherein the ammonia rich gas comprises ammonia and CO, and wherein the sulfide rich gas comprises HS and CO; compressing the ammonia rich gas in a compressing unit to a pressure of 400-600 psig to produce a compressed ammonia rich gas; introducing the compressed ammonia rich gas to an ammonia cracker unit comprising a catalyst to produce a cracked gas, wherein the ammonia cracker unit is characterized by a cracking temperature of 450-550&#xb0; C., and wherein the cracked gas comprises hydrogen, nitrogen, and CO; and introducing the cracked gas to a PSA unit to produce hydrogen and a PSA tail gas, wherein the PSA tail gas comprises nitrogen and CO.

Production of pure hydrogen from ammonia rich sour water stripper overhead

Systems and methods for generating higher alcohols from synthesis gas produced from carbonaceous materials are described, which can include a reactor configured to produce an alcohol stream and COfrom a syngas feed. The alcohol stream can be separated in one or more downstream separators to produce a net reactor product and a methanol stream that can recycled into the reactor. The net reactor product preferably comprises higher-order alcohols such as ethanol, propanol, and butanol.

Production of higher alcohols with minimum methanol content from the gasification of carbonaceous materials

A method of producing syngas comprising receiving raw syngas from a gasification unit; introducing the raw syngas and water to a syngas scrubber to produce unshifted syngas; introducing a first portion of unshifted syngas to a first cooling unit to produce cooled unshifted syngas and a first aqueous condensate comprising cyanide in an amount of 5-200 ppmw; recycling the first aqueous condensate to the syngas scrubber; introducing a second portion of unshifted syngas to a water gas shift unit to produce shifted syngas; introducing the shifted syngas to a second cooling unit to produce cooled shifted syngas and a second aqueous condensate comprising cyanide in an amount of less than 2.5 ppmw; contacting the cooled shifted syngas with the cooled unshifted syngas to produce modified syngas; and introducing the second aqueous condensate to a sour water stripper to produce stripped water and an acid gas comprising HS, CO, and ammonia.

Method for avoiding expensive sour water stripper metallurgy in a gasification plant

A crude oil processing plant that comprises a Fischer-Tropsch reactor is disclosed. The crude oil processing plant comprises a crude oil processing section and a hydrogen production section. The hydrogen production section is coupled to a hydrocracker in the crude oil processing section to deliver a high purity hydrogen stream. The Fischer-Tropsch reactor receives a syngas stream from the hydrogen production section and produces a hydrocarbon stream. When light crude oil is processed, the hydrocracker typically has excess capacities to upgrade the hydrocarbon stream from the Fischer-Tropsch reactor.

Configurations and method of integrating a gas to liquids (GTL) plant in a refinery

A sulfuric acid production plant has a discontinuously operating back-up absorber to allow for sulfur emission control in situations where part of or even the entire sulfuric acid production plant is shut down, inoperable, or otherwise compromised. The back-up absorber receives lean solvent from a storage tank that is configured such that continuous operation of the back-up absorber is possible for several hours.

Back-up configurations and method for sulfuric acid plants

Systems and methods for pre-treatment of acid gas are presented in which ammonium is removed from the acid gas in an absorber that is operated at significantly elevated temperature using dilute phosphoric acid. While seemingly incompatible, absorbing ammonia at high heat in the absorber will allow for production of a diammonium phosphate product that is ultra-low in residual sulfurous compounds and prevent crystallization of phosphate salts due to the increased solubility of the salts in the hot diluted solvent.

Claus plant preprocessing systems and methods for removal of ammonia from claus plant feed gases

Configurations, systems, and methods for a gas-to-liquids plant are presented in which the energy demand for natural gas reformation is provided at least in part by biomass gasification to reduce or eliminate net carbon emissions. Preferred plants, systems, and methods may recycle various process streams to further reduce water demand, improve the hydrogen/carbon ratio of a feed stream to a Fischer-Tropsch process, and recover and/or recycle carbon dioxide.

Growing community of inventors

Lancaster, CA, United States of America

Ravi Ravikumar