Texaco Inc.

Abb Lummus Global Inc.

Other

Randall Hughes Petty

Pei-Shing E Dai

David E Sherwood, Jr

Burton H Bartley

Chih-Hao Mark Tsang

Bobby R Martin

Joseph A Durkin

Robert J Taylor, Jr

Laurence D Neff

Mark Gilmore White

Eugene P Dai

Charles H Schrader

Charles N Campbell, Ii

Glenn Allen Clausen

David Alan Bruce

Charles N Campbell Ii

Joseph Aaron Bertrand

Disclosed is a novel binary sieve catalyst useful for olefin upgrading and fluid catalytic cracking which comprises

FCC process using binary molecular sieves having a core and shell of

Disclosed is a novel binary sieve catalyst useful for olefin upgrading and fluid catalytic cracking which comprises a crystalline zeolite metallosilicate core and a shell selected from an aluminum phosphate molecular sieve (AlPO.sub.4), a silicon-substituted aluminophosphate (SAPO), a metal aluminophosphate (MeAPO), and a crystalline metal aluminophosphate (MeAPSO) and is generally synthesized by a method comprising:

Binary molecular sieves having a core and shell of different structures

Disclosed is a novel process for the synthesis of a metal-containing aluminophosphate having a layered structure and novel optically active metal-containing aluminophosphates useful as enantio-selective catalysts, which comprises:

Synthesis of metal--containing aluminophosphates with layered structure

Disclosed is a process for converting olefinic hydrocarbons using spent FCC catalysts which comprises using spent FCC catalysts, optionally containing spent FCC additives, in the reactor/stripper part of the FCCU, instead of or in addition to a separate olefin upgrader, to upgrade C.sub.2 -C.sub.8 oligomerizable olefins, preferably propylene and ethylene, into C.sub.4 /C.sub.5 olefins and isoparaffins as well as gasoline, wherein feedstock can be product streams of the FCCU containing propylene/ethylene such as, for example, the absorber and depropanizer overheads.

Process for converting olefinic hydrocarbons using spent FCC catalyst

Disclosed is a fluid catalytic cracking process for cracking gas oils and naphtha which provides improved selectivity for C.sub.3 -C.sub.5 olefins employing a catalyst comprising a novel zeolite characterized by a large number of secondary pores, a substantially decreased Lattice Constant of below about 24.19 .ANG., and a substantially decreased Acid Site Density, attained by hydrothermal and acid-treating of an ultrastable Y-zeolite.

FCC process employing low unit cell size y-zeolites

Hydrodesulfurization of a cracked naphtha is effected in the presence of, as catalyst, an alkali metal, a metal of Group VIII, and a metal of Group VI-B on an alumina support containing a hydrotalcite-like composition.

Hydrotalcite-containing catalyst composition

A mild hydrocracking process for the hydrodemetallation (HDM), hydrodesulfurization (HDS) and hydroconversion (HC) of hydrocarbon feedstocks such as residuum feedstocks which provides increased conversion of the 1000.degree. F.+ hydrocarbon fraction to the 1000.degree. F.- fraction and increased yields of middle distillates is disclosed. The process utilizes a catalyst comprising about 2.0 to about 6.0 wt. % of an oxide of a Group VIII metal, about 12.0 to about 25.0 wt. % of an oxide of molybdenum and 0 to about 3.0 wt. % of an oxide of phosphorus supported on a porous alumina support containing about 4.0 to about 30 wt. % of silica.

Mild hydrocracking of heavy hydrocarbon feedstocks employing

Hydrodesulfurization of a cracked naphtha is effected in the presence of, as catalyst, a non-noble metal of Group VIII and a metal of Group VI-B on an alumina support containing a hydrotalcite-like composition. The process of the instant invention gives high levels of hydrodesulfurization compared to prior art magnesia-containing catalysts and lower levels of olefin saturation, and less octane reduction in the desulfurized gasoline.

Hydrodesulfurization process

A process for catalytic hydrodewaxing hydrocarbon feedstocks is disclosed. The catalyst comprises a surface-modified crystalline aluminosilicate zeolite, such as ZSM-5 type zeolite in a matrix or binder, such as alumina, having a specified metals content. The process is especially useful for dewaxing lubricating oil basestocks.

Process for catalytic dewaxing of hydrocarbon feedstocks

Hydrodesulfurization of cracked naphtha with hydrotalcite-containing

A process for hydrodewaxing a hydrocarbon feedstock boiling above about 350.degree. F. by contacting the feedstock and hydrogen at a hydrogen pressure of from about 300 to about 2000 psig at a temperature of 400.degree. to 900.degree. F. and at a space velocity of about 0.1 to about 10.0 LHSV with a catalyst comprising about 0.1 to about 23 wt. % of an oxide of a Group VIII metal, such as nickel, or an oxide of a Group VIB metal, such as molybdenum; supported on a porous alumina support containing about 50 to about 85 wt. % of a crystalline alumino-silicate zeolite of the ZSM-5 type based on the weight of the support. The catalyst is further characterized by having greater than 60% of the pore volume between 45-600 Angstroms in the 70-200 Angstrom range. The process is especially useful for dewaxing lubricating oil basestocks.

Catalytic process for dewaxing hydrocarbon feedstocks

A process for the hydrotreatment of a sulfur and metal-containing hydrocarbon feed comprises contacting said feed with hydrogen and a catalyst in a manner such that the catalyst is maintained at isothermal conditions and is exposed to a uniform quality of feed, where said catalyst has a composition comprising 3.0-5.0 wt. % of an oxide of a Group VIII metal, 14.5-24.0 wt. % of an oxide of a Group VIB metal and 0-2.0 wt. % of an oxide of phosphorus supported on a porous alumina support, and said catalyst is further characterized by having a total surface area of 150-210 m.sup.2 /g and a total pore volume of 0.50-0.75 cc/g with a pore diameter distribution such that micropores having diameters of 100-160A constitute 70-85% of the total pore volume of said catalyst and macropores having diameters of greater than 250A constitute 5.5-22.0% of the total pore volume of said catalyst. The process of the instant invention is particularly effective in achieving desired levels of hydrodesulfurization in the fraction of hydrotreated/hydrocracked petroleum resid product having a boiling point greater than 1000.degree. F.

Hydrotreatment process employing catalyst with specified pore size

A fluid catalytic cracking process for sulfur-containing petroleum charge stocks wherein sulfur contained in coke deposited on the fluidized cracking catalyst in the reactor is converted to sulfur oxides in the regenerator and removed from regenerator off-gases by incorporating a composite of alumina and bismuth oxides in a particulate cracking catalyst. Sulfur oxides produced during regeneration of the catalyst by burning the coke with air in the regenerator are captured by the alumina-bismuth oxides composite and converted to hydrogen sulfide in the cracking reactor. The hydrogen sulfide so produced is readily separated from petroleum products of the catalytic cracking reaction process.

Fluid catalytic cracking

An active alumina composite and a cracking catalyst comprising the composite useful in hydrocarbon conversion processes. The composite and catalyst are particularly useful in fluid catalytic cracking processes, wherein sulfur-containing feedstock is subjected to catalytic conversion at a temperature in the range of about 800.degree. F. to about 1300.degree. F. in the presence of the catalyst which becomes sulfided during the conversion reaction and thereafter the catalyst is subjected to regeneration by burning sulfur-containing coke from the catalyst with an oxygen-containing gas at a temperature within the range of about 800.degree. to 1500.degree. F. The novel catalyst composition comprises 90 to 99 weight percent cracking catalyst and 1 to 10 weight percent of a composite of alumina and bismuth oxides containing 0.05 to 25 weight percent bismuth, calculated as the metal. This catalyst composition has the ability to remove sulfur oxides from gases to a greater extent than catalyst compositions comprising cracking catalyst and active alumina. The composition may comprise also platinum or a platinum group metal as a carbon monoxide combustion promoter.

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Port Neches, TX, United States of America

Randall Hughes Petty