L'air Liquide, Soci&#xe9;t&#xe9; Anonyme Pour L'etude Et L'exploitation Des Proc&#xe9;d&#xe9;s Georges Claude

Raja Swaidan

Dean W Kratzer

Robert A Gagliano

Henri Chevrel

David J Hasse

Philippe A Coignet

Madhava R Kosuri

Canghai Ma

Sudhir S Kulkarni

Tao Li

Junyi Liu

Megha Sharma

Composite hollow fiber gas separation membranes with improved permeance and separation layer adhesion are manufactured by providing dipping a hollow fiber membrane substrate in a pre-coat layer coating composition followed by drying to thereby provide a pre-coated substrate and dipping the pre-coated substrate in a separation layer coating composition followed by drying to thereby provide the composite hollow fiber gas separation membranes. The pre-coating composition includes a first polymer dissolved in a first solvent and the separation layer composition includes a second polymer dissolved in a second solvent. The first and second polymers are the same or different, each of the first and second polymers is at least 1 wt % soluble in a same third solvent, the first and second solvents are the same or different, the first and third solvents are the same or different, and the second and third solvent are the same or different.

Coated composite hollow fiber gas separation membranes with improved permeance and separation layer adhesion

A CMS membrane module includes plurality of hollow fiber CMS membranes that are enclosed within an open cylindrical shell whose ends are embedded in tubesheets. The shell is concentrically disposed within an open cylindrical pressure vessel whose open ends are covered by and secured by end caps. The shell includes a feed fluid inlet formed therein between the tubesheets and a retentate outlet in between one of the tubesheets and an adjacent end cap. A retentate seal is formed between the shell and the pressure vessel at a position between the tubesheets. A permeate seal is formed between the pressure vessel and the tubesheet that is adjacent a permeate port of the module. A structure made up of the CMS membranes, shell, tubesheets, and seals is slidable within the pressure vessel and not fixed in place in relation to the pressure vessel and end caps.

Gas separation membrane module with hollow fiber carbon molecular sieve membranes

One or more polymeric hollow fiber membranes are pyrolyzed to form one or more hollow fiber CMS membranes by directing a flow of pyrolysis gas through a polymeric membrane cartridge (including a porous center tube around which one or more green, polymeric, hollow fiber membranes is arranged) or a bundle of polymeric membranes (including a plurality of green, polymeric hollow fiber membranes oriented so that their ends are disposed with ends of the bundle) in a direction perpendicular to a length direction of the cartridge or bundle in order to sweep away off-gases that are formed during pyrolysis.

Hollow fiber carbon molecular sieve membranes and method of manufacturing using radial-flow pyrolysis

One or more polymeric hollow fiber membranes are pyrolyzed to form one or more hollow fiber CMS membranes by directing a flow of pyrolysis gas through a bundle of polymeric membranes (including a plurality of green, polymeric hollow fiber membranes oriented so that their ends are disposed with ends of the bundle) in a direction perpendicular to a length direction of the bundle in order to sweep away off-gases that are formed during pyrolysis.

Metallopolyimide precursor fibers for aging-resistant carbon molecular sieve hollow fiber membranes having enhanced selectivity include transition metal cations complexed with electronegative regions of a polyimide. CMS membranes are made by pyrolyzing the metallopolyimide precursor fibers. The cations are introduced by including, in the spin dope composition used to extrude the fibers, either a salt of the transition metal and an inorganic anion or a transition metal/organic ligand complex.

Metallopolyimide precursor fibers for aging-resistant carbon molecular sieve hollow fiber membranes with enhanced selectivity

Metallopolyimide precursor fibers for aging-resistant carbon molecular sieve hollow fiber membranes having enhanced selectivity include transition metal cations complexed with electronegative regions of a polyimide. CMS membranes are made by pyrolyzing the metallopolyimide precursor fibers. The cations are introduced by including, in the bore fluid used to extrude the fibers, either a salt of the transition metal and an inorganic anion or a transition metal/organic ligand complex.

A carbon molecular sieve (CMS) membrane is made by pyrolyzing a polymeric precursor membrane in a pyrolysis atmosphere containing a sulfur-containing compound.

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Bear, DE, United States of America

Raja Swaidan