China Petroleum & Chemical Corporation

Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation

Qingqiang Gou

Zifang Guo

Junling Zhou

Jie Lin

Xiaofan Zhang

Dongbing Liu

Rong Gao

Xinyang Li

Junhui Zhang

Jingyan An

Jingjing Lai

Yuanning Gu

Yan Li

Hui Zhao

Jie Fu

Hongtao Wang

Shiyuan Xu

Tingjie Huang

Hongxu Yang

Ting Huang

Dong Ma

Shijun Zhang

Wenbo Song

Lunjia Xie

Zhufang Sun

Peng Kou

Bingyi Li

Taoyi Zhang

Meiyan Fu

Ruixia Li

Ruen Wang

Yanhong Wan

Yonghua Ma

A diimine metal complex represented by Formula I, a preparation method therefor, and application thereof are provided. The complex is used as a main catalyst in catalysts for olefin polymerization, and can achieve catalytic ethylene polymerization at a high temperature to prepare high molecular weight branched polyethylene.

Diimine metal complex, preparation method therefor, and application thereof

A method for preparing an olefin-olefinic alcohol copolymer and an olefin-olefinic alcohol copolymer prepared by the method are provided. The catalyst used in the method for preparing the olefin-olefinic alcohol copolymer has a diimine metal complex as shown in Formula I.

Method for preparing olefin-polar monomer copolymer

An amino-imine metal complex represented by Formula I, its preparation method and an application thereof are provided. The complex is used as a main catalyst in catalysts for olefin polymerization, and can catalyze the polymerization of ethylene at a relatively high temperature to prepare branched polyethylene having high molecular weight.

Amino-imine metal complex and preparation method therefor and application thereof

The present invention discloses a Ziegler-Natta catalyst system for olefin polymerization, comprising at least one compound represented by formula (I) as (i) an internal electron donor, (ii) an external electron donor, or (iii) the both, wherein M, M, M, M, M, M, M', M&#x2032;, M&#x2032;, M&#x2032;, M&#x2032; and M&#x2032; are each independently selected from the group consisting of hydrogen, hydroxy, amino, aldehyde group, carboxy, acyl, halogen atoms, &#x2014;Rand &#x2014;OR, wherein Rand Rare each independently a C-Chydrocarbyl, which is unsubstituted or substituted by a substituent selected from the group consisting of hydroxy, amino, aldehyde group, carboxy, acyl, halogen atoms, C-Calkoxy and heteroatoms; and wherein, when among M-Mand M&#x2032;-M&#x2032;, any two adjacent groups on the same phenyl ring are each independently selected from the group consisting of Rand &#x2014;OR, the two adjacent groups may optionally be linked to form a ring, with a proviso that M, M, M, M, M, M, M&#x2032;, M&#x2032;, M&#x2032;, M&#x2032;, M&#x2032; and M&#x2032; are not simultaneously hydrogen. 

Olefin polymerization catalyst comprising cyclotriveratrylene and derivatives thereof

A catalyst component for ethylene polymerization, comprising an organic silicon compound of the formula (I), below wherein Ris chosen from C-Caliphatic hydrocarbyl groups, and is substituted with at least one substituent chosen from halogens, C-Cacyloxy groups, epoxy, amino, C-Calkylamino groups, di(C-Calkyl)amino groups, C-Calkoxy groups, and oxo group; R, Rand R, which may be the same or different, are each chosen from C-Caliphatic hydrocarbyl, C-Calicyclic hydrocarbyl, C-Caryl, C-Caralkyl, and C-Calkaryl groups. A process for preparing the catalyst component and an active catalyst comprising the catalyst component and useful in polymerization, such as ethylene polymerization. 

Catalyst component for ethylene polymerization, preparation thereof, and a catalyst comprising the catalyst component

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Beijing, China

Qingqiang Gou