Hercules Corporation

Solenis Technologies, L.p.

Hercules Incorportated

Solenis Technologies Cayman, L.p.

Qu-Ming Gu

Huai Nan Cheng

Richard J Riehle

Ronald Richard Staib

Sachin Borkar

Kate Marritt Lusvardi

Joseph M Mahoney

Mingxiang Luo

Jonathan M McKay

William W Maslanka

Frank J Sutman

Robert G Nickol

Erin A S Doherty

Josette Servals Huynh-Ba

Duy T Nguyen

Lloyd A Lobo

Lei Qiao

Clement L Brungardt

Dennis Murphy

William S Carey

Wenhua Xie

Robert Alan Gelman

Richard Lee Brady

Ashley Hawkins Lewis

Peng George Wang

Christopher P Dilkus

Patrick Kovacs

Armin Michel

Jennifer L Rittenhouse-Pruss

Huai N Cheng

Ronald R Staib

Jennifer Rittenhouse-Pruss

Robert Gelman

Richard L Brady

Ashley Lewis

Josette Huynh-Ba

Jonathan M Mckay

Erin A Doherty

Disclosed herein are hydrophobic vinylamine-containing polymers useful as papermaking performance additives for enhancing paper softness with little or no negative effect on paper dry strength properties. The hydrophobic vinylamine-containing polymers are produced by incorporating hydrophobic functional property into primary amine moiety of the vinylamine-containing polymers via reactions with reactive hydrophobes. The hydrophobically modified vinylamine-containing polymers can be further used as base polymers for polymerization with a vinyl monomer by free radical initiated polymerization. The compositions of those hydrophobic vinylamine-containing polymers have shown improved softness, reduced coefficient friction to paper products while maintained or improved dry strength properties of the paper products.

Hydrophobic vinylamine-containing polymer compositions and their use in papermaking applications

A graft copolymer composition of a vinyl monomer and a functionalized vinylamine-containing base polymer and a method of preparing the graft copolymer. It also relates to a paper product made using the composition as a papermaking additive.

Modified vinylamine containing polymers and their use in papermaking

A method of improving dry strength and/or drainage of a paper or paperboard by adding to a paper or paperboard furnish, a graft copolymer composition of a vinyl monomer and a functionalized vinylamine-containing base polymer graft copolymer.

Modified of improving dry strength and/or drainage of a paper or paperboard

Provided is a method of making paper and paperboard. In particular graft copolymers of vinyl monomers and functionalized vinylamine-containing base polymers by Michael addition are added to a paper furnish. The composition can be used alone or in combination with other additives for use in paper making and to improve paper making processes such as paper dry and wet strength properties.

Modified vinylamine-containing polymers and their use in papermaking

Enzyme compositions comprising laccase, lipase, cationic polymer, and optionally laccase activator, for papermaking application are disclosed. It also relates to the use of the enzyme composition to improve dry strength property of a paper product made from lignocellulosic-containing materials before or after mechanical refining in a papermaking process.

Method for making lignocellulosic paper and paper product

Disclosed herein are cellulase compositions useful as papermaking performance additives for improving paper dry strength of a paper product and reducing refining energy in papermaking processes, and improving paper production. These cellulase compositions are formulated using cellulase, papermaking contaminant control polymers, protein stabilizers and cellulase enhancers. These cellulase compositions measure higher in endo-cellulase activity with better stability than conventional cellulase, and have shown differentiating performance in improving paper dry strength properties versus cellulase alone.

Cellulase composition containing cellulase and papermaking polymers for paper dry strength application

A process for producing an acylated vinylamine-containing polymer is disclosed. The acylated vinylamine-containing polymer is produced by reacting a vinylamine-containing polymer with at least one acylating agent.

Process to produce an acylated vinylamine-containing polymer and its application as a papermaking additive

Vinylamine-containing polymers are disclosed where the amine groups are substituted with (1) cationic functional groups, (2) anionic functional groups, (3) hydrophobic functional groups, (4) hydrophilic functional groups, (5) functional groups that impart amphoteric characteristics to the polymers, or (6) combinations thereof. Also disclosed are processes for preparing such polymers, as well as compositions comprising such polymers. Among other applications, these polymers can be used in papermaking applications as dry strength additives, wet strength additives, retention aids, drainage aids, and pitch and stickies control agents.

Modified vinylamine-containing polymers as additives in papermaking

Vinylamine-containing polymers are disclosed where the amine groups are substituted with cationic functional groups. Processes for preparing such polymers, as well as compositions comprising such polymers are also disclosed. Among other applications, these polymers can be used in papermaking applications as dry strength additives, wet strength additives, retention aids, drainage aids, and pitch and stickies control agents.

Quaternary vinylamine-containing polymers as additives in papermaking

Disclosed herein are hydrophobically-modified poly(aminoamides) useful as fixative detackifiers for stickies and pitch control in papermaking processes. These polymers are prepared via modification of amine-containing water-soluble poly(aminoamides) with reactive functional group-containing hydrophobic compounds. In particular, poly(aminoamides) may be modified, under appropriate reaction conditions, with long chain alkyl glycidyl ether, AKD (alkyl ketene dimer), ASA (alkyl succinyl anhydride), or Quab (3-chloro-2-hydroxypropyl-N,N,N-dimethylalkyl ammonium chloride). These novel polymers are effective in inhibiting deposition of organic contaminants in pulp and papermaking systems.

Hydrophobically modified poly(aminoamides)

A stable aqueous composition comprising polyvinylamine and liquid cationic starch in a ratio of from 90 to 55 parts of polyvinylamine on active basis to 10 to 45 parts of liquid cationic starch on active basis is disclosed. The composition can be used in papermaking as a strength or as a drainage aid.

Stable and aqueous compositions of polyvinylamines with cationic starch, and utility for papermaking

Methods for inhibiting the depositions of organic contaminants from pulp in pulp and papermaking systems are disclosed. Hydrophobically modified poly[ethylene glycol] are added to the pulp or applied to deposition-prone surfaces of a papermaking system.

Hydrophobically modifed poly[ethylene glycol] for use in pitch and stickies control in pulp and papermaking processes

The disclosure relates to an adhesive composition for bonding lignocellulosic substrates. The adhesive composition contains a crosslinker and a non-urea diluent where the non-urea diluent is present in an amount from about 0.01 to about 75 weight % based on the total wet weight of the composition and where the crosslinker contains essentially no formaldehyde. Also disclosed is the adhesive further containing. an aqueous mixture of a protein source. The disclosure also relates to a process for making lignocellulosic composites utilizing the disclosed adhesive composition and to the lignocellulosic composites made using the disclosed process.

Diluents for crosslinker-containing adhesive compositions

Several Michael addition adducts of vinylamines with &#x3b1;,&#x3b2;. -unsaturated alkyl carbonyl compounds including amides, esters and acids, particularly acrylamide are presented. Additionally, a process for producing these Michael addition adducts is described. These adducts are generally useful in the manufacture of paper and are particularly useful as dry strength additives to make paperboard products using a papermaking machine.

Michael addition adducts as additives for paper and papermaking

Polysaccharides comprising one or more oxime linkages are provided. Methods for their preparation include the polycondensation of saccharides bearing oxime-forming substituents. In some embodiments, polymerization is conducted in the presence of galactose oxidase. The resulting oxime-linked polysaccharides have desirable properties and are useful in numerous applications including paper manufacturing and drug delivery vehicles.

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Bear, DE, United States of America

Qu-Ming Gu