Milliken + Co

Milliken Research Corporation

Rajnish Batlaw

Patrick D Moore

Marc Delaere

Jusong Xia

Philip G Harris

William S Parks

Kheng Teck Chan

Roberto Guzman

Zhen Zhen Lim

Pedro Van Hoecke

Carlos Ilao, Jr

A bluing composition concentrate comprises an aqueous medium and at least one colorant that exhibits a blue or violet shade when deposited onto a textile material. The concentrate can be used to produce a bluing composition, and the bluing composition can be used to treat textile materials in such a way as to decrease the visually-perceived yellow coloration of textile articles that can occur with repeated use and laundering.

Bluing composition and method for treating textile articles using the same

Black polyurethane foams that exhibit higher strength black colorations without the need for concomitant increases in black colorants therein are provided. Such a resultant jetter black foam article is possible through the unexpectedly effective introduction of small amounts of certain toner compounds or combinations that exhibit specific measurable appearance characteristics. Such toners exhibit at least one absorption peak within a specific range of wavelengths (e.g., from about 560 to 610 nm) and specific ranges of half-height bandwidths (from 40 to 130 nm). Furthermore, such a compound or combination of compounds, is preferably liquid in nature (at room temperature) or in dispersion form and may thus be easily incorporated within target polyurethane precursor compositions for admixture with either black pigments (or dispersions thereof), black polymeric (liquid) colorants, or both. Methods of high strength black polyurethane foam production as well as separate pigmented and liquid polymeric colored foams of such type including the necessary toner compounds and/or combinations, as noted above, are also encompassed within this invention.

High-strength black polyurethane foams

Methods of production of high-strength black polyurethane foams

Novel, quick, and reliable detection methods for determining the authenticity of optical and/or audio disc articles (such as compact discs, digital video discs, CD-ROM discs, and the like) are provided. Such a method basically entails the incorporation of an identifier or marking means within the edges of target optical discs or within any other portion of a target disc such that exposure to non-visible light sources will provide the desired identification upon irradiation or detection of the marking means therein. Such an identifier or marking agent thus may be utilized in conjunction with a transparent holding case whereby the needed light source may be exposed through the transparent walls thereof to permit detection of counterfeit or authentic discs without requiring opening of the case itself. Such a method may also be utilized for discs that are removed from or have not been placed and sealed within such a case as well. Specific methods of utilizing particular transparent cases are thus also encompassed within this invention. Specific methods of utilizing particular transparent cases are thus also encompassed within this invention as are novel storage unit configurations to maximize the benefits of the transparent properties thereof.

Configuration of clarified polypropylene optical disc storage units

Novel optical disc storage units comprising transparent polypropylene are provided. Such storage units exhibit sufficient impact resistance to protect the target disc and sufficient clarity that any informational literature may be placed entirely within the storage unit and easily viewed and read through the walls thereof without impediment. Furthermore, the target storage unit must also include a spine section of sufficient width to permit a section of the informational literature to be placed internally thereon and viewed and easily read (such as, for example, the title and accompanying language describing the target disc placed therein) substantially without impediment as well. Additionally, provided therein are novel insert trays that simultaneously permit proper placement of such internally placed informational literature against the internal portion of the aforementioned walls, and particularly the spine portion, as well as provide antitheft properties. Such insert trays are designed to encompass any discs placed therein to the extent that such discs cannot exit such trays when the container is in closed position without breaking the disc itself. Specific novel storage units, in addition to these necessarily transparent walls and spine portions, are also possible to maximize the benefits of the transparent properties thereof.

Disc holding trays for antitheft purposes within optical or audio disc storage units

A novel, easy, and efficient manner of toning shades of toluene-based gravure inks is provided, particularly through the incorporation of certain polymeric colorants therein said gravure ink formulations. In addition, such toner additives provide a toning capabilities of carbon black-based gravure inks that provides jetter black appearances with lower degrees of redness and bronzing on various types of printing substrates than other toner formulations of standard alkali blue types of toning additives. Such printed substrates and methods of printing utilizing such novel gravure toner additives are also encompassed within this invention.

Toner compositions for black gravure inks

Novel addition products of hydroxyl-protecting groups (such as isocyanates) with oxyalkylene-substituted intermediates, such as poly(oxyalkylenated) aniline compounds, for the eventual production of substituted, and substantially pure, colorants, particularly diazo and triphenylmethane derivatives, through the reaction of such intermediates with certain reactants are provided. These new colorants exhibit improved wax and/or oil solubility and high purity, particularly due to the inability of certain impurities to deleteriously react with the protected hydroxyl groups of either the intermediate or the colorant during and/or after formation thereof. A method for producing such novel colorants through utilization of these novel substantially pure colorant intermediates is also provided.

Colorants for use within ink systems

Novel addition products of isocyanates with oxyalkylene-substituted aminophenol compounds as intermediates for the production of urethane-substituted xanthene colorants, particularly triphenylmethane derivatives such as rhodamines, are provided. The xanthene colorants exhibit improved wax and/or oil solubility and high purity. The urethane-substituted xanthene colorant features very good wax and/or oil solubility, and is believed to be relatively nontoxic. A method for producing this novel colorant is also provided.

Substrates colored with novel magenta colorants

A novel colorant compound is provided which is the addition product of an organic chromophore having at least one reactive hydroxyl or amine substituent, a mono or polyisocyanate, and/or an alcohol. Such a compound provides solubility in oil-based ink compositions, complete water resistance and excellent oil based ink compositions. Furthermore, such colorants provide an easy and efficient way to tone shades of oil based inks. In addition, such colorants provide a way to tone carbon black based lithographic inks that gives the images a appearance of jet black on various types of printing substrates. A method for producing such a colorant is also provided, as well as offset ink compositions comprising such a colorant (including other colorants that provide the same toner performance within black pigment formulations).

Toner compounds and compositions for black offset inks

Novel, quick, and reliable detection methods for determining the presence and/or authenticity of optical and/or audio disc articles (such as compact discs, digital video discs, CD-ROM discs, and the like) when present within a holding container are provided. Specific methods of utilizing particular transparent cases are encompassed within this invention. Specific methods of utilizing particular transparent cases are thus also encompassed within this invention as are navel storage unit configurations to maximize the benefits of the transparent properties thereof.

Optical disc storage containers that facilitate detection of the presence of optical and/or audio discs stored therein

A novel colorant compound is provided which is the addition product of an organic chromophore having at least one reactive hydroxyl or amine substituent, a mono or polyisocyanate, and/or an alcohol. In addition, colorants that provide the same toning characteristics for black offset ink compositions as this novel colorant are provided. Such a compound provides solubility in oil-based ink compositions, complete water resistance and excellent oil based ink compositions. Furthermore, such colorants provide an easy and efficient way to tone shades of oil based inks. In addition, such colorants provide a way to tone carbon black based lithographic inks that gives these inks a appearance of jet black on various types of printing substrates. A method for producing such a colorant is also provided, as well as offset ink compositions comprising such a colorant (including other colorants that provide the same toner performance within black pigment formulations).

Toned black offset inks exhibiting excellent chromatic characteristics

A novel, easy, and efficient manner of toning shades of toluene-based gravure inks is provided, particularly through the incorporation of certain polymeric colorannts therein said gravure ink formulations. In addition, such toner additives provide a toning capabilities of carbon black-based gravure inks that provides jetter black appearances with lower degrees of redness and bronzing on various types of printing substrates than other toner formulations of standards alkali blue types of toning additives. Such printed substrates and methods of printing utilizing such novel gravure toner additives are also encompassed within this invention.

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Spartanburg, SC, United States of America

Rajnish Batlaw