Basf Aktiengesellschaft

Rainer Ohlinger

Peter Bauer

Lothar Schlemmer

Hans Gropper

Norbert Hasenbein

Alfred F Hauss

Matthias Marx

Rolf Wurmb

Hans D Zettler

Friedrich Sauer

Gerhard Zeitler

Frank Werner

Georg Falkenstein

Fritz Zanker

Gerhard Bittner

Lothar Metzinger

Artur Roeber

Rudolf Schmidt

Willy Van Pee

Hans J Astheimer

Jaak Van Steen

Siegfried Krueger

Karl-Heinz Baumann

Hans J Raabe

Bernd Blumenberg

Ludwig Pfannenstiehl

Harald Schnez

Horst Brandtstaedter

In a process for the peroxide-free grafting of ethylenically unsaturated carboxylic acids, carboxylic anhydrides and/or their derivatives to a homopolymer or copolymer of ethylene having a density equal to or greater than 0.930 g/cm.sup.3, the monomers to be grafted are used in a concentration of from 0.01 to 0.5% by weight and the grafting reaction is carried out at from 210.degree. to 300.degree. C. in a conventional extruder or mixer in the absence of a free radical initiator. The graft copolymers are used for the preparation of ionomers and adhesion promoters.

Peroxide-free grafting of homopolymers and copolymers of ethylene having

In a process for the peroxide-free grafting of ethylenically unsaturated carboxylic acids, carboxylic anhydrides and/or their derivatives to a homopolymer or copolymer of ethylene having a density less than 0.930 g/cm.sup.3, the monomers to be grafted are used in a concentration of from 0.01 to 0.5% by weight and the grafting reaction is carried out at from 210.degree. to 300.degree. C. in a conventional extruder or mixer in the absence of a free radical initiator. The graft copolymers are used for the preparation of ionomers and adhesion promoters.

N-(3,5-Dichlorophenyl)-oxazolidine-2,4-diones of the formula ##STR1## where R.sup.1 is haloalkenyl, alkenyl, chloromethyl, CN, CO--O-alkyl, alkoxyalkyl or alkylthioalkyl and R.sup.2 is haloalkenyl, alkenyl, hydrogen or alkyl, are prepared by a process in which 3,5-dichlorophenyl isocyanate is reacted with a glycolate of the formula ##STR2## where R.sup.1 and R.sup.2 have the above meanings and R.sup.3 is alkyl or cyclohexyl, in the presence of a tin(II) salt of the formula ##STR3## where R.sup.4 and R.sup.5 are identical or different and are each hydrogen, alkyl, alkenyl or unsubstituted or alkyl-substituted cycloalkyl, or benzyl or phenyl, or R.sup.4 and R.sup.5 together form --CH.sub.2 --CH.sub.2 --, --CH.dbd.CH-- or o-phenylene, at from 0.degree. to 110.degree. C., the product is heated in the presence of an alcohol of the formula

Preparation of N-(3,5-dichlorophenyl)oxazolidine-2,4-diones

In order to prepare thermoplastic polyurethane elastomers

Two-stage process for the preparation of thermoplastic polyurethane

The invention relates to a process for the continuous preparation of organic isocyanates, preferably polyisocyanates, through the reaction of organic amines, preferably polyamines, with phosgene in the presence of organic solvents under pressure, for example from 5 to 100 bar, at elevated temperatures, for example from 100 to 220.degree. C., whereby the reaction mixture is partially recycled, preferably using natural circulation, and the hydrogen chloride content in the reaction mixture prior to the addition of the amine is less than 0.5 percent by weight based on the total weight of the reaction mixture and the molar ratio of phosgene to NH.sub.2 group in the organic amines is from 12:1 to 200:1.

Process for the continuous preparation of organic mono-and/or

A process for the manufacture of 4,4'-diphenylmethane diisocyanate and a mixture of diphenylmethane diisocyanate isomers containing a controllable amount of uretdione and hydrolizable chlorine which comprises feeding crude MDI to an evaporator, condensing a head fraction in two stages in the presence of an inert gas, feeding the first stage condensate to a distillation column, producing a mixture of diphenylmethane diisocyanate isomers as an overhead, producing 4,4'-diphenylmethane diisocyanate as a side draw, and condensing each of the overhead and side draw in two stages in the presence of an inert gas.

Process for the manufacture of 4,4'-diphenyl-methane diisocyanate and a

Storage-stable, liquid carbodiimide-modified polyisocyanates are prepared by condensation of polyisocyanates in the presence of catalytic amounts of phospholine, phospholidine, phospholine oxides and/or phospholidine oxides, said condensation terminated and the products stabilized by means of perchloric acid or trifluoromethanesulfonic acid.

Storage-stable, liquid carbodiimide modified polyisocyanates and process

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Heidelberg, Germany

Rainer Ohlinger