Dow Corning Corporation

Dow Corning Toray Company, Ltd.

Gallmeyer, Jimmy H.

Randall P Sweet

Katherine L Ulman

Loren D Durfee

William Blackwood

Tsugio Nozoe

Carl M Monroe

Chi-long Lee

Gerald A Gornowicz

Robert A Ekeland

Patrick J Miller

Paul W Pretzer

Ross A Noel

Virgil L Metevia

Jimmy H Gallmeyer

Air bags which are used for safety purposes to protect occupants of vehicles such as automobiles are described together with a process for coating air bags and air bag fabrics with silicone rubber compositions. In particular the invention relates to silicone rubber coatings which cure by hydrosilylation and an air bag coated with an elastomeric coating which is the cured product of a silicone composition comprising an organopolysiloxane (A) having aliphatically unsaturated hydrocarbon or hydrocarbonoxy substituents, an organosilicon crosslinker having at least 3 silicon-bonded hydrogen atoms, a catalyst able to promote the reaction of the aliphatically unsaturated hydrocarbon or hydrocarbonoxy substituents with Si&#x2014;H groups and a reinforcing filler, wherein the organopolysiloxane (A) comprises a branched organopolysiloxane (A1) consisting of: (i) one or more Q units of the formula (SiO) and (ii) from 15 to 8000 D units of the formula RbSiOwhich units (i) and (ii) may be inter-linked in any appropriate combination, and (i{umlaut over (&#x3c5;)}) M units of the formula RRSiOwherein each Rsubstituent is selected from the group consisting of an alkyl group having from 1 to 6 carbon atoms, an alkenyl group having from 1 to 6 carbon atoms and an alkynyl group having from 1 to 6 carbon atoms, at least three Rsubstituents in the branched siloxane being alkenyl or alkynyl units, and each Rsubstituent is selected from the group consisting of an alkyl group having from 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an aryl group, an alkoxy group, an acrylate group and a methacrylate group.

Silicone coatings on air bags

A curable coating composition that exhibits improved cure and adhesion to various substrates, especially synthetic textiles used in the manufacture of air bags, comprises a composition curable by a hydrosilylation reaction, an acryloxy functional alkoxysilane or a methacryloxy functional alkoxysilane, an alkenyl functional silanol terminated organopolysiloxane, and an epoxy functional alkoxysilane. The curable coating composition is especially useful for application to synthetic textiles such as automotive air bags.

Curable coating compositions

A curable coating composition that exhibits improved cure and adhesion to various substrates, especially synthetic textiles used in the manufacture of air bags, comprises a composition curable by a hydrosilylation reaction, and includes a silicone resin, a hydrosilylation reaction inhibitor; and an adhesion promoting additive which comprises (i) an acryloxy functional alkoxysilane or a methacryloxy functional alkoxysilane, (ii) an alkenylsilanol, (iii) an organotitanium compound, (iv) a metal chelate compound, and (v) an epoxy functional alkoxysilane. A filler and a cyclic alkenyl group bearing polysiloxane can also be included in the curable coating composition. The curable coating composition is especially useful for application to synthetic textiles such as automotive air bags.

Organopolysiloxane-based compositions that are used to prepare silicone rubbers that are flame retardant and to the use of such rubbers. More specifically, flame retardant rubbers that are useful as coatings, for example, as marine deck coatings, firewall construction and fireblanket applications. The materials are resin reinforced silicone polymers used in conjunction with ceramic hollow spheres and they have demonstrated good performance in flame retardancy tests.

Silicone composition useful in flame retardant applications

A pressure sensitive adhesive composition which contains a mixture of a silicate resin, a polyorganosiloxane fluid, and a polyisobutylene polymer having at least one functionalized silicon containing moiety. One advantage of the present invention is that it provides a silicone pressure sensitive adhesive composition that has a reduced propensity for cold flow relative to many current silicone pressure sensitive adhesives.

Silicone pressure sensitive adhesive composition containing

A pressure sensitive adhesive composition comprises a mixture of (A) a silicate resin, (B) a silicone fluid, and (C) a thermoplastic multi-segmented copolymer which is a product of the reaction between a diisocyanate and a reactive polyorganosiloxane having two groups reactive with isocyanate thereon. The thermoplastic multi-segmented copolymer comprises from about 1 to about 40 weight percent hard segments derived from reactants selected from the group consisting of organic diisocyanates, organic diols, and organic diamines and from about 60 to about 99 weight percent soft segments comprising from about 15 to about 99 weight percent, based on the weight of the thermoplastic multi-segmented copolymer, of polyorganosiloxane units and from about 0 to about 70 weight percent, based on the weight of the thermoplastic multi-segmented copolymer, of polyalkylene oxide units.

The instant invention pertains to a hot-melt pressure sensitive adhesive composition wherein the composition is comprised of a silicone pressure sensitive adhesive selected from the group consisting of a mixture of (i) a silicone resin and (ii) a silicone fluid and a condensed product of (i) and (ii); the silicone pressure sensitive adhesive exhibiting tackiness and adhesiveness; the silicone pressure sensitive adhesive being blended with (iii) from about 1 to 20 weight percent, based on the total weight of (i) and (ii), of a siloxylated polyether wax. The instant invention also encompasses method of using the composition, methods of making hot-melt silicone pressure sensitive adhesive-coated substrates, and devices made using the composition.

Hot-melt silicone pressure sensitive adhesive with siloxylated polyether

Hot-melt silicone pressure sensitive adhesive compositions containing alkylmethylsiloxane waxes and methods of using the compositions are disclosed. The hot-melt silicone pressure sensitive adhesive compositions include a mixture of (i) a silicate resin, (ii) a silicone fluid, and (iii) an alkylmethylsiloxane wax having a melting point of between 30.degree. C. and 70.degree. C. The alkylmethylsiloxane wax decreases dynamic viscosity of the adhesive compositions at temperatures ranging from about 50.degree. C. to about 200.degree. C.

Silicone pressure sensitive adhesive containing alkylmethylsiloxane wax

Hot-melt silicone pressure sensitive adhesive compositions containing alkylmethylsiloxane waxes, methods of using the compositions and devices made using the compositions are disclosed. The hot-melt silicone pressure sensitive adhesive compositions include a mixture of (i) a silicate resin, (ii) a silicone fluid, and (iii) an alkylmethylsiloxane wax having a melting point of between 30.degree. C. and 70.degree. C. The alkylmethylsiloxane wax decreases dynamic viscosity of the adhesive at temperatures ranging from about 50.degree. C. to about 200.degree. C.

Hot-melt silicone pressure sensitive adhesive composition, methods of using the composition, article made using the composition, and methods of making articles using the composition. The hot-melt silicone pressure sensitive adhesive composition includes a mixture of (i) a silicone resin, (ii) a silicone fluid, and (iii) from about 0.5 to about 10 weight percent, based on the total weight of the silicone resin and the silicone fluid, of a non-flammable hydrocarbon having a weight-average molecular weight of from about 300 to about 1500 as measured by gel permeation chromatography calibrated with narrow distribution polydimethylsiloxane standards.

Method and device for delivering a bioactive agent

A method of making a hot-melt silicone pressure sensitive adhesive-coated substrate comprises (a) heating a hot-melt silicone pressure sensitive adhesive composition which includes a mixture of (i) a silicone resin, (ii) a silicone fluid, and (iii) from about 0.5 to about 10 weight percent, based on the total weight of the silicone resin and the silicone fluid, of a non-flammable hydrocarbon having a weight-average molecular weight of from about 300 to about 1500 as measured by gel permeation chromatography calibrated with narrow distribution polydimethylsiloxane standards (b) coating the heated adhesive composition onto a substrate, and (c) cooling the coated adhesive composition until it is in a generally non-flowing state.

Method of making a hot-melt silicone pressure sensitive adhesive-coated

Hot-melt silicone pressure sensitive adhesive compositions, methods of using the compositions, articles made using the compositions, and methods of making articles using the compositions. The hot-melt silicone pressure sensitive adhesive compositions include a mixture of (i) a silicone resin, (ii) a polyolimethylsiloxane fluid, and (iii) from about 0.5 to about 20 weight percent, based on the total weight of the silicone resin and the polydimethylsiloxane fluid, of a polyphenylmethylsiloxane fluid having a viscosity at 25.degree. C. of from about 5 to about 60,000 centistokes so that the adhesive will be in a generally flowing state at temperatures above about 100.degree. C., as well as being capable of transdermal drug delivery.

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Midland, MI, United States of America

Randall P Sweet