Basf Se Corporation

Rajesh Kumar

Christopher M Tanguay

Nikolay Lebedinski

Yeonsuk K Roh

Donald Charles Mente

Cheng-Le Zhao

Sunitha Grandhee

Theodore Michael Smiecinski

Raymond A Neff

Alexander Gershanovich

David Kaczan

Thomas G Savino

Steven E Wujcik

Calvin T Peeler

Sridhar Gopalkrishnan Iyer

Hai Wu

Lyle Andrew Caillouette

John P Erickson

Eric N Lawson

Daniel Niedzwiecki

Michael T Yang

Vincent J Goldman

Michele Williams-Harry

Fikri Emrah Alemdaroglu

Christopher J Milantoni

Victoria Manea

Jyh-Chiarng Huarng

Nikolay Lebedinksi

Hai Sheng Wu

Raymond Neff

This disclosure provides a pigmented primer composition for forming an n-acyl urea coating on a substrate. The pigmented primer composition includes a polycarbodiimide-polyurethane hybrid. The pigmented primer composition also includes an acid functional polymer and an organic solvent, and includes less than or equal to 10 weight percent of water based on a total weight of the pigmented primer composition. The pigmented primer composition also includes a pigment, an inorganic filler, and less than about 100 parts by weight of toluene diisocyanate per one million parts by weight of the pigmented primer composition. The n-acyl urea coating exhibits corrosion resistance of 2 to 10 as determined using ASTM B117 and ASTM D-1654-08 on a substrate that is unpolished cold rolled steel, aluminum, or galvanized steel.

Pigmented primer composition for forming an n-acyl urea coating

A method of producing a polycarbodiimide polymer comprises heating a precursor compound at a desired temperature. The method further comprises combining the precursor compound, a diisocyanate compound, and a carbodiimidization catalyst to form a reaction mixture. Finally, the method comprises heating the reaction mixture for a first period of time at a first temperature, thereby reacting the precursor compound and the diisocyanate compound in the presence of the carbodiimidization catalyst to produce the polycarbodiimide polymer.

Method of preparing a polycarbodiimide polymer and polycarbodiimide polymer prepared thereby

This disclosure provides a solvent-borne system for forming an n-acyl urea coating on a substrate. In one embodiment, the solvent-borne system comprises a polycarbodiimide-polyurethane hybrid. The solvent-borne system also comprises an acid functional polymer and an organic solvent, and comprises less than or equal to 10 weight percent of water based on a total weight of said solvent-borne system. The solvent-borne system also comprises less than about 100 parts by weight of toluene diisocyanate per one million parts by weight of the solvent-borne system.

Solvent-borne system for forming an n-acyl urea coating

A flexible polyurethane foam article exhibiting flame resistance comprises the reaction product of an isocyanate and an isocyanate-reactive component comprising a polyol reactive with the isocyanate. The isocyanate and the isocyanate-reactive component are reacted in the presence of a blowing agent and a phospholene oxide. A method of producing the flexible polyurethane foam article includes the step of reacting the isocyanate and the isocyanate-reactive component in the presence of the blowing agent and an effective amount of the phospholene oxide to form the flexible polyurethane foam article which is flame resistant.

Method of producing a flexible polyurethane foam article

A continuous process forms a unitary mat on a line having at least two conveyors spaced from each other. The process includes combining the isocyanate, an isocyanate catalyst, and a plurality of lignocellulosic particles to form a mixture and a self-polymerization product of the isocyanate in-situ in the mixture. The process also includes forming the unitary mat from the mixture on a first conveyer and transferring the unitary mat from the first conveyor to a second conveyor across a predetermined distance while maintaining structural integrity of the unitary mat. The lignocellulosic particles have a moisture content of 0.5 to 30 weight percent of water. Moreover, the continuous process is free of a step of adding water to the isocyanate, the isocyanate catalyst, the lignocellulosic particles, and/or the unitary mat.

Continuous process for forming a unitary mat

A composition for forming a polyiso-urea includes a capped polycarbodiimide and a polyol. The capped polycarbodiimide comprises the reaction product of a diisocyanate and a monoisocyanate in the presence of an oxygen scavenger and a carbodiimidization catalyst and in the absence of solvent, has 0.25 wt. % or less of free isocyanate groups, and is a liquid at 25&#xb0; C. A polyiso-urea comprises the reaction product of the capped polycarbodiimide and the polyol.

Polyiso-urea

A proppant includes a particle present in an amount of from 90 to 99.5 percent by weight and a polymeric coating disposed about the particle and present in an amount of from 0.5 to 10 percent by weight, based on the total weight of the proppant. The polymeric coating is formed from a curable composition comprising an isocyanate, an acrylate, and a polyol. A method of forming the proppant includes the steps of combining the isocyanate, the acrylate, and the polyol to form the curable composition, coating the particle with the curable composition, and curing the curable composition to form the polymeric coating.

Proppant

A proppant comprises a particle and a polymeric coating disposed about the particle. The polymeric coating comprises the reaction product of a novolac polyol, an isocyanate, and an azole. The novolac polyol has a number average molecular weight of from about 200 to about 1000 g/mol. A method of forming the proppant comprises the steps of providing the particle, providing the novolac polyol, providing the isocyanate, and providing the azole. The method also includes the steps of combining the novolac polyol, the isocyanate, and the azole to react and form the polymeric coating and coating the particle with the polymeric coating to form the proppant.

Resin-coated proppant and methods of use

A hot melt adhesive (HMA), which is solid at room temperature, comprises the reaction product of 5 to 25% by weight of an isocyanate component having an NCO content of from about 20 to about 50% by weight, 75 to 85% by weight of a polyester, and 1 to 10% by weight of a hydroxy-polymer having an OH number of from about 40 to about 50. A method of forming the adhesive comprises the step of combining the isocyanate component, polyester, and hydroxy-polymer to form the adhesive. The adhesive can be used for various purposes, such as for forming an adhesive layer which adhesively couples surfaces together.

Hot melt adhesive and method of forming the same

A gypsum board comprises a cover sheet and a gypsum layer disposed on the cover sheet. The gypsum layer comprises the reaction product of an isocyanate, water, and stucco. The isocyanate increases the moisture resistance of the gypsum board. A method of manufacturing the gypsum board comprises the steps of combining the isocyanate, the water, and the stucco to form a slurry, and applying the slurry to a cover sheet to form the gypsum layer on the cover sheet.

Moisture-resistant gypsum boards and slurries for making same

A proppant comprises a particle and a polycarbodiimide coating disposed on the particle. The polycarbodiimide coating comprises the reaction product of a polymeric isocyanate and a monomeric isocyanate, in the presence of a catalyst. A method of forming the proppant comprises the steps of providing the particle, providing the polymeric isocyanate, providing the monomeric isocyanate, providing the catalyst, reacting the polymeric isocyanate and the monomeric isocyanate in the presence of the catalyst to form the polycarbodiimide coating, and coating the particle with the polycarbodiimide coating.

A proppant comprises a particle and a polycarbodiimide coating disposed on the particle. The polycarbodiimide coating comprises the reaction product of an isocyanate reacted in the presence of a phospholene oxide catalyst. A method of forming the proppant comprises the steps of providing the particle, providing the isocyanate, providing the phospholene oxide catalyst, reacting the isocyanate in the presence of the phospholene oxide catalyst to form the polycarbodiimide coating, and coating the particle with the polycarbodiimide coating.

A dust suppressing aggregate includes a core particle and a dust suppressing agent. The dust suppressing agent comprises polycarbodiimide and is disposed about the core particle for suppressing dusting of the core particle. A method of forming the dust suppressing aggregate includes the steps of reacting isocyanates in the presence of a catalyst to form the polycarbodiimide and encapsulating the core particle with the polycarbodiimide to form the dust suppressing agent. A system for producing the dust suppressing aggregate includes the core particle, the isocyanates, and the catalyst.

Dust suppressing aggregate

An encapsulated particle including a core particle, a base layer, and an outer layer is provided. The base layer is disposed about the core particle and comprises polycarbodiimide. The outer layer is disposed about the base layer and comprises wax. A method of forming the encapsulated particle including the steps of reacting an isocyanate in the presence of a catalyst to form the polycarbodiimide, encapsulating the core particle with the polycarbodiimide to form the base layer, and encapsulating the base layer with the wax to form the outer layer is also provided.

Encapsulated particle

A proppant comprises a particle and a polyamide imide coating disposed on the particle. A method of forming the proppant comprises the steps of providing the particle, providing the polyamide imide coating, and coating the particle with the polyamide imide coating.

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Riverview, MI, United States of America

Rajesh Kumar