China Petroleum Chemical Corporation

Fushun Research Institute of Petroleum and Petrochemicals, Sinopec Corp.

Dalian Research Institute of Petroleum and Petrochemicals, Sinopec Corp.

Qingtong Zhai

Kai Qiao

Shumei Zhang

Feng Zhou

Huixia Ma

Jie Su

Chunmei Wang

Changxin Guo

Ming Chen

The present invention relates to a preparation process for a Cu-based catalyst and use of the Cu-based catalyst as the dehydrogenation catalyst in producing a hydroxyketone compound such as acetoin. Said Cu-based catalyst shows a high the acetoin selectivity as the dehydrogenation catalyst for producing acetoin.

Preparation process for Cu-based catalyst and use thereof

The present invention relates to a Cu-based catalyst, a preparation process thereof and its use as the dehydrogenation catalyst in producing a hydroxyketone compound such as acetoin. Said Cu-based catalyst contains copper, at least one auxiliary metal selected from metal of Group IIA, non-noble metal of Group VIII, metal of Group VIB, metal of Group VIIB, metal of Group IIB and lanthanide metal of periodic table of elements, and an alkali metal, and further contains at least one ketone additive selected from a ketone represented by formula (II) and a ketone represented by formula (II'). Said Cu-based catalyst shows a high the acetoin selectivity as the dehydrogenation catalyst for producing acetoin.R1-C(&#x2550;O)&#x2014;CH(OH)&#x2014;R2&#x2003;&#x2003;(II)R1-C(&#x2550;O)&#x2014;CH(&#x2550;O)&#x2014;R2&#x2003;&#x2003;(II&#x2032;) In formulae (II) and (II&#x2032;), each group is defined as in the description.

Cu-based catalyst, its preparation process and use thereof

The present invention relates to the field of isobutylene preparation. Disclosed are a catalyst and preparation method thereof, and method for preparing isobutylene by applying the same; the catalyst has a core-shell structure, the core an amorphous silica-alumina particle and/or an aggregate molding thereof, and the shell aluminum oxide comprising silicon and tin; the weight ratio of aluminum oxide comprising silicon and tin to amorphous silica-alumina is 1:60-1:3; in the aluminum oxide comprising silicon and tin, on basis of the weight of aluminum oxide comprising silicon and tin, the content of silicon is 0.5-2 wt %, and of tin is 0.2-1 wt %. The catalyst of the present invention is used to catalyze a mixture of MTBE and TBA to prepare isobutylene, enabling the MTBE cleavage and TBA dehydration reactions to be conducted simultaneously to generate isobutylene, achieving higher conversion rates of TBA and MTBE, and higher selectivity for generating isobutylene.

Catalyst and preparation method thereof, and method for preparing isobutylene by applying the same

Disclosed is a catalyst for preparing isobutene by dissociation of methyl tert-butyl ether, the catalyst comprising amorphous silica alumina and a silicalite-1 molecular sieve, wherein the total IR acid amount of weak acids in the catalyst is in a range from 0.020 to 0.080 mmol/g, and the ratio of B acid/L acid of the weak acids is in a range from 2.5:1 to 4.0:1. Also provided is a method of preparing the catalyst and the use thereof. The catalyst has a high selectivity with respect to isobutene, and high conversion of methyl tert-butyl ether, and can also effectively inhibit formation of the by-product dimethyl ether.

Catalyst for preparing isobutene by dissociation of methyl tert-butyl ether, preparation method and use thereof

Growing community of inventors

Liaoning, China

Qingtong Zhai