Fuelcell Energy, Inc.

Ramakrishnan Venkataraman

Mohammad Farooque

Chao-yi Yuh

Joseph M Daly

Zhiwen Ma

George P Berntsen

Jin-Yun Wang

Carla Juhas

April Corpuz

Fred C Jahnke

Lawrence J Novacco

Stephen Jolly

Eric Nuhfer

Scott C Blanchet

William J Snyder

Matthew Lambrech

Pinakin S Patel

Keith E Davis

Michael L Quatannens

Michael Cramer

Eric Hansell

Ludwig Lipp

Ling Chen

Alan Russell Barlow

Louis F Ernst, Jr

Daniela Nedu

Michael P Quatannens

Joseph P McInerney

William Livingood

Carla Niederhofer

Alan Barlow

A method for controlling a carbon dioxide utilization in a fuel cell assembly includes: measuring a voltage across the fuel cell assembly; determining an estimated carbon dioxide utilization of the fuel cell assembly based on at least the measured voltage across the fuel cell assembly by determining an expected voltage of the fuel cell assembly based on at least a temperature of the fuel cell assembly, a current density across the fuel cell assembly, a fuel utilization of the fuel cell assembly, and a cathode oxygen utilization of the fuel cell assembly; determining the estimated carbon dioxide utilization based on a comparison between the measured voltage and the determined expected voltage; comparing the determined estimated carbon dioxide utilization to a predetermined threshold utilization; and upon determining that the determined estimated carbon dioxide utilization is higher than the predetermined threshold utilization, reducing the carbon utilization of the fuel cell assembly.

System including fuel cell assembly voltage monitor

Disclosed here is a supported catalyst comprising a thermally stable core, wherein the thermally stable core comprises a metal oxide support and nickel disposed in the metal oxide support, wherein the metal oxide support comprises at least one base metal oxide and at least one transition metal oxide or rare earth metal oxide mixed with or dispersed in the base metal oxide. Optionally the supported catalyst can further comprise an electrolyte removing layer coating the thermally stable core and/or an electrolyte repelling layer coating the electrolyte removing layer, wherein the electrolyte removing layer comprises at least one metal oxide, and wherein the electrolyte repelling layer comprises at least one of graphite, metal carbide and metal nitride. Also disclosed is a molten carbonate fuel cell comprising the supported catalyst as a direct internal reforming catalyst.

Supported nickel catalysts used as direct internal reforming catalyst in molten carbonate fuel cells

An end cell assembly for a fuel cell stack includes an end plate and at least two inactive anode parts disposed adjacent to the end plate. Each inactive anode part comprises a nickel foam anode disposed directly above an anode current collector and a separator sheet disposed 5 above the nickel foam anode.

Fuel cell inactive end cell design to improve electric and mechanical contact

A fuel cell system includes a fuel cell unit configured to generate an amount of electrical power for supply to a varying electrical load and a fuel cell controller configured to receive a first indication that the varying electrical load is at a local maximum within a predetermined period, and, in response, operate the fuel cell unit with an operational parameter having a first value such that the fuel cell unit produces a limited maximum amount of electrical power that is a predetermined percentage of a maximum rated power output of the fuel cell unit. The fuel cell controller is also configured to receive an indication that the varying electrical load has reduced, and, in response, operate the fuel cell unit with the operational parameter having a second value such that the fuel cell unit produces an amount of electrical power below the limited maximum amount of electrical power.

Fuel cell load cycling to support the electric grid

A system for capturing carbon dioxide in flue gas includes a fuel cell assembly including at least one fuel cell including a cathode portion configured to receive, as cathode inlet gas, the flue gas generated by the flue gas generating device or a derivative thereof, and to output cathode exhaust gas and an anode portion configure to receive an anode inlet gas and to output anode exhaust gas, a fuel cell assembly voltage monitor configured to measure a voltage across the fuel cell assembly, and a controller configured to receive the measured voltage across the fuel cell assembly from the fuel cell assembly voltage monitor, determine an estimated carbon dioxide utilization of the fuel cell assembly based on the measured voltage across the fuel cell assembly, and reduce the carbon dioxide utilization of the fuel cell assembly when the determined estimated carbon dioxide utilization is above a predetermined threshold utilization.

A fuel cell system includes at least one topping fuel cell module including a topping anode portion configured to output a topping anode exhaust, and a topping cathode portion configured to output a topping cathode exhaust; at least one bottoming fuel cell module including a bottoming anode portion configured to output a bottoming anode exhaust, and a bottoming cathode portion configured to output a bottoming cathode exhaust; and an electrochemical hydrogen separation unit configured to receive at least a portion of the topping anode exhaust, to output a hydrogen-rich stream, and to output a CO-rich stream. The bottoming anode portion is configured to receive the CO-rich stream from the electrochemical hydrogen separation unit.

High efficiency fuel cell system with hydrogen and syngas export

A high efficiency fuel cell system includes a topping fuel cell assembly including a topping cathode portion and a topping anode portion; a carbon dioxide separation unit that receives at least a portion of an anode exhaust stream output from the topping anode portion and separates the portion of the anode exhaust stream into a carbon dioxide stream and a carbon dioxide depleted stream; and a bottoming fuel cell assembly including a bottoming cathode portion and a bottoming anode portion. The bottoming anode portion receives the carbon dioxide depleted stream output from the carbon dioxide separation unit. The carbon dioxide depleted stream being richer in hydrogen than the portion of the anode exhaust stream output from the topping anode portion.

High efficiency fuel cell system with intermediate COrecovery system

A method for addressing electrical grid frequency changes by a fuel cell system includes measuring, by a frequency sensor, a frequency of an electrical grid, determining that the frequency of the electrical grid differs from a normal frequency of the electrical grid by a threshold, determining, based at least in part on the measured frequency, an AC power setpoint bias, applying a magnitude limit, a rate-of-change limit, and a duration limit to the determined AC power setpoint bias to generate a limited power setpoint bias, generating a frequency adjusted power setpoint based on the limited power setpoint bias, and providing the frequency adjusted power setpoint to one or more control modules of the fuel cell system such that the fuel cell system adjusts a power output based on a difference between the measured frequency and the normal frequency.

Fuel cell response to electrical grid frequency events

A load-following fuel cell system for a grid system operating with a high penetration of intermittent renewable energy sources includes a baseload power generation module and a load-following power generation module. The baseload power generation module provides a baseload power to the grid system and includes a high-efficiency fuel cell system. The high-efficiency fuel cell system includes a topping module and a bottoming module. The topping module and the bottoming module are connected in series and the topping module provides an exhaust stream to the bottoming module. The load-following power generation module provides a load-following power to the grid system and includes an energy storage system that separates and stores hydrogen contained in the exhaust stream and a power generation system having one or more fuel cells. The power generation system receives the hydrogen from the energy storage system to provide the load-following power.

Load-following fuel cell system with energy storage

A high efficiency fuel cell system includes a topping fuel cell assembly that includes a topping cathode portion and a topping anode portion, as well as a bottoming fuel cell assembly that includes a bottoming cathode portion and a bottoming anode portion. The assembly also includes a flue gas generating device configured to provide flue gas to the topping cathode portion and/or the bottoming cathode portion, and an oxidizer assembly configured to (i) oxidize anode exhaust output from the bottoming anode portion with air and/or oxygen to generate carbon dioxide-containing exhaust and (ii) generate waste heat for heating the flue gas before the flue gas is provided to the topping cathode portion and/or the bottoming cathode portion. A separation assembly is configured to receive the carbon dioxide-containing exhaust from the oxidizer assembly and to separate carbon dioxide from the carbon dioxide-containing exhaust.

High-efficiency fuel cell system with carbon dioxide capture assembly and method

A high efficiency fuel cell system adapted to receive flue gas from a flue gas generating device and to capture carbon dioxide from the flue gas, the high efficiency fuel cell system comprising a topping fuel cell assembly comprising a topping cathode portion and a topping anode portion, a bottoming fuel cell assembly comprising a bottoming cathode portion and a bottoming anode portion, wherein the bottoming anode portion receives anode exhaust output from the topping anode portion, and a separation assembly configured to receive carbon dioxide-containing exhaust and to separate carbon dioxide from the carbon dioxide-containing exhaust, wherein the carbon dioxide-containing exhaust is one of anode exhaust output from the bottoming anode portion and a gas derived from the anode exhaust output from the bottoming anode portion, and wherein at least one of the topping cathode portion and the bottoming cathode portion receives at least a portion of the flue gas output from the flue gas generating device.

High-efficiency molten carbonate fuel cell system with carbon dioxide capture assembly and method

A high efficiency fuel cell system comprising a topping fuel cell assembly comprising a topping cathode portion and a topping anode portion; and a bottoming fuel cell assembly comprising a bottoming cathode portion and a bottoming anode portion, wherein the bottoming anode portion receives anode exhaust output from the topping anode portion and the topping cathode portion receives cathode exhaust from the bottoming cathode portion, and wherein the topping fuel cell assembly has a greater number of fuel cells than the bottoming fuel cell assembly so that the topping fuel cell assembly utilizes more fuel than the bottoming fuel cell assembly.

High-efficiency molten carbonate fuel cell system and method

A modular fuel cell stack assembly comprising a plurality of fuel cell stacks, each of the stacks having a plurality of stack faces and a plurality of stack corners formed between the stack faces, wherein the plurality of stack faces include a cathode inlet face adapted to receive oxidant gas for use in a cathode side of the fuel cell stack, a cathode outlet face adapted to output cathode exhaust from the cathode side, an anode inlet face adapted to receive fuel for use in an anode side of the fuel cell stack and an anode outlet face adapted to output anode exhaust from the anode side, and wherein at least one of the cathode inlet face, cathode outlet face, anode inlet face and anode outlet face is an open face without a manifold, and a containment structure for housing the plurality of fuel cell stacks and for providing fuel and oxidant gas to said fuel cell stacks, the containment structure including at least one sealed chamber for sealingly enclosing and isolating at least one open face. Also provided is a modular fuel cell assembly comprising a plurality of fuel cell stacks, an oxidizer disposed centrally of the fuel cell stacks and adapted to receive anode exhaust from the fuel cell stacks, to generate oxidant gas using the anode exhaust and to distribute the oxidant gas to the fuel cell stacks, and a containment structure for housing the plurality of fuel cell stacks and the oxidizer and adapted to receive fuel and distribute the fuel to the fuel cell stacks.

Growing community of inventors

Danbury, CT, United States of America

Ramakrishnan Venkataraman