Zimmer Aktiengesellschaft

Thueringisches Institut Fuer Textil-und Kunststoff-forschung E.v.

Smartpolymer Gmbh

Alceru Schwarza Gmbh

Thuringishces Institut Fur Textil Und Kunststoff-forschung E.v.

Smart Advanced Systems Gmbh

Thuringisches Institut Fur Textil Und Kunststoff-forschung E. V.

Smartmelamine D.o.o.

Ralf-Uwe Bauer

Sabine Riede

Frank-Günter Niemz

Klaus Heinemann

Uwe Kind

Frank Schubert

Frank Meister

Christoph Michels

Bernd Riedel

Michael Mooz

Marcus Krieg

Birgit Kosan

Mario Schrödner

Thomas Welzel

Rüdiger Strubl

Markus Krieg

Enrico Brandt

MUwe Kind

Christoph Kindler

Jürgen Melle

Mario Schrodner

Frank-Günther Niemz

Silke Bräuer

Disclosed are free-flowing mixtures comprising a granular material comprising a thermoplastic elastomer, a functionalized thermoplastic elastomer, at least one phase change material bound to the thermoplastic elastomers, and at least one binding agent capable of adsorbing and/or absorbing portions of the phase change material. The binding agent is substantially present between the granulate materials, and either: i) the proportion by weight of the phase change material in the granular material is 60% to 90% and the binding agent is a non-silicate binding agent, or ii) the proportion by weight of the phase change material in the granular material is more than 70% and up to 90%. Also described are various compositions comprising the mixture and methods for producing the mixture.

Free-flowing mixture, its use, and method for its production

Methods for producing cellulose articles having controlled release of active ingredient include dispersing pulp in aqueous direct solvent for cellulose to form a slurry. Organically modified or ion-exchange-activated phyllosilicate is homogenized in a direct solvent for cellulose with exfoliation by shearing, then mixed with the slurried pulp. A mixture of active ingredient and a lipophilic matrix material or a water-in-oil ('W/O') emulsion containing active ingredient is stabilized with thickener, converted into a gel-like paste, and mixed with the slurried pulp. Water is stripped from the mixture until all cellulose is dissolved, the mixture is formed into shaped articles, and dried. Exemplary active ingredients include cosmetic active ingredients, fat-soluble vitamins or apolar plant extracts. Domains of active ingredient and matrix material or emulsion containing active ingredient are present as fine divisions within the inventive articles. Exemplary shaped articles include functional fibers in knitted, woven and nonwoven fabrics; paper; foils and membranes.

Method for producing shaped functional cellulose articles with targeted release of active ingredients

The invention describes electrically conductive shaped bodies with an inherent positive temperature coefficient (PTC), produced from a composition which contains at least one organic matrix polymer (compound component A), at least one submicroscale or nanoscale, electrically conductive additive (compound component B) and at least one phase-change material with a phase-transition temperature in the range from &#x2212;42&#xb0; C. to +150&#xb0; C. (compound component D). The phase-change material is incorporated into an organic network (compound component C). The electrically conductive shaped body with an inherent PTC effect is, in particular, a filament, a fibre, a spun-bonded web, a foam, a film, a foil or an injection-moulded article. The switching point for the PTC behavior is dependent on the type and also the phase-conversion temperature of the phase-change material. By way of example, a self-regulating surface heater in the form of a film, foil and/or textile can be realized in this way.

Electrically conductive shaped body with a positive temperature coefficient

The invention relates to molded cellulose bodies, in particular fibers, filaments, directly spun nonwovens, films, or foams which have flame-resistant properties. The fibers and filaments can be further processed as textiles into yarns, wovens, knitted fabrics, and nonwovens. The molded bodies are produced from solutions of cellulose and melamine cyanurate or cellulose and crosslinked or partially crosslinked melamine resin particles in an organic solvent. The melamine cyanurate or the melamine resin particles provide the molded cellulose bodies with flame-retardant properties. The molded cellulose bodies made of cellulose and melamine cyanurate or melamine resin particles can further contain flame retardants, in particular flame retardants which act synergistically, in a particulate form. The obtained textile fibers and nonwoven materials have a soft touch and can be processed or finished as filaments or yarns on conventional textile machines.

Flame-resistant molded cellulose bodies produced according to a direct dissolving method

The invention molecularly equips polyester or polyolefin molding compositions in situ with zinc ions before extrusion, enabling direct processing of the molding compositions from the melt even at high temperatures and ensuring a long-term antibacterial action. The inventive molding compositions include at least one polyester polymer or polyolefin polymer and at least one zinc salt-organoligand complex.

Polyester and polyolefin molding compositions having bioactive properties and moldings produced therefrom

Device and procedure for safely conveying and handling a cellulose solution suitable for manufacturing solvent-spun cellulose molded parts, in particular for manufacturing fibers, films and membranes, in devices for conveying and handling the spinnable cellulose solution, provided with a tempering device, wherein the temperature in the tempering system is reduced once the temperature in the cellulose solution has exceeded at least a first limiting temperature, as a result of which the temperature of the spinning solution drops and the reaction mixture is prevented from passing through. A procedure and device with two switching stages is also disclosed.

Device and method for the secure conveyance and handling of spinnable cellulose solutions

Process for manufacture of cellulose mouldings, such as fibres, filaments, or films, from TCF-bleached or ECF-bleached cellulose, in which the bleached cellulose is dissolved in an aqueous tertiary aminoxide to form a mouldable cellulose, the cellulose solution deforms, and the moulding comes into being by coagulation of the deformed solution, characterized in that, to reduce the cellulose decomposition in the process, TCF-bleached cellulose is used comprising carboxyl group content in the range from 1 to 35 &#x3bc;mol/g or an ECF-bleached cellulose with carboxyl group content in the range from 1 to 50 &#x3bc;mol/g. Cellulose mouldings having a reduced cellulose decomposition may be formed by said process.

Method for producing cellulose shaped-bodies

The invention relates to a method for continually producing a suspension of cellulose in an aqueous tertiary amine oxide. The method includes (a) mixing cellulose and an amine oxide-free aqueous phase to form a cellulose suspension in a mass ratio in the range of 1:3 to 1:40, (b) dehydrating the cellulose suspension, wherein the dehydrated cellulose suspension has a cellulose content in the range of 20 to 80 percent-by-mass; (c) mixing the cellulose suspension with an aqueous amine oxide while the cellulose suspension is falling through a vertical fall zone to obtain an aqueous amine oxide-cellulose suspension with an amine oxide content in the range of 70 to 80 percent-by-mass; and (d) conveying the aqueous amine oxide-cellulose suspension through a horizontal shear zone. The invention also relates to a device for carrying out this method.

Method and device for continually producing a suspension of cellulose in an aqueous amine oxide

The invention relates to a method for continually producing an extrusion solution for producing cellulosed shaped bodies, such as fibres and films, according to the lyocell method. According to the inventive method, (a) a cellulose suspension is produced from cellulose and an aqueous phase in a mass ratio ranging from 1:3 to 1:40, whereby shearing is maintained for between 5 to 200 minutes. (b) The cellulose suspension is dewatered to form a material having a cellulose content ranging from 20 to 80 mass % and the aqueous phase produced thereby is at least partially returned to step (a). (c) The humid cellulose material being homogenised is transported through a first shearing zone in the absence of N-methylmorpholine-N-oxide. (d) The cellulose material is transported through a second shearing zone after sufficient aqueous N-Methyl-morpholine-N-oxide has been added to the homogenised cellulose material so that, after mixing, a suspension having a N-Methylmorpholine-N-oxide content ranging from 70 to 80 mass % in the liquid phase is obtained. The cellulose material or the suspension completely fills in the available cross-section of transport in the shearing zones and (e) the produced cellulose suspension being sheared is converted into the extrusion solution in aqueous N-Methylmorpholine-N-oxide, whereby water evaporates.

Method and device for continually producing an extrusion solution

Process for producing formed cellulosic articles, particularly fibers and filaments, comprising a) dissolving cellulose in an aqueous solution of a tertiary amine oxide, especially N-methyl-morpholine N-oxide, and b) extruding the cellulose solution through an extrusion die via an air gap into a precipitation bath with precipitation of the formed articles, said cellulose solution and/or said precipitation bath containing a tenside, characterized in that in the step b) the tenside content c of the cellulose solution and/or of the precipitation bath is in the range 100 ppm>c>5 ppm, and the width of the air gap is in the range from 2 to 20 mm. With this process the air gap width can be considerably reduced without deterioration of the properties of the fibers/filaments.

Method for producing cellulosic forms

The invention relates to a method for producing a cellulose solution in an aqueous amine oxide, preferably N-methyl-morpholine-N-oxide, for processing to form cellulosed moulded bodies according to the Lyocell method, whereby said solution has an increased thermal stability. Cellulose is suspended in an aqueous amine oxide and the suspension is converted into the cellulose solution. The inventive method is characterised in that the base use of the cellulose used for producing the solution and of the optionally used additives is detected in a dispersion in aqueous amine oxide solution and in that the cellulose solution is formed by adding a base quantity which matches the detected own consumption of the cellulose and optionally the additives. Cellulose solutions having a stability which is essentially independent from the provenance of the used cellulose can he formed.

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Rudolstadt, Germany

Ralf-Uwe Bauer