Tohoku University

Dowa Holdings Co., Ltd.

Qiwu Zhang

Kazuyuki Tohji

Hiroyuki Kai

Norihiro Shimoi

Yasumitsu Tanaka

A method for producing a negative electrode active material for a lithium ion secondary battery, comprising a step of charging either silicon and copper (II) oxide or silicon and copper metal in a pulverization device, pulverizing either the silicon and copper (II) oxide or silicon and copper metal, and simultaneously mixing either silicon and copper (II) oxide or silicon and copper metal thus pulverized. A negative electrode active material for a lithium ion secondary battery is produced by the method.

Method for producing negative electrode active material for lithium ion secondary battery

A negative electrode active material for a lithium ion secondary battery, comprising silicon, copper and oxygen as major constitutional elements, the negative electrode active material for a lithium ion secondary battery, containing fine particles of silicon having an average crystallite diameter (D) measured by an X-ray diffractometry of 50 nm or less, and having elemental ratios, expressed by molar ratios, Cu/(Si+Cu+O) and O/(Si+Cu+O) of from 0.02 to 0.30, wherein the negative electrode active material contains an intermetallic compound of silicon and copper.

Negative electrode active material for lithium ion secondary battery

In the case where a silicon substance having a high theoretical capacity as a negative electrode active material for a lithium ion secondary battery is used as a negative electrode active material, such a negative electrode active material is provided that has a high initial battery capacity and suffers less deterioration in performance even when many cycles of charge and discharge are repeated. A lithium ion secondary battery using the negative electrode active material is provided. Silicon and copper (II) oxide, or silicon, metallic copper and water are pulverized and simultaneously mixed in a pulverization device, thereby providing a negative electrode active material that has good cycle characteristics and a large battery capacity.

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Miyagi, Japan

Qiwu Zhang