Chinese Academy of Sciences

Beijing Zhongkaihongde Technology Co., Ltd

Qixun Ban

Qingshan Zhu

Chuanlin Fan

Wenheng Mu

Cunhu Wang

Jibin Liu

Haitao Yang

A system and method for preparing a vanadium battery high-purity electrolyte, comprising preparing a low-valence vanadium oxide with a valence of 3.5 with liquid phase hydrolysis and fluidization reduction with vanadium oxytrichloride, adding clean water and sulfuric acid for dissolution, and further performing ultraviolet activation to obtain the vanadium electrolyte, for use in an all-vanadium redox flow battery stack. The high-temperature tail gas in the reduction fluidized bed is combusted for preheating the vanadium powder material, to recover the sensible heat and latent heat of the high-temperature tail gas, and the sensible heat of the reduction product is recovered through heat transfer between the reduction product and the fluidized nitrogen gas. An internal member is arranged in the reduction fluidized bed to realize the precise regulation of the valence state of the reduction product, and ultraviolet is used to activate the vanadium ions, improving the activity of the electrolyte.

System and method for preparing vanadium battery high-purity electrolyte

A system and method for producing a high-purity and high-activity vanadium electrolyte, comprising converting high-purity vanadium oxytrichloride into an ammonium salt in a fluidized bed by gas phase ammoniation, then in another fluidized bed, reducing the ammonium salt into a low-valence vanadium oxide having an average vanadium valence of 3.5, adding clean water and sulfuric acid for dissolution, and further performing activation by ultrasound to obtain a 3.5-valence vanadium electrolyte which can be directly used in a new all-vanadium redox flow battery stack. The method of producing an ammonium salt containing vanadium in the fluidized bed by gas phase ammoniation is of short process and high efficiency. Precise regulation of the valence state of the reduction product is implemented by arranging an internal member in the reduction fluidized bed, and ultrasonication is used to activate the vanadium ion, thereby greatly improving the activity of the electrolyte.

System and method for producing high-purity and high-activity vanadium electrolyte

A system and method for preparing a high-purity vanadium electrolyte, comprising preparing a low-valence vanadium oxide with vanadium oxytrichloride by ammonium salt precipitation and fluidization reduction, and preparing the high-purity vanadium electrolyte at a low temperature by adding a sulfuric acid solution and clean water under the conditions of ultrasound-assisted dissolution and activation. Efficient utilization of heat is achieved through heat exchange between the ammonium salt and the reduction tail gas and heat exchange between the reduction product and fluidized nitrogen gas. Ammonia gas in the reduction tail gas is recovered for precipitation of vanadium to achieve the recycling of ammonia gas. An internal member is arranged in the reduction fluidized bed to realize the precise regulation of the valence state of the reduction product. Furthermore, ultrasound-assisted dissolution and activation are employed to prepare the vanadium electrolyte at a low temperature, thereby improving the activity of the electrolyte.

System and method for preparing high purity vanadium electrolyte

A system and method for producing a 3.5-valence high-purity vanadium electrolyte, comprising hydrolyzing high-purity vanadium oxytrichloride into vanadium pentoxide in a fluidized bed, and reducing vanadium pentoxide into a low-valence vanadium oxide having an average vanadium valence of 3.5 adding water and a sulfuric acid solution under a microwave field applied externally for dissolution at a low temperature, to obtain a 3.5-valence high-purity vanadium electrolyte. The preparation of vanadium pentoxide by means of gas-phase hydrolysis in the fluidized bed is of short process and high efficiency. By providing an internal member within the reduction fluidized bed, the precise regulation of the valence state of the reduction product is achieved, and the special chemical effect of the microwave field is used to promote dissolution of the vanadium oxide and activate the vanadium ions, thereby greatly improving the activity of the electrolyte.

System and method for producing 3.5-valence high-purity vanadium electrolyte

The present invention provides a system and method for purifying vanadium pentoxide. Industrial grade vanadium pentoxide is converted to vanadium oxytrichloride by low temperature fluidizing chlorination, wherein chlorinating gas is preheated via heat exchange between fluidizing gas and chlorination flue gas, and an appropriate amount of air is added to enable a part of carbon powder to combust so as to achieve a balanced heat supply during the chlorination, thereby increasing the efficiency of chlorination and ensuring good selectivity in low temperature chlorination. The vanadium oxytrichloride is purified by rectification, and then subjected to plasma oxidation, thereby obtaining a high-purity vanadium pentoxide product and chlorine gas. The chlorine gas is returned for low temperature chlorination. The system and method have advantages of favorable adaptability to raw material, no discharge of contaminated wastewater, low energy consumption and chlorine consumption in production, stable product quality, etc.

System and method for purifying vanadium pentoxide

The present invention provides a system and method for purifying and preparing vanadium pentoxide powder. Industrial grade vanadium pentoxide is converted to vanadium oxytrichloride by low temperature fluidizing chlorination, wherein chlorinating gas is preheated via heat exchange between fluidizing gas and chlorination flue gas, and an appropriate amount of air is added to enable a part of carbon powder to combust so as to achieve a balanced heat supply during the chlorination, thereby increasing the efficiency of chlorination and ensuring good selectivity in low temperature chlorination. The vanadium oxytrichloride is purified by rectification, and then subjected to fluidized gas phase ammonification, thereby obtaining ammonium metavanadate, and further obtaining a high-purity vanadium pentoxide powder product through fluidized calcination. The system and method have advantages of favorable adaptability to raw material, no discharge of contaminated wastewater, low energy consumption and chlorine consumption in production, stable product quality etc.

System and method for purifying and preparing high-purity vanadium pentoxide powder

The present invention provides a system and method for producing high-purity vanadium tetraoxide powder. Industrial grade vanadium pentoxide is converted to vanadium oxytrichloride by low temperature fluidizing chlorination, wherein chlorinating gas is preheated via heat exchange between fluidizing gas and chlorination flue gas, and an appropriate amount of air is added to enable a part of carbon powder to combust so as to achieve a balanced heat supply during the chlorination, thereby increasing the efficiency of chlorination and ensuring good selectivity in low temperature chlorination. The vanadium oxytrichloride is purified by rectification, and then subjected to fluidized gas phase hydrolyzation, thereby producing a high-purity vanadium pentoxide product and a by-product solution of hydrochloric acid, and further obtaining a high-purity vanadium tetraoxide powder product through fluidized hydrogen reduction. The system and method have advantages of favorable adaptability to raw material, no discharge of contaminated wastewater, low energy consumption, etc.

System and method for producing high-purity vanadium tetraoxide powder

The present invention provides a system and method for producing high-purity vanadium pentoxide powder. Industrial grade vanadium pentoxide is converted to vanadium oxytrichloride by low temperature fluidizing chlorination, wherein chlorinating gas is preheated via heat exchange between fluidizing gas and chlorination flue gas, and an appropriate amount of air is added to enable a part of carbon powder to combust so as to achieve a balanced heat supply during the chlorination, thereby increasing the efficiency of chlorination and ensuring good selectivity in low temperature chlorination. The vanadium oxytrichloride is purified by rectification, and then subjected to fluidized gas phase hydrolyzation and fluidized calcination, thereby producing a high-purity vanadium pentoxide product and a by-product of hydrochloric acid solution. The system and method have advantages of favorable adaptability to raw material, no discharge of contaminated wastewater, low energy consumption in production, low operation cost, stable product quality, etc.

System and method for producing high-purity vanadium pentoxide powder

The present invention provides a system and method for preparing high-purity vanadium pentoxide powder. Industrial grade vanadium pentoxide is converted to vanadium oxytrichloride by low temperature fluidizing chlorination, wherein chlorinating gas is preheated via heat exchange between fluidizing gas and chlorination flue gas, and an appropriate amount of air is added to enable a part of carbon powder to combust so as to achieve a balanced heat supply during the chlorination, thereby increasing the efficiency of chlorination and ensuring good selectivity in low temperature chlorination. The vanadium oxytrichloride is subjected to purification by rectification, ammonium salt precipitation and fluidized calcination, thereby obtaining high-purity vanadium pentoxide, wherein the ammonia gas produced during calcination is condensed and then recycled for ammonium salt precipitation. The system and method have advantages of favorable adaptability to raw material, less pollution, low energy consumption in production, low operation cost, stable product quality, etc.

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Beijing, China

Qixun Ban