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Raelynn M Miller

Deng-Yang Jan

Jaime G Moscoso

Susan C Koster

Robert J Schmidt

James A Johnson

Guy B Woodle

Gregory John Lewis

Gregory J Gajda

Paula L Bogdan

John E Bauer

Julio C Marte

Michael G Gatter

Masao Takayama

Mathias P Koljack

James F Mc Gehee

Stephen T Wilson

Stephen W Sohn

Mark G Riley

John Qianjun Chen

Bryan James Egolf

Feng Xu

Elena Z Maurukas

A process is disclosed using a new catalyst for use in the alkylation of benzene with a substantially linear olefin. The catalyst allows for cation exchange with a rare earth element to increase the alkylation of benzene, while reducing the amount of isomerization of the alkyl group. This is important for increasing the quality of the alkylbenzene by increasing the linearity of the alkylbenzene.

Detergent alkylation using a rare earth exchanged catalyst

A method of operating a continuous or semi-continuous system for a catalyst regeneration process. The system comprises a regenerator, the regenerator comprising a combustion zone and a halogenation zone. The catalyst is fed into the regenerator. A circulating regeneration gas is introduced into a regenerator circuit including oxygen, the circulating regeneration gas having a nitrogen concentration that is less than air. Oxygen from the circulating regeneration gas reacts with the coke to provide water and carbon dioxide. Water and the carbon dioxide formed in this first reaction then further react with the coke to form carbon monoxide and hydrogen.

Catalyst regenerator process

A process is presented for the formation of a SAPO-34 catalyst product. The process, that involves treatment with water or optionally at least one dissolved solid selected from the group consisting of ammonium chloride, ammonium phosphate, ammonium sulfate, ammonium acetate, ammonium carbonate, ammonium nitrate and mixtures thereof creates a SAPO-34 catalyst that has an increased selectivity for production of ethylene and propylene.

Water treated catalyst to produce light olefins

A method for preparing a family of zeolites, examples of which have been designated UZM-5, UZM-5P and UZM-6, and are represented by the empirical formulaMCRAlESiOThe method includes forming a Charge Density Mismatch (CDM) reaction mixture comprising reactive sources of Al, Si, optionally a framework element, E, and at least one organic nitrogen containing cation template, C, in the hydroxide form. After the CDM mixture is mixed while aging, an organic cation crystallization template, R, and at least one alkali metal or alkaline earth metal, M, is added. The combined final reaction mixture is reacted with mixing to produce the zeolite, which may be used in various hydrocarbon conversion processes.

UZM-5, UZM-5P, and UZM-6 crystalline aluminosilicate zeolites and methods for preparing the same

A process for alkylating aromatic compounds using a family of zeolites, examples of which have been designated UZM-5, UZM-5P and UZM-6, and are represented by the empirical formula:MCRAlESiOwhere M is an alkali or alkaline earth metal, E is an optional framework element, C organic nitrogen containing cation template, and R is an organic cation crystallization template. The zeolites have at least two x-ray diffraction peaks, one at a d-spacing of 3.9&#xb1;0.12 &#x212b; and one at a d-spacing 8.6&#xb1;0.20 &#x212b;; a tetragonal unit cell; and a micropore volume ranging from about 0.10 cc/g to about 0.18 cc/g.

Aromatic alkylation process using UZM-5, UZM-5P and UZM-6 zeolites

The present invention provides a process for decomposing a cumene hydroperoxide to produce phenol and acetone. The process utilizes a solid catalyst that can be non-layered or layered. The process includes: (1) introducing a process stream containing cumene hydroperoxide into a reaction vessel; (2) contacting the process stream with catalyst particles to form a process stream; and (3) withdrawing a portion of the product stream from the reactor and recovering phenol and acetone products.

Solid acid catalyst and process for decomposition of cumene hydroperoxide

Hydrocarbon conversion processes using a new family of zeolites identified as UZM-8HS are described. The UZM-8HS zeolite are derived from UZM-8 zeolites by treating the UZM-8 with a fluoro-silicate salt, an acid, etc. The UZM-8HS zeolites have unique x-ray diffraction patterns. These zeolites can be used in alkylation of aromatics, transalkylation of aromatics, isomerization of aromatics and alkylation of isoparaffins.

Hydrocarbon conversion processes using a catalyst comprising a UZM-8HS composition

Disclosed is a process and apparatus for alkylating light olefin with benzene at near but less than full conversion of the olefin. We have found that stopping below full conversion of the olefin maximizes yield of monoalkylbenzene.

Process for the high yield production of monoalkylaromatics

The present invention provides a catalyst particle of an inner core, an outer layer surrounding and bonded to the inner core, the outer layer of a zeolite beta catalyst, and the outer layer having a volumetric fraction from about 0.17 to about 0.62 of the entire catalyst particle.

Hydrocarbon conversion processes using a new family of zeolites identified as UZM-8 and UZM-8HS are described. The UZM-8 and UZM-8HS are related in that the UZM-8HS are derived from the UZM-8 zeolite by treating the UZM-8 with a fluoro-silicate salt, an acid, etc. The UZM-8 and -8HS have unique x-ray diffraction patterns. These zeolites can be used in alkylation of aromatics, transalkylation of aromatics, isomerization of aromatics and alkylation of isoparaffins.

Hydrocarbon conversion processes using catalysts comprising UZM-8 and UZM-8HS compositions

A layered catalyst composition is disclosed where the composition is prepared by bonding an outer layer comprising a bound zeolite (e.g. zeolite beta) to an inner core material (e.g. cordierite). The use of an organic bonding agent in the catalyst preparation procedure provides a composition that is sufficiently resistant to mechanical attrition to be used commercially in aromatic alkylation processes (e.g. benzene alkylation to ethylbenzene). Advantages associated with the use of layered compositions include a significant reduction in the amount of zeolite used for a given reactor loading and improved selectivity to desired alkylated aromatic products. Further benefits are realized when the layered composition is formed into shapes having a sufficiently high void volume to reduce pressure drop across the alkylation catalyst bed. This is especially relevant for operation involving high recycle rates and consequently low alkylating agent concentrations in the reaction zone. Such conditions are known to promote reduced byproduct formation.

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LaGrange, IL, United States of America

Raelynn M Miller