National Institute of Clean-and-low-carbon Energy

China Energy Investment Corporation Limited

Quan Lin

Peng Wang

Bo Feng

Qi Sun

Ping Miao

Yijun Lv

Kui Zhagn

Zhuowu Men

Fengbo Zhang

The present disclosure relates to the technical field of Fischer-Tropsch synthesis reaction catalysts, and discloses a supported &#x3b5;/&#x3b5;' iron carbide catalyst for Fischer-Tropsch synthesis reaction, preparation method thereof and Fischer-Tropsch synthesis process, wherein the method comprises the following steps: (1) dipping a catalyst carrier in a ferric salt aqueous solution, drying and roasting the dipped carrier to obtain a catalyst precursor; (2) subjecting the catalyst precursor and Hto a precursor reduction at the temperature of 300-550&#xb0; C.; (3) pretreating the material obtained in the step (2) with Hand CO at the temperature of 90-185&#xb0; C., wherein the molar ratio of H/CO is 1.2-2.8:1; (4) preparing carbide with the material obtained in the step (3), Hand CO at the temperature of 200-300&#xb0; C., wherein the molar ratio of H/CO is 1.0-3.2:1. The preparation method has the advantages of simple and easily obtained raw materials, simple and convenient operation steps, being capable of preparing the catalyst with 100% pure phase &#x3b5;/&#x3b5;&#x2032; iron carbide as the active phase, the catalyst has lower selectivity of COand CHand higher selectivity of effective products.

Supported &#x3b5;/&#x3b5;' iron carbide catalyst for Fischer-Tropsch synthesis reaction, preparation method thereof and Fischer-Tropsch synthesis process

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Beijing, China

Quan Lin