Shell Internationale Research Maatschappij, B.v.

University of California

Rajamani Krishna

Richard C Darton

Heinz Voetter

Hubrecht C Van Meurs

Jeffrey R Long

Brian M Wiers

Zoey R Herm

A metal organic framework Fe(bdp)(BDP=1,4-benzenedipyrazolate) with triangular channels is particularly suited for C5-C7 separations of alkanes according to the number of branches in the molecule rather than by carbon number. The metal-organic framework can offer pore geometries that is unavailable in zeolites or other porous media, facilitating distinct types of shape-based molecular separations.

Metal-organic framework for the separation of alkane isomers

Process and apparatus for the combustion of coke present on solid particles from which hydrocarbons have been substantially removed by heating, and for the production of recoverable heat from hydrocarbon-bearing solid particles, in a series of at least two combustion stages. The process comprises the followng steps:

Process for the combustion of coke present on solid particles and for

Hydrocarbons are extracted from a hydrocarbon-bearing substrate, e.g. shale oil, bituminous coal, tar sand, in the substantial absence of oxygen at temperatures above 400.degree. C., by passing substrate particles through a plurality of successive stages in which the substrate is mixed with a solid heat-bearing medium, the mixture being maintained in a fluidized-bed condition, and the liberated hydrocarbons being removed by passage of an inert stripping gas in cross-current flow with respect to the passage of the substrate particles. The average cross-sectional area of at least one or more of the stages subsequent to the first one is preferably smaller than the average cross-sectional area of one or more of the preceding stages. An apparatus for carrying out the process is described.

Process for the extraction of hydrocarbons from a hydrocarbon-bearing

Hydrocarbon-bearing substrate particles are pre-heated by heating the same with a solid heat-bearing medium by indirect counter-current flow using a series of heat transfer loops each containing a circulating heat transfer medium chosen such that the whole series permits a staged rise in temperature of the substrate particles and a staged drop in temperature of the solid heat-bearing medium. Preferably the heat transfer fluid in the loops circulates between the substrate and the hot spent substrate by means of the so-called thermosyphon effect. An apparatus for carrying out the method is described.

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Amsterdam, Netherlands

Rajamani Krishna