Wilson Greatbatch Ltd.

Eleanor & Wilson Greatbatch Foundation

Other

Ralph T Mead

Wilson Greatbatch

Frank W Rudolph

Norbert W Frenz

Esther S Takeuchi

Robert L McLean

Barry C Muffoletto

Steven J Ebel

John M Greenwood, Jr

Michael A Zelinsky

Clifford J Post

Pamela P Keister

Ester S Takeuchi

A solid cathode liquid organic electrolyte alkali metal high rate cell wherein a combination of an elongated alkali metal anode and elongated solid cathode with separator therebetween is wound to form an anode-cathode subassembly having a jellyroll type configuration and wherein the combination is shaped so that the resulting sub-assembly has a substantially rectangular cross-section. The anode-cathode sub-assembly is placed in a conductive cell casing of prismatic shape having opposed flat faces, a lead of either the anode or cathode is attached to the cell casing depending upon whether case positive or case negative electrical configuration is desired and a lead of the other of the anode or cathode is connected to an electrical connector means extending through the casing in an insulated manner. The anode and cathode and separator are in face-to-face contact throughout the entire cross-section of the subassembly.

Prismatic high rate cell

A solid cathode liquid organic electrolyte alkali metal high rate cell wherein a combination of an elongated alkali metal anode and elongated solid cathode with separator therebetween is wound to form an anode-cathode subassembly having a jellyroll type configuration and wherein the combination is shaped so that the resulting sub-assembly has a substantially rectangular cross-section, the shaping of the combination being done either simultaneously with or subsequent to the winding thereof. The anode-cathode sub-assembly is placed in a conductive cell casing of prismatic shape having opposed flat faces, a lead of either the anode or cathode is attached to the cell casing depending upon whether case positive or case negative electrical configuration is desired and a lead of the other of the anode or cathode is connected to an electrical connector means extending through the casing in an insulated manner. Liquid electrolyte is introduced to the anode-cathode sub-assembly in the casing whereupon the casing then is sealed closed. The foregoing provides a new and improved prismatic high rate battery which significantly reduces the time required to manufacture the cell stack assembly while maintaining the requisite performance, safety and reliability standards in operation.

A cathode produced from a new process for manufacturing a cathode component from a free-standing sheet of cathode material, is described. The process comprises a first step of adjusting the particle size of the cathode active material to a useful size followed by mixing with binder and conductive additives suspended in a suitable solvent to form a paste. The paste is then fed into a series of roll mills to form the sheet material, or the paste can first be pelletized before the rolling step. The cathode sheet material is dried and punched into cathode plates having a myriad of geometric shapes suitable for cathode preparation by compressing a current collector between two plates of the cathode material.

Cathode component for use in electrochemical cells

A solid cathode liquid organic electrolyte alkali metal high rate cell wherein a combination of an elongated alkali metal anode and elongated solid cathode with separator therebetween is wound to form an anode-cathode subassembly having a jellyroll type configuration and wherein the combination is shaped so that the resulting sub-assembly has a substantially rectangular cross-section, the shaping of the combination being done either simultaneously with or subsequent to the winding thereof. The anode-cathode sub-assembly is placed in a conductive cell casing of prismatic shape having opposed flat faces, a lead of either the anode or cathode is attached to the cell casing depending upon whether case positive or case negative electrical configuration is desired and a lead of the other of the anode or cathode is connected to an electrical connector means extending through the casing in an insulated manner. Liquid electrolyte is introduced to the anode-cathode sub-assembly in the casing whereupon the casing then is sealed closed. The foregoing provides a new and improved prismatic high rate battery which significantly reduces the time required to manufacture the cell stack assembly while maintaining the requisite performance, safety and reliability standards in operation,

Method of making prismatic cell

A new process for manufacturing a cathode component from a free-standing sheet of cathode material, is described. The process comprises a first step of adjusting the particle size of the cathode active material to a useful size followed by mixing with binder and conductive additives suspended in a suitable solvent to form a paste. The paste is then fed into a series of roll mills to form the sheet material, or the paste can first be pelletized before the rolling step. The cathode sheet material is dried and punched into cathode plates having a myriad of geometric shapes suitable for cathode preparation by compressing a current collector between two plates of the cathode material.

Process for making cathode components for use in electrochemical cells

A solid cathode liquid organic electrolyte lithium cell for delivering high current pulses comprising a casing, a cathode structure in the casing comprising a plurality of plates in spaced apart relation, a lithium anode comprising a plurality of anode sections interposed between the cathode plates, a non-aqueous liquid organic electrolyte comprising the combination of a lithum salt and an organic solvent in the casing operatively contacting the anode and the cathode an electrical connection provided to the anode and an electrical connection provided to the cathode. In accordance with one aspect of the invention the cathode includes as active material Ag.sub.x V.sub.2 O.sub.y where x is in the range from about 0.5 to about 2.0 and y is in the range from about 4.5 to about 6.0 which advantageously has high volumetric capacity and high rate capability with the result that the cell of the present invention delivers high capacity, shows good current pulsing behavior at various levels of discharge, and has a sloping discharge cause enabling end of life to be predicted.

Non-aqueous lithium battery

A solid cathode liquid organic electrolyte lithium cell for delivering high current pulses comprising a casing, a cathode structure inthe casing comprising a plurality of plates in spaced apart relation, a lithium anond comprising a plurality of anode sections interposed between the cathode plates, a non-aqueous liquid organic electrolyte comprising the combination of a lithum dalt and an organic solvent in the casing operatively contacting the anode and the cathode an electrical connection provided to the anode and an electrical connection provided to the cathode. In accordance with one aspect of the invention the cathode includes as active material Ag.sub.x V.sub.2 O.sub.y where x is in the range from about 0.5 to about 2.0 and y is in the range from about 4.5 to about 6.0 which advantageously has high volumetric capacity and high rate capability with the result that the cell of the present invention delivers high capacity, shows good current pulsing behavior at various levels of discharge, and has a sloping discharge cause enabling end of life to be predicted. In accordance with another aspect of the present invention, the anode comprises a continuous elongated lithium element enclosed within a separator and folded into a plurality of sections interposed between the cathode plates, each of which individually is enclosed within separator material thereby enhancing the reliability of the cell. The cell of the present invention finds advantageous use as a power source for an implantable cardiac defibrillator.

Non-agueous lithium battery

A lithium-iodine cell comprising a casing of electrically conducting material, an anode including a lithium element within the casing, an electrical conductor operatively connected to the lithium element and extending out from the casing, and a cathode comprising iodine-containing material in operative contact with both the casing and the lithium element. The anode electrical conductor is completely sealed from the rest of the cell, and the casing serves as the cathode current collector. The anode operative surface is provided with a coating of an organic electron donor material. The anode conductor is enclosed within the combination of an insulator element within the casing, an isolator element between the insulator and the conductor, and a ferrule having one end within the insulator and the other end extending from the casing. During assembly, the cathode material is introduced in heated form and a filling element is employed which serves to keep the edge of the casing open end clean to facilitate subsequent welding of a lid to the casing.

Method of making a lithium-iodine cell

A lithium-iodine cell comprising a casing of electrically conducting material, an anode including a lithium element within the casing, an electrical conductor operatively connected to the lithium element and extending out from the casing, and a cathode comprising iodine-containing material in operative contact with both the casing and the lithium element. The anode electrical conductor is completely sealed from the rest of the cell, and the casing serves as the cathode current collector. The lithium anode element is shaped in a manner increasing the area of the operative surface thereof and enhancing the bond to the anode conductor, and the anode operative surface is provided with a coating of an organic electron donor material. The anode conductor is enclosed within the combination of an insulator element within the casing, an isolator element between the insulator and the conductor, and a ferrule having one end associated with the insulator within the casing and the other end extending from the casing. After assembly, the cathode material is introduced in heated form by means of a filling element through an opening in the lid of the casing which subsequently is closed.

Lithium-iodine cell

A lithium-iodine cell comprising a casing of electrically conducting material, an anode including a lithium element within the casing, an electrical conductor operatively connected to the lithium element and extending out from the casing, and a cathode comprising iodine-containing material in operative contact with both the casing and the lithium element. The anode electrical conductor is completely sealed from the rest of the cell, and the casing serves as the cathode current collector. The anode operative surface is provided with a coating of an organic electron donor material. The anode is enclosed within an insulator element within the casing and a ferrule having one end within the insulator and the other end extending from the casing.

Methods for making lithium-iodine cell

A lithium-bromine cell comprising a casing which can be of electrically conducting material and containing a lithium anode element from which a sealed conductor extends through the casing. A filling element which can be of electrically conducting material and which has a passage therethrough is fixed to the sealed casing with one end of the passage in communication with the interior of the casing and the other end externally exposed. Bromine is introduced through the passage to the interior of the casing into operative relationship with the lithium anode whereupon the passage is closed to complete the cell. The electrically conducting casing serves as a cathode current collector in operative contact with the bromine cathode, and after closing of the passage the electrically conducting filling element serves as an electrical terminal for the cell. An electrical potential difference exists between the terminal and the anode conductor during operation of the cell.

Method of making a lithium-bromine cell

A lithium-iodine cell comprising a region of iodine-containing cathode material having at least two surface portions, a current collector element operatively contacting one of the surface portions and a lithium anode element operatively contacting the other cathode surface. The lithium anode element is embraced by a holder in a manner exposing a surface of the element to the cathode material and sealing the corresponding anode current collector element from exposure to the cathode material, the holder being of a material which does not exhibit electronic conduction when exposed to iodine. The anode and cathode current collectors have extending lead portions, and the cathode lead is insulated from the lithium anode element. A pair of cells are combined, being heat sealed together around the peripheries, with the corresponding cathode regions contacting opposite surfaces of a separator sheet to form a battery.

Growing community of inventors

Kenmore, NY, United States of America

Ralph T Mead