Desoto, Inc.

Betzdearborn, Inc.

Other

Rohm and Haas Company

Commonwealth Edison Company

Ralph L Minnis

John A Kelly

Frank J Ragas

David B Mitchell

Steven M Deboo

Gerson E Beauchamp

Thomas Peter Curran

James D Haff

Phillip M Egerbrecht

Rashmi Patwardhan

Wun Ten Tai

Joseph D Bates

Edward Joseph Murphy

Karel Kriz

Steve J Vargo

Elias P Moschovis

James J Killeen

Mark J Deschryver

Gene V Wayman

A novel high-purity polymer dispersant and sludge conditioner added to the feedwater entering the secondary side of a nuclear steam generator for minimizing the accumulation of metal-oxide deposits within the nuclear steam generator during the continuing operation of the generator is disclosed. The high-purity polymer is selected from a group consisting of acrylic acid polymer, methacrylic acid polymer, acrylate polymer, methacrylate polymer, copolymers, and terpolymers, acrylate/acrylamide copolymer, acrylate/methacrylate copolymer, terpolymers, and mixtures thereof. Methods of making and applying the polymer dispersant and sludge conditioner are described. Means for removing the metal oxides and polymer from the blowdown stream are disclosed.

Polymer dispersants and methods of use in a nuclear steam generator

There is provided a composition comprising tannin containing hydroxyl groups which has been (a) chemically modified by reaction of at least one of said hydroxyl groups with at least one member selected from the group consisting of an esterification agent (e.g. acetic anhydride), etherification agent (e.g. dichloromethane or quaternary organic amine such as N-(3-chloro-2-hydroxypropyl) trimethyl ammonium chloride) to form the corresponding ester, or ether, through said hydroxyl group, and (b) derivatized. The chemically modified tannin is derivatized by reaction with aldehyhde (e.g. formaldehyde), or aldehyde and at least one member selected from the group consisting of ammonia and organic amine containing at least one primary or secondary nitrogen (e.g. cyclohexyl amine); said derivatized tannin being water soluble or dispersable at a pH below 7 and water insoluble at a pH above 7. The chemically modified tannins are useful for the coagulation and/or detackification of solid particles suspended in the aqueous system, such as paint particles suspended in the waste water of a paint spray booth operation. Such tannins also have utility for demulsifying oil-in-water emulsions.

Treatment of aqueous systems using a chemically modified tannin

A method of removing layers of heat cured paint buildup on supporting hangers is disclosed. The method includes coating support hangers with a layer of a thermally expandable material in a water soluble carrier and thereafter applying a water insoluble coating layer. The thermally expandable material, the carrier and the water insoluble coating are all selected so as to be relatively unaffected by the curing temperatures of the paint line where the hangers are to be used. When an undesirably thick coating of cured paint has built-up on the hangers, it is removed by heating to a temperature sufficient to expand the thermally expandable material thereby cracking the paint layers. Thereafter, the hangers are soaked in a hot aqueous solution to dissolve the carrier layer and remove the cracked, cured paint layers.

Thermo responsive method of removing cured paint

There is provided a composition comprising tannin containing hydroxyl groups which has been (a) chemically modified by reaction of at least one of said hydroxyl groups with at least one member selected from the group consisting of an esterification agent (e.g. acetic anhydride), etherification agent (e.g. dichloromethane or quaternary organic amine such as N-(3-chloro-2-hydroxypropyl) trimethyl ammonium chloride) to form the corresponding ester, or ether, through said hydroxyl group, and (b) derivatized. The chemically modified tannin is derivatized by reaction with aldehyhde (e.g. formaldehyde), or aldehyde and at least one member selected from the group consisting of ammonia and organic amine containing at least one primary or secondary nitrogen (e.g. cyclohexyl amine); said derivatized tannin being water soluble or dispersable at a pH below 7 and water insoluble at a pH above 7. The above modified tannins are useful for the coagulation and/or detackification of solid particles suspended in an aqueous system, such as paint particles suspended in the waste water of a paint spray booth operation. Such tannins also have utility for demulsifying oil-in-water emulsions.

Treatment of Aqueous systems using a chemically modified tannin

The present invention is directed to aqueous dielectric coatings exhibiting reduced migration of the electrical ions of the conductive substrate. The coating composition comprises: (1) a binder comprising: (a) an aqueous polymerizable emulsion comprising: at least one monoethylenically unsaturated monomer; a monoethylenically unsaturated acid; and a copolymerizable surfactant; and (b) a volatile base and (2) a pigment.

Aqueous dielectric coating compositions and method of producing coatings

Dielectric coating compositions intended for application to conductive papers are disclosed. These coating compositions comprise a pigmented aqueous dispersion of a carboxyl-functional copolymer of copolymerized monoethylenically unsaturated monomers including form 8% to 18% by weight of monoethylenically unsaturated carboxylic acid, such as acrylic acid. The carboxyl-functional copolymer is dispersed in water with the aid of a volatile amine, such as ammonia, and the water dispersion is pigmented to contain calcium carbonate and/or clay in a pigment to binder weight ratio of from 0.5:1 to 6:1.

Aqueous dielectric coatings based on copolymers of high acid content

A method of forming an aqueous emulsion laminating adhesive having an extended pot life is disclosed in which monoethylenically unsaturated monomers are polymerized to form a copolymer having a glass transition temperature in the range of about -10.degree. C. to about -50.degree. C. The polymerization is carried out in aqueous emulsion in the presence of emulsified epoxy resin in an amount of from about 2% to about 60%, based on the weight of the monomers which are copolymerized. An aqueous emulsion of amine-functional resin is then mixed into aqueous emulsion containing copolymer and epoxy resin formed by the aqueous emulsion copolymerization to provide a weight ratio of amino hydrogen atoms to oxirane groups of from about 0.1 to about 1.0.

Aqueous emulsion laminating adhesive

Electrically conductive paper is coated with an insulating coating comprising an organic solvent-soluble solution copolymer of monoethylenically unsaturated monomers comprising from about 1% to about 8% of copolymerized acrylamide or a monoethylenic derivative thereof in combination with from 4% to 10% of copolymerized monoethylenically unsaturated carboxylic acid including from 1/4th to 3/4ths of methacrylic acid based on total carboxylic acid monomer.

Electrographic coatings containing acrylamide copolymers

A low temperature curing solution coating composition is disclosed for the protection of solvent-sensitive thermoplastic moldings. In these compositions, a solvent medium consisting essentially of alcoholic solvents has dissolved therein a self-curing solution copolymer of monoethylenically unsaturated monomers containing an ether of an N-methylol functional monomer, especially isobutoxymethyl acrylamide. This solution is catalyzed with from 3% to 12%, based on the weight of the copolymer, of a long chain dialkyl naphthalene disulfonic acid. The catalyzed compositions are stable and cure at 150.degree. F. to 200.degree. F. without damaging the thermoplastic moldings.

Low temperature curing thermosetting coatings for solvent-sensitive

Electrically conductive paper is coated with an insulating coating which is an aqueous latex of an aqueous emulsion copolymer of monoethylenically unsaturated monomers comprising from 5% to 40% of copolymerized acrylamide or a monoethylenic derivative thereof, preferably isobutoxymethyl acrylamide. A proportion of monoethylenically unsaturated carboxylic acid is preferably included in the copolymer.

Electrographic coating containing aqueous emulsion copolymerized

Electrically conductive paper is coated with an insulating coating to provide improved electrographic properties using a solvent-soluble copolymer comprising from 5% to 40% of copolymerized acrylamide or a monoethylenic derivative thereof. The coating is preferably pigmented with calcium carbonate, and the presence of the copolymerized acrylamide allows an increase in the pigment to binder ratio into the range of from 2:1 to 6:1.

A low temperature curing solution coating composition is disclosed for the protection of solvent-sensitive thermoplastic moldings. In these compositions, a solvent medium consisting essentially of alcoholic solvents has dissolved therein a self-curing solution copolymer of monoethylenically unsaturated monomers containing an ether of an N-methylol functional monomer, especially isobutoxymethyl acrylamide. This solution is catalyzed with from 0.5% to 2.0%, based on the weight of the copolymer, of sulfuric acid. The catalyzed compositions are stable and cure at 150.degree. F. to 200.degree. F. without damaging the thermoplastic moldings.

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Des Plaines, IL, United States of America

Ralph L Minnis