The Dow Chemical Company

Dow Global Technolgoies LLC

Ralph D Priester, Jr

Robert B Turner

James R Porter

Martin C Cornell

Alan K Schrock

Christopher P Christenson

Richard D Peffley

Ronald M Herrington

Robert E O'Neill

Wayne R Willkom

Marty C Cornell

Robert Carswell

Ricky L Tabor

Jeffery D Zawisza

Rick L Tabor

Kimberly F Bennett

Melissa J Zawisza

Chris P Christenson

Peder E Danielsen

Cynthia K Groseth

Patricio Jimenez, Jr

Wayne R Wilkomm

Michael K Laughner

Robert A Kirchhoff

Richard Allen Lundgard

Hani Farah

Leo R Novak

Larry W Mobley

Laura A Grier

Raymond A Plepys

James J Jakubowski

Edwin J Strojny

James E Pate, Iii

Kenneth W Skaggs

Paul L Neill

Kimbley A Bushman

Manuel Gonzales, Jr

Debra H Stutts

Robert A Kuklies

Stephen R Burkes

Werner A Lidy

A polyurethane-polymer composition suitable for preparing a lightweight tire support includes at least one isocyanate, at least one polyol, and at least one chain extender. A polyurethane-polymer composition can also include an additive such as a catalyst, a filler, a surfactant, a colorant, and a mold-release agent. A lightweight tire support can be prepared from a polyurethane-polymer composition by, for example, reaction injection molding. Such a tire support desirably has temperature stability and load-bearing capability.

Lightweight tire support and composition and method for making a tire support

The present invention provides a unitary run flat tire (RFT) reinforcement using filament material that is formed into a relatively rigid shape. The reinforcement is insertable into a mold for an RFT support and can maintain the needed structural rigidity for such insertion. Further, the invention provides an RFT support that is molded and includes the RFT reinforcement. The invention also provides a wheel assembly including a tire, a rim, and an RFT support between the rim and the tire, where the support includes the RFT reinforcement. The RFT support can have a colored indicator formed or subsequently applied thereto to indicate one or more attributes of the support.

Method of manufacturing a filament formed reinforcement member and a run flat tire support therewith

The present invention provides a unitary run flat tire (RFT) reinforcement that is formed into a relatively rigid shape. The reinforcement is insertable into a mold for an RFT support and can maintain the needed structural rigidity for such insertion. Further, the invention provides an RFT support that is molded and includes the RFT reinforcement. The invention also provides a wheel assembly including a tire, a rim, and an RFT support between the rim and the tire, where the support includes the RFT reinforcement. The RFT support can have a colored indicator formed or subsequently applied thereto to indicate one or more attributes of the support.

Run flat tire support and colorant therefor

The present invention provides a process for preparing a stable dispersion of a preformed polymer in a polyol in a single mixer. A preformed polymer is mixed under sufficient heat and shear to reduce its particle size to a desired size in the presence of a polyol. The present invention also provides stable dispersions of polymers in polyols and polyurethane formulations containing stable dispersions made by the process of the present invention.

Dispersion of a preformed polymer in a polyol

Polyurethane/polyurea polymers can be electrostatically painted without first being coated with a conductive primer. Disclosed is an improvement in a process for electrostatically painting polyurethane/polyurea polymers, the improvement being to prepare the polymer from a formulation including a non-volatile metal salt conductivity inducing material. The polymers of the present invention can be charged with sufficient charge density to permit efficient paint transfer to the polymer surface. Also disclosed is a composition of at least two adjacent layers, one layer being an outer layer of electrostatically applied paint, and the other an inner layer of polyurethane/polyurea polymer.

Electrostatically painted polymers and a process for making same

Polyurethane/polyurea polymers can be electrostatically painted without first being coated with a conductive primer. Disclosed is a process for electrostatically painting polyurethane/polyurea polymers, the process having a step of including a non-volatile metal salt conductivity inducing material. The conductivity of the polymers of the present invention can allow them to be charged with sufficient charge density to permit efficient paint transfer to the polymer surface. Also disclosed is a composition of at least two adjacent layers, one layer being an outer layer of electrostatically applied paint, and the other an inner layer of polyurethane/polyurea polymer.

Process for electrostatically painting polymers containing a

A blended composition containing polycarbonate, polyester, an olefinic epoxide-containing copolymer and a polyamine compound, which composition possesses a desirable balance of impact resistance, solvent resistance, and resistance to thermal deformation.

Polycarbonate compositions modified with a polyamine compound

Novel catalyst compositions comprising complexes of tin(IV) salts and amine compounds are used to prepare polyurethanes, polyureas, polycarbodiimides and polyisocyanurates. The complexes, which preferably employ primary amines, allow delay of gelation until they dissociate under certain reaction conditions. The complexes can be prepared neat or in situ in an active hydrogen containing formulation component. The complexes serve to delay gelation of the formulation because they can be prepared to be relatively stable to moisture and will predictably dissociate upon heating, either as a result of the exothermic nature of the reaction being catalyzed or with application of an external heat source. The catalyst compositions are particularly useful for preparation of carpet underlay and in other applications requiring significant delay prior to gelation.

Process for preparation of polyurethanes utilizing novel catalysts

The invention includes a process for preparing a flexible, water-blown polyurea foam by reacting a reaction mixture containing at least one polyisocyanate component and an active hydrogen component, wherein active hydrogen compounds of relatively high equivalent weight have an average of about 1.5 to about 4 active hydrogen-containing groups per molecule, of which active hydrogen-containing groups: an average of (a) from about 5 to about 60 percent are primary aliphatic amine groups or (b) at least about 25 percent are primary aromatic, secondary aliphatic, Lewis acid-blocked primary or secondary aliphatic or aromatic amine groups or mixtures of such groups. An amount of at least one alkali metal halide salt effective to increase load bearing strength of the foam is incorporated into the reaction mixture. Differing amounts of alkali metal halide salts are suitably incorporated into different areas of the foam to produce areas having differing load bearing strengths. The invention includes the foams formed by the processes of the invention as well as active hydrogen compositions containing the alkali metal halide salts and useful in the processes.

Flexible polyurea foams having controlled load bearing qualities

Described herein is an isocyanate-reactive compound containing at least one linkage of the formula:

Combustion-modified polyurethane foam

A polyurea foam is formed from a reaction mixture comprising at least one polyisocyanate component and an active hydrogen component, wherein active hydrogen compounds of relatively high equivalent weight have an average of about 1.5 to about 10 active hydrogen-containing groups per molecule, of which active hydrogen-containing groups: an average of (a) from about 5 to about 60 percent are primary or secondary aliphatic amine groups or (b) at least about 25 percent are primary aromatic, Lewis acid-blocked primary aliphatic, secondary aliphatic or aromatic amine groups or mixtures thereof. Carbon dioxide is adducted to said active hydrogen component. The adduct releases carbon dioxide to blow the foam.

Use of carbon dioxide adducts as blowing agents in cellular and

Polyurethanes are produced from compositions comprising at least one relatively high equivalent weight component and at least one chain extender selected from the group consisting of heterocyclic diamines, diaromatic disulfides, alkyl ethers of halogen-substituted aromatic diamines, polysubstituted alkyl diamines and alkyl acid esters of halogen-substituted diamino phenols of designated structures. Polyurethanes having high thermal stability, high tear strength and high modulus are produced.

Chain extenders for polyurethanes

Flexible polyurethane foams are prepared by reacting a polyisocyanate with certain amine-terminated compounds. The amine terminated compounds are characterized in having at least 30 percent of their active hydrogen-containing groups in the form of primary aromatic, Lewis acid-blocked primary aliphatic and/or secondary aromatic or aliphatic amine groups. The resulting foams exhibit excellent physical properties, even in the absence of a cross-linker compound.

Flexible polyurea or polyurea-polyurethane foams prepared from high

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Lake Jackson, TX, United States of America

Ralph D Priester, Jr