Basf Aktiengesellschaft

Rainer Theysohn

Rolf Wurmb

Horst Reimann

Franz Zahradnik

Graham E McKee

Erhard Seiler

Gunter Pipper

Walter Ziegler

Wolfgang Seydl

Martin Welz

Richard Pflueger

Hans Georg Dorst

Hans-Josef Sterzel

Hermann Gausepohl

Klaus Bronstert

Klaus Muehlbach

Klaus Penzien

Bernd Leutner

Franz Brandstetter

Christoph Plachetta

Claus Cordes

Klaus Boehlke

Rolf Steinberger

Franz Schmidt

Dieter Stein

Hermann Fischer

Gerhard Zeitler

Rainer Bueschl

Hans-Ulrich Schlimper

Karlheinz Ulmerich

Franz G Mietzner

Paul Matthies

Eduard Heil

Richard Thoma

Joachim Kunde

Siegfried Riegger

Bernhard H Nowakowsky

Frank Weiss

Dietrich-Wolfgang Mueller

Hans Willing

A thermoplastic molding composition composed of, based on the total of A, B, C and D,

Blends of styrene-acrylonitrile polymer, styrene-methyl

Thermoplastic molding materials contain, as essential components, (A) from 40 to 95% by weight of a nylon and (B) from 5 to 60% by weight of a noncrosslinked copolymer based on

Thermoplastic molding materials based on nylons and ethylene copolymers

High-impact polyamide molding compositions contain as essential components

Polyamide compositions containing alkyl orthotitanate or dialkyltin

A process for the preparation of high-impact nylon molding materials, containing 30-88% by weight of a thermoplastic nylon, 10-50% by weight of an organosilane-coated silicate reinforcing filler, 0.1-5% by weight of a polyurethane ionomer, 2-30% by weight of a carboxyl-containing thermoplastic elastomer and, where appropriate, effective amounts of conventional additives, by mixing the silicate filler, coated with an organosilane and a polyurethane ionomer, with the thermoplastic elastomer and the nylon at above the melting point of the nylon, wherein, in a first stage, the silicate filler coated with an organosilane and a polyurethane ionomer is mixed with the nylon at above the melting point of the latter, and in a second stage the thermoplastic elastomer is finely dispersed in the filler-containing nylon at above the melting point of the latter.

Preparation of high-impact nylon molding materials

Novel nylon molding materials having high impact strength contain, as an additive, a copolymer of ethylene, a primary or secondary C.sub.2 -C.sub.8 -alkyl acrylate or methacrylate and a monomer possessing a (latent) acid functional group, in particular an ethylene/n-butyl acrylate/acrylic acid copolymer.

Nylon molding materials having high impact strength

Nylons are prepared by a continuous process in which, in a precondensation zone, an aqueous solution of a salt of a dicarboxylic acid of 6 to 18 carbon atoms and a diamine of 6 to 18 carbon atoms is heated to 250.degree.-300.degree. C. under superatmospheric pressure, with simultaneous vaporization of water and formation of a prepolymer, the prepolymer and the vapor are separated, and the former is fed into a polycondensation zone and condensed under superatmospheric pressure of from 1 to 10 bar and at from 250.degree. to 300.degree. C., wherein the aqueous salt solution is condensed under superatomspheric pressure of from 1 to 10 bar in the first third of the tubular precondensation zone provided with baffles, until the degree of conversion is not less than 93%, and the prepolymer and the vapor phase are brought into intimate contact with one another in the remaining two thirds of the precondensation zone.

Continuous preparation of nylon from aqueous salt solution in

Polylactams are prepared continuously by a process in which a lactam containing from 1 to 25% by weight of water is heated in a prepolymerization zone under a pressure of from 1 to 10 bar at from 220.degree. to 280.degree. C. for 1 to 10 minutes, water being vaporized at the same time, with the proviso that the degree of conversion on emergence from the prepolymerization zone is not less than 85%, the prepolymer and the vapor are separated continuously, and the prepolymer is passed into a polymerization zone and is polymerized further under superatmospheric pressure at from 240.degree. to 290.degree. C.

Continuous hydrolytic preparation of polylactams

A process for the preparation of finely divided polyolefin molding materials from 100 parts by weight of a polyolefin and from 0.01 to 30 parts by weight of an electrically conductive additive, with or without other additives, wherein the mixture of the finely divided polyolefin particles and the electrically conductive additives is brought to the crystallite melting point of the polyolefin by the heating effect of the mixing action, and is then brought to a temperature which is from 3.degree. to 40.degree. C. above the said crystallite melting point while being subjected to a defined mixing intensity, after which the mixture is either cooled within 120 seconds or is directly compression-molded.

Manufacture of electrically conductive polyolefin moldings, and their use

A flameproofed thermoplastic molding material which possesses good long-term stability and contains 100 parts of a nylon, 10-100 parts of an inorganic filler, 1-12 parts of red phosphorus and 1-40 parts of melamine cyanurate. The molding materials may be used to produce moldings, especially for electrical articles.

Flameproofed filled nylon molding materials

A process for the preparation of finely divided polyolefin molding materials from 100 parts by weight of polyolefin and from 1 to 30 parts by weight of a conductive carbon black, with or without other additives, wherein the mixture of polyolefin powder and carbon black is compounded, in a first stage, until the crystallite melting point of the polyolefin is reached, and is then brought, in a second stage, to a temperature which is from 3.degree. to 40.degree. C. above the said crystallite melting point, after which the mixture is discharged from the mixer within from 0.5 to 30 seconds and is cooled within 120 seconds.

Preparation of finely divided polyolefin molding materials containing

Thermoplastics reinforced with glass fiber mats contain from 10 to 60% by weight of such mats and from 5 to 60% by weight of a finely divided inert filler, the sum of the percentages by weight of glass fiber mats and filler being not greater than 70% by weight. The inert filler is a talc, having a foliated crystalline structure, which has a mean flake thickness of not more than 5 .mu.m and a ratio of mean flake diameter to mean flake thickness of from 5:1 to 500:1. When processing the thermoplastic filled with talc and glass fiber mats, homogeneous impregnation of the glass fiber mats with the filled thermoplastic is achieved.

Thermoplastics, reinforced with glass fiber mats, which possess improved

A flameproofed nylon molding composition which can be processed by thermoplastic methods and which contains, as the flameproofing agent, from 5 to 30% by weight of brominated styrene oligomers and a synergistic metal oxide. The compositions may be used for the manufacture of injection moldings for the electrical industry.

Flameproofed nylon molding compositions

Filled nylon molding compositions of increased rigidity containing red phosphorus as a flameproofing agent and talc or mica as a filler. They may be converted to moldings which are used, above all, in the electrical industry.

Flameproof nylon molding compositions

Glass-fiber-reinforced thermoplastic molding compositions showing improved flowability and toughness and containing from 0.1 to 2% by weight, based on the total mixture, of a low molecular weight polyolefin wax to which from 2 to 50% by weight of polar side chains have been grafted.

Glass-fiber-reinforced thermoplastic molding compositions showing

Thermoplastic molding compositions comprise a linear nylon, an adduct of hexachlorocyclopentadiene and a dienophile as a flameproofing agent, zinc oxide as a synergistic agent, and reinforcing fillers. The zinc oxide is manufactured by adding an aqueous solution of a zinc salt and an aqueous solution of a base to an aqueous suspension of an inorganic carrier, the zinc oxide being precipitated at a pH of from 10 to 12. The molding compositions can be processed to give flameproof moldings having good mechanical properties.

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Frankenthal, Germany

Rainer Theysohn