Exxon Research and Engineering Company

Ramachandra A Nadkarni

Rollie B Williams

Gopal H Singhal

Metal constituents are recovered from the heavy bottoms produced during the liquefaction of coal and similar carbonaceous solids in the presence of a catalyst containing metal constituents by reducing the carbonaceous content of the heavy bottoms, contacting the resultant heavy bottoms deficient in carbonaceous material with an aqueous solution of a mineral acid in the presence of an added alcohol and an added oxidizing agent to extract the metal constituent from the insoluble catalyst residues into the aqueous solution, and using the metal constituents extracted as constituents of the catalyst. Preferably, the metal constituent comprising the catalyst is molybdenum, the mineral acid is sulphuric acid, hydrochloric acid or phosphoric acid, the oxidizing agent is hydrogen peroxide and the alcohol is methanol. In a preferred embodiment of the invention, the carbonaceous content of the heavy bottoms is reduced by subjecting the heavy bottoms to a solvent extraction at elevated temperature and pressure with a hydrocarbon solvent in the presence of molecular hydrogen.

Recovery of catalyst from coal liquefaction residues

Coal, oil shale and similar carbonaceous solids are beneficiated by subjecting the solids to electromagnetic radiation having a frequency between about 0.1 MHz and about 10.sup.5 MHz in the presence of an aqueous acid solution. The electromagnetic energy enables the acid to solubilize a substantial portion of the mineral matter contained in the solids at low temperatures and pressures, thereby producing beneficiated carbonaceous solids containing relatively small amounts of inorganic constituents.

Coal and oil shale beneficiation process

In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by treating them with electromagnetic radiation having a frequency between about 0.10 MHz and about 10.sup.5 MHz in the presence of water or other aqueous medium. During the treatment step, the electromagnetic radiation facilitates the extraction of alkali metal constituents from the water-insoluble alkali metal compounds comprising the alkali metal residues. The resultant aqueous solution enriched in water-soluble alkali metal constituents is then separated from the particles depleted in alkali metal constituents and recycled to the gasification process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

Growing community of inventors

Baytown, TX, United States of America

Ramachandra A Nadkarni