Georgia-pacific Chemicals LLC

Ramji Srinivasan

Cornel Hagiopol

Brian Lee Swift

Bobby Lee Williamson

Adam K Sniady

Kim K Tutin

John B Hines

Feng Jing

Kelly A Shoemake

Kurt D Gabrielson

Benjamin D Gapud

Stacey L Wertz

Paul S Baxter

James H Knight

Peter Boyer

Robert W Fleming

Arun Narayan

Ahmed A Iman

Natasha Wright

Binder compositions and methods for making and using same are provided. In at least one specific embodiment, the binder composition can include at least one unsaturated compound having two or more unsaturated carbon-carbon bonds and at least one free radical precursor. At least one of the unsaturated carbon-carbon bonds can be a pi-bond that is not conjugated with an aromatic moiety and can be capable of free radical addition. The free radical precursor can be present in an amount of about 7 wt % to about 99 wt %, based on the weight of the one or more unsaturated compounds.

Binder compositions and methods for making and using same

Methods for making phenolic resins modified with one or more monosaccharides and methods for making composite products therewith are provided. In at least one specific embodiment, a method for making a composite product can include contacting a plurality of cellulosic sheets with a resin composition that includes a phenolic resin and a monosaccharide. The resin composition can include about 0.5 wt % to about 30 wt % of the monosaccharide, based on a combined weight of the phenolic resin and the monosaccharide. The method can also include at least partially curing the resin composition to produce a composite product.

Modified phenolic resins for making composite products

A method for making a composite product can include combining a plurality of lignocellulose substrates and a binder to produce a resinated furnish. The binder can be or include a polyphenolic compound, a free radical precursor, and an unsaturated compound having two or more unsaturated carbon-carbon bonds. At least one of the unsaturated carbon-carbon bonds is a pi-bond that is not conjugated with an aromatic moiety and is capable of free radical addition. The method can also include pressing the resinated furnish between at least two surfaces in a press, where at least one of the at least two surfaces can be a porous surface, and at least partially curing the binder in the resinated furnish to produce a composite product.

Methods for making composite products containing lignocellulose substrates

Binder compositions and methods for making and using same are provided. In at least one specific embodiment, the binder composition can include at least one polyphenolic compound, at least one unsaturated compound, and at least one free radical precursor. The unsaturated compound can have two or more unsaturated carbon-carbon bonds. At least one of the unsaturated carbon-carbon bonds can be a pi-bond that is not conjugated with an aromatic moiety and is capable of free radical addition.

Fiberglass mats, binder compositions, and methods for making the same are provided. The fiberglass mat can include a plurality of glass fibers and an at least partially cured binder composition. The binder composition, prior to at least partial curing, can include a first copolymer modified by reaction with one or more base compounds. The first copolymer can include one or more unsaturated carboxylic acids, one or more unsaturated carboxylic anhydrides, or a combination thereof, and one or more vinyl aromatic derived units. The first copolymer can have a weight average molecular weight (Mw) of about 500 to about 200,000. The first copolymer can be present in an amount ranging from about 60 wt % to about 95 wt %, based on a combined weight of the first copolymer and the one or more base compounds.

Binder compositions for making fiberglass products

Binder compositions and methods for making and using same are provided. The binder composition can include at least one polyamidoamine prepolymer and at least one copolymer. The copolymer can include one or more vinyl aromatic derived units, and one or more unsaturated carboxylic acids, one or more unsaturated carboxylic anhydrides, or a combination thereof. The copolymer can be modified by reaction with one or more base compounds.

An aqueous binder composition, useful for making fiber products, especially fiberglass insulation, comprising an aqueous substantially alkaline (pH of at least 5.0) solution of a polyol and a hydrolyzed (solubilized) copolymer of maleic anhydride and a vinyl aromatic compound, preferably styrene (i.e., a SMA copolymer); the copolymer is solubilized using ammonia, an ammine, a primary alkanolamines (preferably monoethanolamine), a secondary alkanolamine (preferably diethanolamine (DEA)), a tertiary alkanolamine (preferably triethanolamine (TEA)), or a mixture thereof and the binder composition is cured as a consequence of cross-linking, esterification reactions between pendant carboxyls on the solubilized (hydrolyzed) copolymer (SMA) chains and hydroxyl groups of the polyol, including the diethanolamine and/or triethanolamine preferably used in the solubilization of the SMA.

Formaldehyde free binder

Binder compositions for making fiberglass products and methods for making and using same are provided. The binder composition can include a phenol-aldehyde resin or a mixture of Maillard reactants and one or more modifiers selected from the group consisting of a copolymer comprising one or more vinyl aromatic derived units and at least one of maleic anhydride and maleic acid; an adduct of styrene, at least one of maleic anhydride and maleic acid, and at least one of an acrylic acid and an acrylate; and one or more latexes.

Modified binders for making fiberglass products

The present invention relates to formaldehyde scavenger treatments for porous fiberglass material having formaldehyde emitting binders thereon. The invention also relates to methods of making porous fiberglass material having reduced formaldehyde emissions.

Porous fiberglass materials having reduced formaldehyde emissions

A process for making a fibrous product using a binder based on a formaldehyde-containing resin and especially for making fiberglass insulation products, and to the fibrous products themselves, wherein the fibrous product has a backing sheet affixed thereto and the backing sheet is coated or impregnated with a formaldehyde scavenger composition, with the result that the fibrous products exhibit a reduced level of formaldehyde emission.

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Johns Creek, GA, United States of America

Ramji Srinivasan