US Government As Represented by the Secretary of the Army

University of Massachusetts

Other

Ramaswamy Nagarajan

Jayant Kumar

Ferdinando F Bruno

Lynne Ann Samuelson

Susan Tripathy, Legal Representative

Wei Liu

Michael S Sennett

Bon-Cheol Ku

Ravi Mosurkal

Weeradech Kiratitanavit

Joey L Mead

Julie Chen

Zhiyu Xia

Subhalakshmi Nagarajan

Soo-Hyoung Lee

Sucharita Roy

Sharavanan Balasubramaniam

Todd Emrick

Sukant K Tripathy

E Bryan Coughlin

Lian Li

Pradeep Kurup

Shivshankar Sivasubramanian

Susan J Braunhut

Donna McIntosh

Bridgette Budhlall

Mario J Cazeca

Klaudia Foley

Ryan M Bouldin

Zarif Farhana Mohd Aris

Jungrae Park

Vishal Bavishi

Sethumadhavan Ravichandran

Timothy Ponrathnam

Shiran Yu

Claire Lepont

Siddhant Iyer

Disclosed herein is a curable composition with high optical transparency and good oxygen and moisture barrier properties, compositions for making the same, and methods of making and of using the same.

Oxygen and moisture barrier compositions and related methods

A synergistic flame retardant composition comprising a phenolic compound comprising condensed tannin, hydrolysable tannin, lignin, cardanol, quercetin, catechin, epicatechin, anthocyanidin, catechol, dopamine, hydroxytyrosol, adrenaline, 4-hydroxyphenylacetic acid, gallic acid, digallic acid, methyl gallate, ellagic acid, phloroglucinol, hexahydroxydiphenic acid, luteic acid, casuarictin, or a combination thereof; and a phosphorus-containing compound comprising a Ccarbocyclic polyol substituted with at least one phosphate group.

Synergistic flame retardant compositions and fiber blends including the same

A flexible circuit module is disclosed. The flexible circuit module includes a fabric member including a plurality of fibers having non-conductive elements, and conductive elements oriented through the plane of the fabric. Each conductive element includes a first fiber element strand and a first unterminated end opposite the first fiber element strand, and a second fiber element strand having second unterminated end opposite the second fiber element strand. The fabric member further includes a first side with the first fiber element strands extending therefrom and a second side with second fiber element strands extending therefrom. A first hook-and-loop busbar is conductively connected to the first fiber element strands and a second hook-and-loop busbar is conductively connected to the second fiber element strands.

Electrical system with hook-and-loop busbars

An electrochemical tongue can be used for detection of metal ions. The reference electrode of the electrochemical tongue can be coated with a polymer. More than one reference electrode can be used, and the electrochemical tongue can be inserted into a cone penetrometer for portable, in situ analysis.

Electrochemical tongue

A method of forming a crosslinked polyphenol, the method comprising: reacting a bio-based phenolic compound comprising at least one phenolic hydroxyl group, with a crosslinking agent comprising at least two functional groups reactive with the phenolic hydroxyl group, wherein the at least two functional groups are each independently a halogen group, acid halide group, sulfonyl halide group, glycidyl group, anhydride group, or a combination comprising at least one of the foregoing, to provide the crosslinked polyphenol.

Crosslinked phenolic compound, method of forming, and polymer composition containing the same

A surfactant produced by reacting naturally occurring polysaccharides that are not water soluble with a hydrophilic substituent on a carboxylic portion of the polysaccharide. In a second reaction, the surfactant is further substituted on a hydroxylic portion with a hydrophobic or lipophilic substituent, so as to make the reaction product both water soluble and capable of attracting oily material that is hydrophobic to be removed from a substrate by cleaning in water. Methods of making the surfactant and the follow-on reaction product are described.

Hydrophilic modification of water insoluble polysaccharide as surface-active agents

A chemical compound of structural formula (I) useful in preparation of flame retardant materials is disclosed. Homopolymer, and copolymers of a compound of formula (I), as well as methods of preparing said homo- and copolymers are also disclosed. Polymers described herein advantageous possess low heat release capacities and high char yields.

Flame-retardant derivatives

Wireless strain and displacement sensors wirelessly monitor structural health and integrity, and are made by printing inductor-interdigital capacitor sensing circuits on a variety of substrates, including ceramic substrates, with thermally processable conductive inks. Sensors of the invention can be employed to detect strain and displacement of civil structures, such as bridges and buildings. The sensors include sensing elements that are mounted or printed on stiff, inflexible substrates, which prevent the sensing elements from bending, stretching, or otherwise warping when the sensor is strained. An interlayer between the sensing elements allows the sensing elements to move with respect to each other during application of strain. Thus, strain causes the sensing elements to move but not to deform, causing changes in sensor resonance that can be detected through wireless radio-frequency interrogation. Because the sensing elements do not change shape when under strain, the sensor can undergo millions of measurement cycles before breaking.

Wireless passive radio-frequency strain and displacement sensors

Metal flakes, an organic metal precursor, an organic solvent and either no binder, or a volatile or a thermally decomposable binder are combined to form a paste. The paste is deposited in a circuit pattern on a substrate and the circuit pattern is cured. While curing, the organic metal precursor decomposes to leave an electrically conductive path, and the printed circuit is thus formed. A precursor to an electrically conductive circuit material includes an organic metal precursor, metal microparticles, and an organic solvent. The method can be employed to form printed circuits, for a variety of electrical, electronic and sensing application, such as crack detection in ceramic, plastics, concrete, wood, fabric, leather, rubber or paper and composite materials.

Conductive formulations for use in electrical, electronic and RF applications

A method for synthesizing a biocompatible, water-soluble oligo/polyflavanoid, includes polymerizing an optionally substituted flavanoid with a polymerization agent in the presence of a biocompatible polymerization solubilizer, thereby producing the biocompatible, soluble oligo/polyflavanoid. Also included is a biocompatible, soluble, oligo/polyflavanoid or a pharmaceutically acceptable salt, solvate, or complex thereof. Also included are methods of treating a subject for cancer, cardiac damage, viral infection, and obesity.

Synthesis of oligo/poly(catechins) and methods of use

An assembled hematin is formed by depositing hematin on an electrically charged substrate in one or more layers alternating with one or more layers of polyelectrolyte, preferably a cationic polymer. In a method for polymerizing an aromatic monomer, the assembled hematin is contacted with the monomer and a template, preferably an anionic polymer. In a method for polymerizing aniline, the aniline, sulfonated multi walled carbon nano tubes, PEG hematin and a reaction initiator are dispersed in water.

Assembled hematin, method for forming same and method for polymerizing aromatic monomers using same

Hematin, a hydroxyferriprotoporphyrin, is derivatized with one or more non-proteinaceous amphipathic groups. The derivatized hematin can serve as a mimic of horseradish peroxidase in polymerizing aromatic monomers, such as aromatic compounds. These derivatized hematins can also be used as catalysts in polymerizing aromatic monomers, and can exhibit significantly greater catalytic activity than underivatized hematin in acidic solutions. In one embodiment, polymerization is in the presence of a template, along which aromatic monomers align. An assembled hematin includes alternating layers of hematin and a polyelectrolyte, which are deposited on an electrically charged substrate. Assembled hematin can also be used to polymerize aromatic monomers.

Polymerization of aromatic monomers using derivatives of hematin

The invention relates to a novel method for enzymatic polymerization which includes (1) obtaining a reaction mixture including a monomer, a template, and an enzyme; and (2) incubating the reaction mixture for a time and under conditions sufficient for the monomer to align along the template and polymerize to form a polymer-template complex. The template can be a micelle, a borate-containing electrolyte, or lignin sulfonate. Such a complex possesses exceptional electrical and optical stability, water solubility, and processibility, and can be used in applications such as light-weight energy storage devices (e.g., rechargeable batteries), electrolytic capacitors, anti-static and anti-corrosive coatings for smart windows, and biological sensors.

Enzymatic polymerization

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Dracut, MA, United States of America

Ramaswamy Nagarajan